J.P. Steyer

Pretreatment methods to improve sludge anaerobic degradability: a review.

This paper presents a review of the main sludge treatment techniques used as a pretreatment to anaerobic digestion. These processes include biological (largely thermal phased anaerobic), thermal hydrolysis, mechanical (such as ultrasound, high pressure and lysis), chemical with oxidation (mainly ozonation), and alkali treatments. The first three are the most widespread. Emphasis is put on their impact on the resulting sludge properties, on the potential biogas (renewable energy) production and on their application at industrial scale. Thermal biological provides a moderate performance increase over mesophilic digestion, with moderate energetic input. Mechanical treatment methods are comparable, and provide moderate performance improvements with moderate electrical input. Thermal hydrolysis provides substantial performance increases, with a substantial consumption of thermal energy. It is likely that low impact pretreatment methods such as mechanical and thermal phased improve speed of degradation, while high impact methods such as thermal hydrolysis or oxidation improve both speed and extent of degradation. While increased nutrient release can be a substantial cost in enhanced sludge destruction, it also offers opportunities to recover nutrients from a concentrated water stream as mineral fertiliser.

Benchmark Simulation Model No 2: finalisation of plant layout and default control strategy

The COST/IWA Benchmark Simulation Model No 1 (BSM1) has been available for almost a decade. Its primary purpose has been to create a platform for control strategy benchmarking of activated sludge processes. The fact that the research work related to the benchmark simulation models has resulted in more than 300 publications worldwide demonstrates the interest in and need of such tools within the research community. Recent efforts within the IWA Task Group on Benchmarking of control strategies for WWTPs have focused on an extension of the benchmark simulation model. This extension aims at facilitating control strategy development and performance evaluation at a plant-wide level and, consequently, includes both pretreatment of wastewater as well as the processes describing sludge treatment. The motivation for the extension is the increasing interest and need to operate and control wastewater treatment systems not only at an individual process level but also on a plant-wide basis. To facilitate the changes, the evaluation period has been extended to one year. A prolonged evaluation period allows for long-term control strategies to be assessed and enables the use of control handles that cannot be evaluated in a realistic fashion in the one week BSM1 evaluation period. In this paper, the finalised plant layout is summarised and, as was done for BSM1, a default control strategy is proposed. A demonstration of how BSM2 can be used to evaluate control strategies is also given.

Instrumentation, Control and Automation in Wastewater Systems

nstrumentation, control and automation (ICA) in wastewater treatment systems is now an established and recognised area of technology in the profession.nnThere are obvious incentives for ICA, not the least from an economic point of view. Plants are also becoming increasingly complex which necessitates automation and control. Instrumentation, Control and Automation in Wastewater Systems summarizes the state-of-the-art of ICA and its application in wastewater treatment systems and focuses on how leading-edge technology is used for better operation.nnThe book is written for:nn * The practising process engineer and the operator, who wishes to get an updated picture of what is possible to implement in terms of ICA; * The process designer, who needs to consider the couplings between design and operation; * The researcher or the student, who wishes to get the latest technological overview of an increasingly complex field.nnThere is a clear aim to present a practical ICA approach, based on a technical and economic platform. The economic benefit of different control and operation possibilities is quantified. The more qualitative benefits, such as better process understanding and more challenging work for the operator are also described. Several full-scale experiences of how ICA has improved economy, ease of operation and robustness of plant operation are presented. The book emphasizes both unit process control and plant wide operation.

Software sensors for highly uncertain WWTPs: a new approach based on interval observers

This paper presents the practical implementation of a new robust interval observer on a 1 m3 continuous fixed bed anaerobic reactor used for the treatment of industrial wine distillery wastewater. This interval observer is able to generate guaranteed intervals for the unmeasured variables (i.e. acidogenic and methanogenic bacteria, alkalinity and chemical oxygen demand) from few on-line measurements (i.e. input liquid flow rate, CO2 gaseous flow rate, volatile fatty acids and total inorganic carbon). The main advantage of this approach is its independance with respect to disturbances and uncertainty in the initial conditions, in the kinetics and, last but not least, in the process inputs.

A waste characterisation procedure for ADM1 implementation based on degradation kinetics.

In this study, a procedure accounting for degradation kinetics was developed to split the total COD of a substrate into each input state variable required for Anaerobic Digestion Model n°1. The procedure is based on the combination of batch experimental degradation tests (anaerobic respirometry) and numerical interpretation of the results obtained (optimisation of the ADM1 input state variable set). The effects of the main operating parameters, such as the substrate to inoculum ratio in batch experiments and the origin of the inoculum, were investigated. Combined with biochemical fractionation of the total COD of substrates, this method enabled determination of an ADM1-consistent input state variable set for each substrate with affordable identifiability. The substrate to inoculum ratio in the batch experiments and the origin of the inoculum influenced input state variables. However, based on results modelled for a CSTR fed with the substrate concerned, these effects were not significant. Indeed, if the optimal ranges of these operational parameters are respected, uncertainty in COD fractionation is mainly limited to temporal variability of the properties of the substrates. As the method is based on kinetics and is easy to implement for a wide range of substrates, it is a very promising way to numerically predict the effect of design parameters on the efficiency of an anaerobic CSTR. This method thus promotes the use of modelling for the design and optimisation of anaerobic processes.

Thermal pre-treatment of aerobic granular sludge: Impact on anaerobic biodegradability

The aerobic granular systems are a good alternative to the conventional activated sludge (AS) ones to reduce the production of sludge generated in wastewater treatment plants (WWTP). Although the quantity of produced sludge is low its post-treatment is still necessary. In the present work the application of the anaerobic digestion combined with a thermal pre-treatment was studied to treat two different aerobic granular biomasses: one from a reactor fed with pig manure (G1) and another from a reactor fed with a synthetic medium to simulate an urban wastewater (G2). The results obtained with the untreated aerobic granular biomasses showed that their anaerobic biodegradability (BD) (33% for G1 and 49% for G2) was similar to that obtained for an activated sludge (30-50%) and demonstrate the feasibility of their anaerobic digestion. The thermal pre-treatment before the anaerobic digestion was proposed as a good option to enhance the BD when this was initially low (33% G1) with an enhancement between 20% at 60 °C and 88% at 170 °C with respect to the untreated sludge. However when the initial BD was higher (49% G2) the thermal pre-treatment produced a slight improvement in the methane production (14% and 18%) and at high temperatures (190 and 210 °C) which did not justify the application of such a treatment.

Modeling and experiments on the influence of biofilm size and mass transfer in a fluidized bed reactor for anaerobic digestion

The kinetics of fluidized bed bioparticles for glucose fermentation into methane is investigated. As bed stratification occurs, the behaviour of biofilms is different along the height of the column. The experimental part of this study concerns the characterization of bioparticles coming from different heights of a pilot-scale reactor. Biofilm sizes and activities are measured. Batch tests are achieved with glucose, acetate and propionate as carbon sources in order to estimate the specific activity of each trophic group. The experimental sections shows that, for thick biofilms, the acidogenic activity is lower and the methanogenic activity is higher than for thin films. The modelling part describes the relationship between mass transfer limitations (when several trophic groups are involved) and biofilm size. The dynamic simulations gave a good fit to the experimental batch tests. Both simulations and experiments indicates that the biomass composition of the biofilm depends on biofilm size. When biofilm thickness increases, the amount of acidogens decreases and the amount of methanogens increases, mainly because acidogen growth is diffusion-limited. The biomass distribution in the biofilm among each trophic group appeared to be a very important parameter. This shows that bed stratification has an influence not only on the hydrodynamics of the fluidized layer but also on the kinetics of organic carbon elimination by methanogenic biofilms. This phenomenon has to be taken into account for further modelling and design of fluidized bed fermenters.

Instrumentation, control and automation in wastewater - From London 1973 to Narbonne 2013

Key developments of instrumentation, control and automation (ICA) applications in wastewater systems during the past 40 years are highlighted in this paper. From the first ICA conference in 1973 through to today there has been a tremendous increase in the understanding of the processes, instrumentation, computer systems and control theory. However, many developments have not been addressed here, such as sewer control, drinking water treatment and water distribution control. It is hoped that this review can stimulate new attempts to more effectively apply control and automation in water systems in the coming years.

Modelling micro-pollutant fate in wastewater collection and treatment systems: status and challenges

This paper provides a comprehensive summary on modelling of micro-pollutants (MPs) fate and transport in wastewater. It indicates the motivations of MP modelling and summarises and illustrates the current status. Finally, some recommendations are provided to improve and diffuse the use of such models. In brief, we conclude that, in order to predict the contaminant removal in centralised treatment works, considering the dramatic improvement in monitoring and detecting MPs in wastewater, more mechanistic approaches should be used to complement conventional, heuristic and other fate models. This is crucial, as regional risk assessments and model-based evaluations of pollution discharge from urban areas can potentially be used by decision makers to evaluate effluent quality regulation, and assess upgrading requirements, in the future.

Bioelectrochemical treatment of table olive brine processing wastewater for biogas production and phenolic compounds removal.

Industry of table olives is widely distributed over the Mediterranean countries and generates large volumes of processing wastewaters (TOPWs). TOPWs contain high levels of organic matter, salt, and phenolic compounds that are recalcitrant to microbial degradation. This work aims to evaluate the potential of bioelectrochemical systems to simultaneously treat real TOPWs and recover energy. The experiments were performed in potentiostatically-controlled single-chamber systems fed with real TOPW and using a moderate halophilic consortium as biocatalyst. In conventional anaerobic digestion (AD) treatment, ie. where no potential was applied, no CH4 was produced. In comparison, Bio-Electrochemical Systems (BES) showed a maximum CH4 yield of 701xa0±xa013xa0NmL CH4·LTOPW(-1) under a current density of 7.1xa0±xa00.4xa0Axa0m(-2) and with a coulombic efficiency of 30%. Interestingly, up to 80% of the phenolic compounds found in the raw TOPW (i.e. hydroxytyrosol and tyrosol) were removed. A new theoretical degradation pathway was proposed after identification of the metabolic by-products. Consistently, microbial community analysis at the anode revealed a clear and specific enrichment in anode-respiring bacteria (ARB) from the genera Desulfuromonas and Geoalkalibacter, supporting the key role of these electroactive microorganisms. As a conclusion, bioelectrochemical systems represent a promising bioprocess alternative for the treatment and energy recovery of recalcitrant TOPWs.