James M. Burlitch
Massachusetts Institute of Technology
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Featured researches published by James M. Burlitch.
Journal of Organometallic Chemistry | 1965
Dietmar Seyferth; James M. Burlitch
Abstract Detailed procedures for the preparation of C 6 H 5 HgCCl 3 , C 6 H 5 HgCCl 2 Br, C 6 H 5 HgCClBr 2 and C 6 H 5 HgCBr 3 by the Reutov-Lovtsova method are given. Evidence is presented which indicates that the reaction of phenylmercuric halide, haloform and potassium tert -butoxide forms C 6 H 5 HgCX 3 by way of nucleophilic displacement of halide ions from mercury by the trihalomethyl anion.
Journal of Organometallic Chemistry | 1967
Dietmar Seyferth; James M. Burlitch; Hadwig Dertouzos; Harry D. Simmons
Abstract The reaction of phenyl(trihalomethyl)mercury compounds, C6H5HgCX2Br (X=Cl and Br), with organosilicon and organogermanium hydrides in benzene at 80° results in insertion of CCl2 and CBr2, respectively, into the Si—H and Ge—H bonds to give Si—CX2H and Ge—CX2H compounds. Triethylgermane was found to be four times more reactive than triethylsilane, and triethylsilane was 0.8 times as reactivate as cyclohexene. Evidence was obtained which suggest that dihalocarbenes (free or complexed) are involved as intermediates in these reactions. Tri-n-butyltin hydride reduced the C-Br bond of C6H5HgCX2Br mercurials, and C6H5HgCCl2H, C6H5HgCClBrH and C6H5HgCBr2H were prepared and characterized. However, this is not a practical preparative route to these mercurials.
Journal of the American Chemical Society | 1965
Dietmar Seyferth; James M. Burlitch; Richard J. Minasz; Jeffrey Yick-Pui. Mui; Harry D. Simmons; Arno J. H. Treiber; Susan R. Dowd
Journal of the American Chemical Society | 1967
Dietmar Seyferth; Michael E. Gordon; Jeffrey Yick-Pui. Mui; James M. Burlitch
Journal of the American Chemical Society | 1965
Dietmar Seyferth; Jeffrey Yick-Pui. Mui; Michael E. Gordon; James M. Burlitch
Journal of the American Chemical Society | 1963
Dietmar Seyferth; James M. Burlitch
Journal of the American Chemical Society | 1967
Dietmar Seyferth; Jeffrey Yick-Pui. Mui; James M. Burlitch
Journal of Organic Chemistry | 1962
Dietmar Seyferth; James M. Burlitch; James K. Heeren
Journal of the American Chemical Society | 1969
James M. Burlitch
Journal of the American Chemical Society | 1967
Byungkook. Lee; James M. Burlitch; James L. Hoard