J. R. Goicoechea

Water in Star-forming Regions with the Herschel Space Observatory (WISH). I. Overview of Key Program and First Results

Water In Star-forming regions with Herschel (WISH) is a key program on the Herschel Space Observatory designed to probe the physical and chemical structures of young stellar objects using water and related molecules and to follow the water abundance from collapsing clouds to planet-forming disks. About 80 sources are targeted, covering a wide ranee of luminosities-from low ( 10(5) L-circle dot)-and a wide range of evolutionary stages-from cold prestellar cores to warm protostellar envelopes and outflows to disks around young stars. Both the HIFI and PACS instruments are used to observe a variety of lines of H2O, (H2O)-O-18 and chemically related species at the source position and in small maps around the protostars and selected outflow positions. In addition, high-frequency lines of CO, (CO)-C-13, and (CO)-O-18 are obtained with Herschel and are complemented by ground-based observations of dust continuum, HDO, CO and its isotopologs, and other molecules to ensure a self-consistent data set for analysis. An overview of the scientific motivation and observational strategy of the program is given, together with the modeling approach and analysis tools that have been developed. Initial science results are presented. These include a lack of water in cold gas at abundances that are lower than most predictions, strong water emission from shocks in protostellar environments, the importance of UV radiation in heating the gas along outflow walls across the full range of luminosities, and surprisingly widespread detection of the chemically related hydrides OH+ and H2O+ in outflows and foreground gas. Quantitative estimates of the energy budget indicate that H2O is generally not the dominant coolant in the warm dense gas associated with protostars. Very deep limits on the cold gaseous water reservoir in the outer regions of protoplanetary disks are obtained that have profound implications for our understanding of grain growth and mixing in disks.

Astronomical identification of CN-, the smallest observed molecular anion

We present the first astronomical detection of a diatomic negative ion, the cyanide anion CN-, as well as quantum mechanical calculations of the excitation of this anion through collisions with para-H2. CN- is identified through the observation of the J = 2-1 and J = 3-2 rotational transitions in the C-star envelope IRC +10216 with the IRAM 30-m telescope. The U-shaped line profiles indicate that CN-, like the large anion C6H-, is formed in the outer regions of the envelope. Chemical and excitation model calculations suggest that this species forms from the reaction of large carbon anions with N atoms, rather than from the radiative attachment of an electron to CN, as is the case for large molecular anions. The unexpectedly large abundance derived for CN-, 0.25 % relative to CN, makes likely its detection in other astronomical sources. A parallel search for the small anion C2H- remains so far unconclusive, despite the previous tentative identification of the J = 1-0 rotational transition. The abundance of C2H- in IRC +10216 is found to be vanishingly small, < 0.0014 % relative to C2H.

Interstellar OH+, H2O+ and H3O+ along the sight-line to G10.6–0.4

We report the detection of absorption lines by the reactive ions OH + ,H 2O + and H3O + along the line of sight to the submillimeter continuum source G10.6−0.4 (W31C). We used the Herschel HIFI instrument in dual beam switch mode to observe the ground state rotational transitions of OH + at 971 GHz, H2O + at 1115 and 607 GHz, and H3O + at 984 GHz. The resultant spectra show deep absorption over a broad velocity range that originates in the interstellar matter along the line of sight to G10.6−0.4 as well as in the molecular gas directly associated with that source. The OH + spectrum reaches saturation over most velocities corresponding to the foreground gas, while the opacity of the H2O + lines remains lower than 1 in the same velocity range, and the H3O + line shows only weak absorption. For LSR velocities between 7 and 50 kms −1 we estimate total column densities of N(OH + ) ≥ 2.5 × 10 14 cm −2 , N(H2O + ) ∼6 × 10 13 cm −2 and N(H3O + ) ∼4.0 × 10 13 cm −2 . These detections confirm the role of O + and OH + in initiating the oxygen chemistry in diffuse molecular gas and strengthen our understanding of the gas phase production of water. The high ratio of the OH + by the H2O + column density implies that these species predominantly trace low-density gas with a small fraction of

Herschel/HIFI observations of interstellar OH+ and H2O+ towards W49N: a probe of diffuse clouds with a small molecular fraction

We report the detection of absorption by interstellar hydroxyl cations and water cations, along the sight-line to the bright continuum source W49N. We have used Herschels HIFI instrument, in dual beam switch mode, to observe the 972 GHz N = 1-0 transition of OH+ and the 1115 GHz 1(11)-0(00) transition of ortho-H2O+. The resultant spectra show absorption by ortho-H2O+, and strong absorption by OH+, in foreground material at velocities in the range 0 to 70 km s(-1) with respect to the local standard of rest. The inferred OH+/H2O+ abundance ratio ranges from similar to 3 to similar to 15, implying that the observed OH+ arises in clouds of small molecular fraction, in the 2-8% range. This conclusion is confirmed by the distribution of OH+ and H2O+ in Doppler velocity space, which is similar to that of atomic hydrogen, as observed by means of 21 cm absorption measurements, and dissimilar from that typical of other molecular tracers. The observed OH+/H abundance ratio of a few x10(-8) suggests a cosmic ray ionization rate for atomic hydrogen of 0.6-2.4 x 10(-16) s(-1), in good agreement with estimates inferred previously for diffuse clouds in the Galactic disk from observations of interstellar H-3(+) and other species.

THE CHEMISTRY OF INTERSTELLAR OH+, H2O+, AND H3O+: INFERRING THE COSMIC-RAY IONIZATION RATES FROM OBSERVATIONS OF MOLECULAR IONS

We model the production of OH+, H2O+, and H3O+ in interstellar clouds, using a steady-state photodissociation region code that treats the freezeout of gas species, grain surface chemistry, and desorption of ices from grains. The code includes polycyclic aromatic hydrocarbons (PAHs), which have important effects on the chemistry. All three ions generally have two peaks in abundance as a function of depth into the cloud, one at AV 1 and one at AV ~ 3-8, the exact values depending on the ratio of incident ultraviolet flux to gas density. For relatively low values of the incident far-ultraviolet flux on the cloud (? 1000; ? = 1 = local interstellar value), the columns of OH+ and H2O+ scale roughly as the cosmic-ray primary ionization rate ?crp divided by the hydrogen nucleus density n. The H3O+ column is dominated by the second peak, and we show that if PAHs are present, N(H3O+) ~4 ? 1013?cm?2 independent of ?crp or n. If there are no PAHs or very small grains at the second peak, N(H3O+) can attain such columns only if low-ionization potential metals are heavily depleted. We also model diffuse and translucent clouds in the interstellar medium, and show how observations of N(OH+)/N(H) and N(OH+)/N(H2O+) can be used to estimate ?crp/n, ?/n and AV in them. We compare our models to Herschel observations of these two ions, and estimate ?crp ~4-6 ? 10?16(n/100 cm?3)?s?1 and ?/n = 0.03?cm3 for diffuse foreground clouds toward W49N.

Herschel observations of EXtra-Ordinary Sources (HEXOS):The present and future of spectral surveys with Herschel/HIFI

We present initial results from the Herschel GT key program: Herschel observations of EXtra-Ordinary Sources (HEXOS) and outline the promise and potential of spectral surveys with Herschel/HIFI. The HIFI instrument offers unprecedented sensitivity, as well as continuous spectral coverage across the gaps imposed by the atmosphere, opening up a largely unexplored wavelength regime to high-resolution spectroscopy. We show the spectrum of Orion KL between 480 and 560 GHz and from 1.06 to 1.115 THz. From these data, we confirm that HIFI separately measures the dust continuum and spectrally resolves emission lines in Orion KL. Based on this capability we demonstrate that the line contribution to the broad-band continuum in this molecule-rich source is ~20-40% below 1 THz and declines to a few percent at higher frequencies. We also tentatively identify multiple transitions of HD18O in the spectra. The first detection of this rare isotopologue in the interstellar medium suggests that HDO emission is optically thick in the Orion hot core with HDO/H2O ~ 0.02. We discuss the implications of this detection for the water D/H ratio in hot cores. Herschel is an ESA space observatory with science instruments provided by European-led Principal Investigator consortia and with important participation from NASA.Figure 2 (page 6) is also available in electronic form at http://www.aanda.org

Comparative study of CH+ and SH+ absorption lines observed towards distant star-forming regions

Aims. The HIFI instrument onboard Herschel has allowed high spectral resolution and sensitive observations of ground-state transitions of three molecular ions: the methylidyne cation CH^+, its isotopologue ^(13)CH^+, and sulfanylium SH^+. Because of their unique chemical properties, a comparative analysis of these cations provides essential clues to the link between the chemistry and dynamics of the diffuse interstellar medium. Methods. The CH^+, ^(13)CH^+, and SH^+ lines are observed in absorption towards the distant high-mass star-forming regions (SFRs) DR21(OH), G34.3+0.1, W31C, W33A, W49N, and W51, and towards two sources close to the Galactic centre, SgrB2(N) and SgrA^*+50. All sight lines sample the diffuse interstellar matter along pathlengths of several kiloparsecs across the Galactic Plane. In order to compare the velocity structure of each species, the observed line profiles were deconvolved from the hyperfine structure of the SH^+ transition and the CH^+, ^(13)CH^+, and SH^+ spectra were independently decomposed into Gaussian velocity components. To analyse the chemical composition of the foreground gas, all spectra were divided, in a second step, into velocity intervals over which the CH^+, ^(13)CH^+, and SH^+ column densities and abundances were derived. Results. SH^+ is detected along all observed lines of sight, with a velocity structure close to that of CH^+ and ^(13)CH^+. The linewidth distributions of the CH^+, SH^+, and ^(13)CH^+ Gaussian components are found to be similar. These distributions have the same mean (⟨Δυ⟩ ~ 4.2 km s^(-1)) and standard deviation (σ(Δυ) ~ 1.5 km s^(-1)). This mean value is also close to that of the linewidth distribution of the CH^+ visible transitions detected in the solar neighbourhood. We show that the lack of absorption components narrower than 2 km s^(-1) is not an artefact caused by noise: the CH^+, ^(13)CH^+, and SH^+ line profiles are therefore statistically broader than those of most species detected in absorption in diffuse interstellar gas (e.g. HCO^+, CH, or CN). The SH^+/CH^+ column density ratio observed in the components located away from the Galactic centre spans two orders of magnitude and correlates with the CH^+ abundance. Conversely, the ratio observed in the components close to the Galactic centre varies over less than one order of magnitude with no apparent correlation with the CH^+ abundance. The observed dynamical and chemical properties of SH^+ and CH^+ are proposed to trace the ubiquitous process of turbulent dissipation, in shocks or shears, in the diffuse ISM and the specific environment of the Galactic centre regions.

Water cooling of shocks in protostellar outflows: Herschel-PACS map of L1157

Context. The far-IR/sub-mm spectral mapping facility provided by the Herschel-PACS and HIFI instruments has made it possible to obtain, for the first time, images of H2O emission with a spatial resolution comparable to ground based mm/sub-mm observations. Aims. In the framework of the Water In Star-forming regions with Herschel (WISH) key program, maps in water lines of several outflows from young stars are being obtained, to study the water production in shocks and its role in the outflow cooling. This paper reports the first results of this program, presenting a PACS map of the o-H2O 179 mu m transition obtained toward the young outflow L1157. Methods. The 179 mu m map is compared with those of other important shock tracers, and with previous single-pointing ISO, SWAS, and Odin water observations of the same source that allow us to constrain the H2O abundance and total cooling. Results. Strong H2O peaks are localized on both shocked emission knots and the central source position. The H2O 179 mu m emission is spatially correlated with emission from H-2 rotational lines, excited in shocks leading to a significant enhancement of the water abundance. Water emission peaks along the outflow also correlate with peaks of other shock-produced molecular species, such as SiO and NH3. A strong H2O peak is also observed at the location of the proto-star, where none of the other molecules have significant emission. The absolute 179 mu m intensity and its intensity ratio to the H2O 557 GHz line previously observed with Odin/SWAS indicate that the water emission originates in warm compact clumps, spatially unresolved by PACS, having a H2O abundance of the order of 10(-4). This testifies that the clumps have been heated for a time long enough to allow the conversion of almost all the available gas-phase oxygen into water. The total H2O cooling is similar to 10(-1) L-circle dot, about 40% of the cooling due to H-2 and 23% of the total energy released in shocks along the L1157 outflow.

Far-infrared Detection of C3 in Sagittarius B2 and IRC +10216.

We report on the detection of nine lines of the nu2 bending mode of triatomic carbon, C3, in the direction of Sagittarius B2. The R(4) and R(2) lines of C3 have been also detected in the carbon-rich star IRC +10216. The abundances of C3 in the direction of Sgr B2 and IRC +10216 are approximately 3x10-8 and approximately 10-6, respectively. In Sgr B2 we have also detected the 23-12 line of NH with an abundance of a few times 10-9. Polyatomic molecules will have a weak contribution from their pure rotational spectrum to the emission/absorption in the far-infrared. We suggest, however, that they could be, through their low-lying vibrational bending modes, the dominant carriers of emission/absorption in the spectrum of bright far-infrared sources.

Detection of hydrogen fluoride absorption in diffuse molecular clouds with Herschel/HIFI: an ubiquitous tracer of molecular gas

We discuss the detection of absorption by interstellar hydrogen fluoride (HF) along the sight line to the submillimeter continuum sources W49N and W51. We have used Herschels HIFI instrument in dual beam switch mode to observe the 1232.4762 GHz J = 1-0 HF transition in the upper sideband of the band 5a receiver. We detected foreground absorption by HF toward both sources over a wide range of velocities. Optically thin absorption components were detected on both sight lines, allowing us to measure - as opposed to obtain a lower limit on - the column density of HF for the first time. As in previous observations of HF toward the source G10.6-0.4, the derived HF column density is typically comparable to that of water vapor, even though the elemental abundance of oxygen is greater than that of fluorine by four orders of magnitude. We used the rather uncertain N(CH) - N(H-2) relationship derived previously toward diffuse molecular clouds to infer the molecular hydrogen column density in the clouds exhibiting HF absorption. Within the uncertainties, we find that the abundance of HF with respect to H-2 is consistent with the theoretical prediction that HF is the main reservoir of gas-phase fluorine for these clouds. Thus, hydrogen fluoride has the potential to become an excellent tracer of molecular hydrogen, and provides a sensitive probe of clouds of small H-2 column density. Indeed, the observations of hydrogen fluoride reported here reveal the presence of a low column density diffuse molecular cloud along the W51 sight line, at an LSR velocity of similar to 24 km s(-1), that had not been identified in molecular absorption line studies prior to the launch of Herschel.