Jacob J. Keizer

Influence of burning intensity on water repellency and hydrological processes at forest and shrub sites in Portugal

In addition to the incineration of vegetation and litter layer, fires are also responsible for the formation of a water repellent layer with significantly different severity and spatial distribution patterns following different burning intensities. Those spatial distribution patterns have an enormous influence on soil wetting patterns, and on hydrological processes at different scales. This study attempts to understand the role of water repellence severity and spatial distribution patterns on soil, slope, and catchment water processes, and on the transmission of hydrological processes between different scales. The comparison between microplot (0.24 m2), plot (16 m2), and catchment (<1.2 km2) scales shows that water repellence spatial homogeneity enhances water fluxes transfer between the different scales. In fact, the more intense the fires, the more severe and spatially uniform the soil water repellency became. For burned areas with heterogeneous soil water repellency, overland flow produced in water repellent patches infiltrated downslope at hydrophilic sites, thereby reducing superficial water fluxes at wider scales. For the more severe and homogeneous water repellent areas following forest wildfires, overland flow was enhanced downslope, increasing fast superficial water fluxes at wider scales.

Competitive sorption of metals in water repellent soils: Implications for irrigation recycled water

Australia is a water-stressed nation and demand on potable water supply is increasing. Consequently water conservation and reuse are increasingly becoming important. Irrigation of recycled wastewater on water repellent soils is a technology that is being trialled as a means of improving crop production and conserving potable supply. However, recycled water contains potentially harmful heavy metals. This paper reports the competitive sorption and desorption of several common heavy metals found in soils collected from a farm located in the south-east of South Australia. The soil from this location is severely water repellent, but some sites were amended with kaolinite clay (Si4Al4O10(OH)8) about 7 and 15 years ago. The metals studied were Cu, Pb, Cd, Cr, Ni, and Zn. Competitive sorption of the metals was distinctly observed. For all heavy metals, the quantity of metal sorbed was higher in amended soil, and there was a strong correlation between the specific sorption to total sorption ratio and the amount of clay in the soil. The sorption intensities varied with metal, Cr, Pb, and Cu having a high sorption tendencies and Zn, Cd, and Ni having comparatively low sorption tendencies. The total sorption capacity for all metals increased in clay-treated soils compared with non-treated soils. On average, clay-amended water repellent soils had a 20–40% increased capacity to adsorb total metals; however, this increase was largely caused by the increased capacities to adsorb Zn, Cd, and Ni. The effect of clay treatment largely enhanced the sorption capacity of relatively weakly adsorbing heavy metals. The implications for using recycled wastewater on the long-term sustainable agro-environmental management of these soils are discussed.