J. Tikkanen

The low-temperature magnetostructure and magnetic field response of Pr0.9Ca0.1MnO3: the roles of Pr spins and magnetic phase separation

With the goal of elucidating the background of photoinduced ferromagnetism phenomena observed in the perovskite structured (Pr,Ca) manganites, the low-temperature magnetostructure of the material Pr0.9Ca0.1MnO3 was revised using cold neutron powder diffraction, SQUID magnetometry and ab initio calculations. Particular emphasis was placed on determining the presence of nanoscale magnetic phase separation. Previously published results of a canted A-AFM average ground state were reproduced to a good precision both experimentally and theoretically, and complemented by investigating the effects of an applied magnetic field of 2.7 T on the magnetostructure. Explicit evidence of nanoscale magnetic clusters in the material was obtained based on high-resolution neutron diffractograms. Along with several supporting arguments, we present this finding as a justification for extending the nanoscale magnetic phase separation model of manganites to the material under discussion despite its very low Ca doping level in the context of the model. In the light of the new data, we also conclude that the low temperature magnetic moment of Pr must be ca. 300% larger than previously thought in this material, close to the high spin value of 2μB per formula unit.

The Magnetocaloric Performance of (Pr,Ca) Manganites Estimated by Magnetic Transition Entropies

The magnetocaloric applicability of the perovskite-structured (Pr,Ca) manganite family (PCMO) was estimated based on the magnetic transition entropies of polycrystalline bulk samples. Transitions in the temperature range from 5 to 400 K were investigated in external fields up to 5 T. Earlier results published on the matter were reproduced, extended to Ca concentrations below x = 0.2 and up to x = 1, and complemented by determining standardized refrigerant capacity estimates corresponding to the largest entropy changes detected in each sample. The quantitative agreement between the measured transition entropies and literature also served to verify a time-optimized data collection method based on quick temperature scans of magnetization at constant magnetic fields. Making use of the mathematical regularity of magnetization curves, improved time, and cryogen efficiency was arguably attained compared with a more traditional data collection method without significant loss of accuracy. The results of this paper convey a very graphical overview of the quite well established phase diagram of PCMO and promise a significant magnetocaloric effect below 150 K, possibly on par with that exhibited by Gd-based alloys around room temperature. However, little hope can be offered for the room temperature refrigeration applications of PCMO.

Dirty limit scattering behind the decreased anisotropy of doped YBa2Cu3O7-δ thin films

We measured the resistivity of pulsed-laser-deposited BaCeO3 (BCO)-doped YBCO thin films containing spherical BCO particles in fields up to 30 T. The average diameter of the particles depends on the dopant concentration being below 4 nm in all the samples. Raised values of the upper critical field, Bc2, were observed in all the samples. Additionally, the parameter γ, describing the electron mass anisotropy, decreased from 6.2 in the undoped sample to 3.1 in the 8 wt.% BCO-doped sample. These results can be explained by the increased number of defects decreasing the mean free path of electrons and thus lowering the coherence length, which in turn increases Bc2.

Mechanisms of photoinduced magnetization in Pr0.6Ca0.4MnO3 studied above and below charge-ordering transition temperature

We report the effect of photonic field on the electronic and magnetic structure of a low bandwidth manganite [Formula: see text] [Formula: see text]MnO3 (PCMO) thin film. In particular, the present study confirmed a mechanism that was recently proposed to explain how optical excitation can bias or directly activate the metamagnetic transition associated with the colossal magnetoresistance (CMR) effect of PCMO. The transition is characterized by a shift in the dynamic equilibrium between ferromagnetic (FM) and antiferromagnetic clusters, explaining how it can be suddenly triggered by a sufficient external magnetic field. The film was always found to support some population of FM-clusters, the proportional size of which could be adjusted by the magnetic field and, especially in the vicinity of a thermomagnetic irreversibility, by optical excitation. The double exchange mechanism couples the magnetic degrees of freedom of manganites to their electronic structure, which is further coupled to the ion lattice via the Jahn-Teller mechanism. In accordance, it was found that producing optical phonons into the lattice could lower the free energy of the FM phase enough to significantly bias the CMR effect.