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James C. Bohling

University of Utah

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Journal of Organometallic Chemistry | 2002

Syntheses and structures of monoplatinum model complexes for diplatinum polyynediyl adducts LnPt(CC)zPtLn

Thomas B. Peters; Qinglin Zheng; Jürgen Stahl; James C. Bohling; Atta M. Arif; Frank Hampel; J. A. Gladysz

Abstract The CuI-catalyzed reactions of trans-(Ph3P)2PtCl2 with HCCSiMe3 or HCCCCSiMe3 (greater than two equivalents, HNEt2), and trans-(p-tol)(Ph3P)2PtCl (4) or trans-(C6F5)(p-tol3P)2PtCl with HCCCCH, give trans-(Ph3P)2Pt(CCSiMe3)2 (2), trans-(Ph3P)2Pt(CCCCSiMe3)2 (3), trans-(p-tol)(Ph3P)2PtCCCCH (5), and trans-(C6F5)(p-tol3P)2PtCCCCH (7) in 74–81% yields. These compounds are characterized crystallographically, and their physical properties compared. A convenient three-step synthesis of 4 from (COD)PtCl2 is described.

Chemical Communications | 2000

Olefin metatheses in metal coordination spheres: novel trans-spanning bidentate and facially-spanning tridentate macrocyclic phosphine complexes

Eike B. Bauer; Johannes Ruwwe; Jose M. Martín-Alvarez; Thomas B. Peters; James C. Bohling; Frank Hampel; Sławomir Szafert; Tadeusz Lis; J. A. Gladysz

The title reaction is applied to square-planar rhodium and platinum complexes with trans PPh2(CH2)6CHCH2 ligands, and square-planar platinum or octahedral tungsten complexes with trans or facial PPh[(CH2)6CHCH2]2 ligands. Ring-closing (poly)macrocyclizations occur.

Chemistry: A European Journal | 2006

A Synthetic Breakthrough into an Unanticipated Stability Regime: A Series of Isolable Complexes in which C6, C8, C10, C12, C16, C20, C24, and C28 Polyynediyl Chains Span Two Platinum Atoms

Qinglin Zheng; James C. Bohling; Thomas B. Peters; Anja C. Frisch; Frank Hampel; J. A. Gladysz

Angewandte Chemie | 2002

Sp carbon chains surrounded by sp3 carbon double helices: a class of molecules that are accessible by self-assembly and models for "insulated" molecular-scale devices.

Jürgen Stahl; James C. Bohling; Eike B. Bauer; Thomas B. Peters; Wolfgang Mohr; Jose M. Martín-Alvarez; Frank Hampel; J. A. Gladysz

Journal of the American Chemical Society | 2007

sp Carbon Chains Surrounded by sp3 Carbon Double Helices: Coordination-Driven Self-Assembly of Wirelike Pt(C⋮C)nPt Moieties That Are Spanned by Two P(CH2)mP Linkages

Jürgen Stahl; Wolfgang Mohr; Laura de Quadras; Thomas B. Peters; James C. Bohling; Jose M. Martín-Alvarez; Gareth R. Owen; Frank Hampel; J. A. Gladysz

Angewandte Chemie | 2002

sp Carbon Chains Surrounded by sp3 Carbon Double Helices: A Class of Molecules that are Accessible by Self-Assembly and Models for “Insulated” Molecular-Scale Devices We thank the Deutsche Forschungsgemeinschaft (SFB 583), Johnson Matthey PMC (platinum loan), the Spanish Ministerio de Educación y Ciencia, and the Fulbright Commission (Fellowships, J.M.M.-A.) for support, and Dr. A. M. Arif for assistance with the analysis of one crystal structure.

Jürgen Stahl; James C. Bohling; Eike B. Bauer; Thomas B. Peters; Wolfgang Mohr; Jose M. Martín-Alvarez; Frank Hampel; J. A. Gladysz

Organometallics | 1999

C8 and C12 sp Carbon Chains That Span Two Platinum Atoms: The First Structurally Characterized 1,3,5,7,9,11-Hexayne

Thomas B. Peters; James C. Bohling; and Atta M. Arif; J. A. Gladysz

Angewandte Chemie | 2002

Von sp3-Kohlenstoff-Helices umgebene sp-Kohlenstoffketten: eine Klasse von Molekülen, die durch Selbstorganisation zugänglich und Modellverbindungen für „isolierte“ molekulare Bauelemente sind

Jürgen Stahl; James C. Bohling; Eike B. Bauer; Thomas B. Peters; Wolfgang Mohr; Jose M. Martín-Alvarez; Frank Hampel; J. A. Gladysz

Pure and Applied Chemistry | 2008

En route to diplatinum polyynediyl complexes trans,trans -(Ar)(R 3 P) 2 Pt(C≡C) n Pt(PR 3 ) 2 (Ar): Untold tales, including end-group strategies

Jürgen Stahl; James C. Bohling; Thomas B. Peters; Laura de Quadras; J. A. Gladysz

Angewandte Chemie | 2002

Von sp3-Kohlenstoff-Helices umgebene sp-Kohlenstoffketten: eine Klasse von Molekülen, die durch Selbstorganisation zugänglich und Modellverbindungen für „isolierte“ molekulare Bauelemente sind Wir danken der Deutschen Forschungsgemeinschaft (SFB 583), Johnson Matthey PMC (Platin-Spende), dem Ministerio de Educación y Ciencia und der Fulbright Commission (Stipendien, J.M.M.-A.) für finanzielle Unterstützung und Dr. A. M. Arif für die Mithilfe bei einer Kristallstrukturanalyse.

Jürgen Stahl; James C. Bohling; Eike B. Bauer; Thomas B. Peters; Wolfgang Mohr; Jose M. Martín-Alvarez; Frank Hampel; J. A. Gladysz

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J. A. Gladysz

Texas A

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Thomas B. Peters

University of Utah

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Frank Hampel

University of Erlangen-Nuremberg

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Jürgen Stahl

University of Erlangen-Nuremberg

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Wolfgang Mohr

University of Erlangen-Nuremberg

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Jose M. Martín-Alvarez

University of Valladolid

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Eike B. Bauer

University of Erlangen-Nuremberg

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Qinglin Zheng

University of Erlangen-Nuremberg

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Atta M. Arif

University of Utah

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Anja C. Frisch

University of Erlangen-Nuremberg

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