Jamie Gengler

The permanent electric dipole moments of calcium monohydride, CaH.

Numerous branch features in the (0,0) A 2Pi-X 2Sigma+ band system of calcium monohydride CaH have been studied by optical Stark spectroscopy. The Stark shifts, Stark splittings, and appearance of electric-field-induced transitions in the high resolution laser-induced fluorescence spectra are analyzed to produce values for the magnitude of the permanent electric dipole moments mid R:micromid R: of 2.94(16) D and 2.372(12) D for the X 2Sigma+(v=0) and A 2Pi(v=0) states, respectively. A comparison with values predicted from a semiempirical electrostatic model and previous ab initio calculations for mid R:micromid R: (X 2Sigma+) is presented. The change in mid R:micromid R: upon excitation from the X 2Sigma+ state to the A 2Pi state is rationalized using a simple molecular orbital description.

Molecular beam optical Stark study of rhodium mononitride

The optical Stark effect in the Q(1) and R(0) lines of the [15.1]1-X (1)Sigma+ (1,0) band of rhodium mononitride (RhN) were recorded and analyzed to determine the permanent electric dipole moments mu for the X (1)Sigma+(upsilon=0) and [15.1]1(upsilon=1) states to be 2.43(5) and 1.75(1) D, respectively. The determined dipole moments are compared to predicted values obtained from density functional theory [Stevens et al., Chem. Phys. Lett. 421, 281 (2006)] and an all-electron ab initio calculation [Shim et al., J. Mol. Struct. THEOCHEM 393, 127 (1997)]. A simple single configuration molecular orbital correlation diagram is used to rationalize the relative values of mu for the 4d mononitrides and RhO. An electronic configuration for the [15.1]1 state is proposed based on the interpretation of the (103)Rh and (14)N magnetic hyperfine interactions.

A molecular beam optical Stark study of the [15.8] and [16.0] Π1∕22-XΣ−4 (0,0) band systems of rhodium monoxide, RhO

The R11S(0) and R11S(1) branch features of the [15.8] and [16.0]Π1∕22-XΣ−4 (0,0) subband systems of rhodium monoxide, RhO, have been studied at near the natural linewidth limit of resolution by optical Stark spectroscopy using laser induced fluorescence detection. The Stark shifts and splittings were analyzed to produce the magnitude of the permanent electric dipole moment, ∣μ∣, of 3.81(2)D for the XΣ3∕2−4 (v=0) state. The results are compared to density functional theory calculations. Trends in observed values of ∣μ∣ across the 4d series of transition metal monoxides are interpreted in terms of simple single configuration molecular orbital correlation diagrams.

The Zeeman effect in the (0,0) band of the A Π7−X Σ7+ transition of manganese monohydride, MnH

The Zeeman tuning of the P(1)(0) line (nu=17 568.35 cm(-1)) of the A (7)Pi-X (7)Sigma(+) (0,0) band of manganese monohydride, MnH, has been investigated. The laser induced fluorescence spectrum of a supersonic molecular beam sample was recorded at a resolution of approximately 40 MHz and with field strengths of up to 362.0 mT. The observed spectrum was successfully fitted using a traditional effective Zeeman Hamiltonian to determine an effective magnetic g-factor for the J=2 level of the F(1)-spin component of the A (7)Pi(v=0) state. Spectral predictions of the P(1)(0) line at field strengths used in magnetic trapping experiments are presented.