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James H. Jensen

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Archive | 1984

The Mechanism of the Oscillating Air Oxidation of Benzaldehyde

James H. Jensen; Mark G. Roelofs; E. Wasserman

During the oxygen or air oxidation of benzaldehyde catalyzed by cobalt and bromide several measureable parameters oscillate including: redox potential, absorbance at 620 nm, oxygen concentration, rate of benzaldehyde disappearance and free radical concentration. At 55–100°C in a 90/10 acetic acid/water mixture the oscillations will last for many hours[1]. A typical cycle is shown in Figure 1.

Journal of the American Chemical Society | 1983

New type of oscillating reaction: air oxidation of benzaldehyde

James H. Jensen

Journal of the American Chemical Society | 1966

Catalysis of α-Hydrogen Exchange. II. Isobutyraldehyde-2-d Exchange via N-Methyliminium Ion Formation1

Jack Hine; B. C. Menon; James H. Jensen; Julien Mulders

Journal of the American Chemical Society | 1965

CATALYSIS OF

Jack Hine; James G. Houston; James H. Jensen; Julien Mulders

Journal of the American Chemical Society | 1983

alpha

Mark G. Roelofs; E. Wasserman; James H. Jensen; Allan E. Nader

Journal of the American Chemical Society | 1987

-HYDROGEN EXCHANGE. I. THE REACTION OF ISOBUTYRALDEHYDE-2-d WITH TERTIARY AMINES AND OXYGEN BASES

Mark G. Roelofs; E. Wasserman; James H. Jensen

Journal of Organic Chemistry | 1965

Mechanism of an oscillating organic reaction: oxidation of benzaldehyde with oxygen catalyzed by cobalt/bromine

Jack Hine; James G. Houston; James H. Jensen

Journal of the American Chemical Society | 1971

Oscillations and complex mechanisms: O2 oxidation of benzaldehyde

Jack Hine; Michael S. Cholod; James H. Jensen

Journal of Organic Chemistry | 1971

Hydration, Hydrate Acidity, and Aldolization of Isobutyraldehyde1a

Jack Hine; Francis A. Via; James H. Jensen

Journal of the American Chemical Society | 1973

Bifunctional catalysis of the dedeuteration of acetone-d6 by 3-dimethylaminopropylamine and 2-(dimethylaminomethyl)cyclopentylamines

Jack Hine; Jesse L. Lynn; James H. Jensen; Frank C. Schmalstieg

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Jack Hine

Ohio State University

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Mark G. Roelofs

Stanford University

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