Jan Cami

Detection of C60 and C70 in a Young Planetary Nebula

Cosmic Fullerenes Since the discovery of the buckminsterfullerene C60 in laboratory experiments, it has been speculated that fullerenes could form abundantly in carbon-rich evolved stars and, because of their stability, survive the harsh radiation field in the interstellar medium as a gas-phase species. Cami et al. (p. 1180; published online 22 July; see the Perspective by Ehrenfreund and Foing) have detected large amounts of fullerenes in a peculiar planetary nebula with an extremely hydrogen-poor dust formation zone. Contrary to expectations, the fullerenes are not gaseous; they are cool, are in a neutral charge state, and represent about 1.5% of the available carbon. Hydrogen-poor conditions allow fullerenes to form in space. In recent decades, a number of molecules and diverse dust features have been identified by astronomical observations in various environments. Most of the dust that determines the physical and chemical characteristics of the interstellar medium is formed in the outflows of asymptotic giant branch stars and is further processed when these objects become planetary nebulae. We studied the environment of Tc 1, a peculiar planetary nebula whose infrared spectrum shows emission from cold and neutral C60 and C70. The two molecules amount to a few percent of the available cosmic carbon in this region. This finding indicates that if the conditions are right, fullerenes can and do form efficiently in space.

THE NASA AMES POLYCYCLIC AROMATIC HYDROCARBON INFRARED SPECTROSCOPIC DATABASE: THE COMPUTED SPECTRA

The astronomical emission features, formerly known as the unidentified infrared bands, are now commonly ascribed to polycyclic aromatic hydrocarbons (PAHs). The laboratory experiments and computational modeling done at the NASA Ames Research Center to create a collection of PAH IR spectra relevant to test and refine the PAH hypothesis have been assembled into a spectroscopic database. This database now contains over 800 PAH spectra spanning 2-2000 μm (5000-5 cm–1). These data are now available on the World Wide Web at www.astrochem.org/pahdb. This paper presents an overview of the computational spectra in the database and the tools developed to analyze and interpret astronomical spectra using the database. A description of the online and offline user tools available on the Web site is also presented.

The dust condensation sequence in red supergiant stars

Context. Red supergiant (RSG) stars exhibit significant mass loss by means of a slow, dense wind. They are often considered to be the more massive counterparts of Asymptotic Giant Branch (AGB) stars. While AGB mass loss is related to their strong pulsations, the RSG are often only weakly variable. This raises the question of whether their wind-driving mechanism and the dust composition of the wind are the same. Aims. We study the conditions at the base of the wind by determining the dust composition of a sample of RSG. The dust composition is assumed to be sensitive to the density, temperature, and acceleration at the base of the wind. We compare the derived dust composition with the composition measured in AGB star winds. Methods. We compile a sample of 27 RSG infrared spectra (ISO-SWS) and supplement these with photometric measurements to derive the full spectral energy distribution (SED). These data are modelled using a dust radiative-transfer code, taking into account the optical properties of the relevant candidate materials to search for correlations between mass-loss rate, density at the inner edge of the dust shell, and stellar parameters. Results. We find strong correlations between the dust composition, mass-loss rate, and the stellar luminosity, roughly in agreement with the theoretical dust condensation sequence. We identify the need for a continuous (near-)IR dust opacity and tentatively propose amorphous carbon, and we note significant differences with AGB star winds in terms of the presence of PAHs, absence of “the” 13 μm band, and a lack of strong water bands. Conclusions. Dust condensation in RSG is found to experience a freeze-out process that is similar to that in AGB stars. Together with the positive effect of the stellar luminosity on the mass-loss rate, this suggests that radiation pressure on dust grains is an important ingredient in the driving mechanism. Still, differences with AGB stars are manifold and thus the winds of RSG should be studied individually in further detail.

THE NASA AMES PAH IR SPECTROSCOPIC DATABASE VERSION 2.00: UPDATED CONTENT, WEB SITE, AND ON(OFF)LINE TOOLS

A significantly updated version of the NASA Ames PAH IR Spectroscopic Database, the first major revision since its release in 2010, is presented. The current version, version 2.00, contains 700 computational and 75 experimental spectra compared, respectively, with 583 and 60 in the initial release. The spectra span the 2.5-4000 μm (4000-2.5 cm-1) range. New tools are available on the site that allow one to analyze spectra in the database and compare them with imported astronomical spectra as well as a suite of IDL object classes (a collection of programs utilizing IDLs object-oriented programming capabilities) that permit offline analysis called the AmesPAHdbIDLSuite. Most noteworthy among the additions are the extension of the computational spectroscopic database to include a number of significantly larger polycyclic aromatic hydrocarbons (PAHs), the ability to visualize the molecular atomic motions corresponding to each vibrational mode, and a new tool that allows one to perform a non-negative least-squares fit of an imported astronomical spectrum with PAH spectra in the computational database. Finally, a methodology is described in the Appendix, and implemented using the AmesPAHdbIDLSuite, that allows the user to enforce charge balance during the fitting procedure.

The close circumstellar environment of Betelgeuse. Adaptive optics spectro-imaging in the near-IR with VLT/NACO

Context. Betelgeuse is one the largest stars in the sky in terms of angular diameter. Structures on the stellar photosphere have been detected in the visible and near-infrared as well as a compact molecular environment called the MOLsphere. Mid-infrared observations have revealed the nature of some of the molecules in the MOLsphere, some being the precursor of dust. Aims. Betelgeuse is an excellent candidate to understand the process of mass loss in red supergiants. Using diffraction-limited adaptive optics (AO) in the near-infrared, we probe the photosphere and close environment of Betelgeuse to study the wavelength dependence of its extension, and to search for asymmetries. Methods. We obtained AO images with the VLT/NACO instrument, taking advantage of the “cube” mode of the CONICA camera to record separately a large number of short-exposure frames. This allowed us to adopt a “lucky imaging” approach for the data reduction, and obtain diffraction-limited images over the spectral range 1.04−2.17 μm in 10 narrow-band filters. Results. In all filters, the photosphere of Betelgeuse appears partly resolved. We identify an asymmetric envelope around the star, with in particular a relatively bright “plume” extending in the southwestern quadrant up to a radius of approximately six times the photosphere. The CN molecule provides an excellent match to the 1.09 μm bandhead in absorption in front of the stellar photosphere, but the emission spectrum of the plume is more difficult to interpret. Conclusions. Our AO images show that the envelope surrounding Betelgeuse has a complex and irregular structure. We propose that the southwestern plume is linked either to the presence of a convective hot spot on the photosphere, or to the rotation of the star.

ON THE EXCITATION AND FORMATION OF CIRCUMSTELLAR FULLERENES

We compare and analyze the Spitzer mid-infrared spectrum of three fullerene-rich planetary nebulae in the Milky Way and the Magellanic Clouds: Tc1, SMP SMC 16, and SMP LMC 56. The three planetary nebulae share many spectroscopic similarities. The strongest circumstellar emission bands correspond to the infrared active vibrational modes of the fullerene species C60 and little or no emission is present from polycyclic aromatic hydrocarbons. The strengths of the fullerene bands in the three planetary nebulae are very similar, while the ratios of the [Ne III]15.5 μm/[Ne II]12.8 μm fine structure lines, an indicator of the strength of the radiation field, are markedly different. This raises questions about their excitation mechanism and we compare the fullerene emission to fluorescent and thermal models. In addition, the spectra show other interesting and common features, most notably in the 6-9 μm region, where a broad plateau with substructure dominates the emission. These features have previously been associated with mixtures of aromatic/aliphatic hydrocarbon solids. We hypothesize on the origin of this band, which is likely related to the fullerene formation mechanism, and compare it with modeled hydrogenated amorphous carbon that present emission in this region.

Carbonaceous molecules in the oxygen-rich circumstellar environment of binary post-AGB stars - C60 fullerenes and polycyclic aromatic hydrocarbons

Context. The circumstellar environment of evolved stars is generally rich in molecular gas and dust. Typically, the entire environment is either oxygen-rich or carbon-rich, depending on the evolution of the central star. Aims. In this paper we discuss three evolved disc sources with evidence of atypical emission lines in their infrared spectra. The stars were taken from a larger sample of post-AGB binaries for which we have Spitzer infrared spectra, characterised by the presence of a stable oxygen-rich circumbinary disc. Our previous studies have shown that the infrared spectra of post-AGB disc sources are dominated by silicate dust emission, often with an extremely high crystallinity fraction. However, the three sources described here are selected because they show a peculiar molecular chemistry. Methods. Using Spitzer infrared spectroscopy, we study in detail the peculiar mineralogy of the three sample stars. Using the observed emission features, we identify the different observed dust, molecular and gas species. Results. The infrared spectra show emission features due to various oxygen-rich dust components, as well as CO2 gas. All three sources show the strong infrared bands generally ascribed to polycyclic aromatic hydrocarbons. Furthermore, two sample sources show C60 fullerene bands. Conclusions. Even though the majority of post-AGB disc sources are dominated by silicate dust in their circumstellar environment, we do find evidence that, for some sources at least, additional processing must occur to explain the presence of large carbonaceous molecules. There is evidence that some of these sources are still oxygen-rich, which makes the detection of these molecules even more surprising.

The close circumstellar environment of Betelgeuse II. Diffraction-limited spectro-imaging from 7.76 to 19.50 m with VLT/VISIR ?

Context. Mass-loss occurring in red supergiants (RSGs) is a major contributor to the enrichment of the interstellar medium in dust and molecules. The physical mechanism of this mass loss is however relatively poorly known. Betelgeuse is the nearest RSG, and as such a prime object for high angular resolution observations of its surface (by interferometry) and close circumstellar environment. Aims. The goal of our program is to understand how the material expelled from Betelgeuse is transported from its surface to the interstellar medium, and how it evolves chemically in this process. Methods. We obtained di raction-limited images of Betelgeuse and a calibrator (Aldebaran) in six filters in the N band (7.76 to 12.81 m) and two filters in the Q band (17.65 and 19.50 m), using the VLT/VISIR instrument. Results. Our images show a bright, extended and complex circumstellar envelope at all wavelengths. It is particularly prominent longwards of 9-10 m, pointing at the presence of O-rich dust, such as silicates or alumina. A partial circular shell is observed between 0.5 and 1.0 00 from the star, and could correspond to the inner radius of the dust envelope. Several knots and filamentary structures are identified in the nebula. One of the knots, located at a distance of 0:9 00 west of the star, is particularly bright and compact. Conclusions. The circumstellar envelope around Betelgeuse extends at least up to several tens of stellar radii. Its relatively high degree of clumpiness indicates an inhomogeneous spatial distribution of the material lost by the star. Its extension corresponds to an important intermediate scale, where most of the dust is probably formed, between the hot and compact gaseous envelope observed previously in the near infrared and the interstellar medium.

Cosmic Carbon Chemistry: From the Interstellar Medium to the Early Earth

Astronomical observations have shown that carbonaceous compounds in the gas and solid state, refractory and icy are ubiquitous in our and distant galaxies. Interstellar molecular clouds and circumstellar envelopes are factories of complex molecular synthesis. A surprisingly large number of molecules that are used in contemporary biochemistry on Earth are found in the interstellar medium, planetary atmospheres and surfaces, comets, asteroids and meteorites, and interplanetary dust particles. In this article we review the current knowledge of abundant organic material in different space environments and investigate the connection between presolar and solar system material, based on observations of interstellar dust and gas, cometary volatiles, simulation experiments, and the analysis of extraterrestrial matter. Current challenges in astrochemistry are discussed and future research directions are proposed.

Carbon-rich dust past the asymptotic giant branch: aliphatics, aromatics, and fullerenes in the Magellanic Clouds

Infrared spectra of carbon-rich objects that have evolved off the asymptotic giant branch reveal a range of dust properties, including fullerenes, polycyclic aromatic hydrocarbons (PAHs), aliphatic hydrocarbons, and several unidentified features, including the 21 μm emission feature. To test for the presence of fullerenes, we used the position and width of the feature at 18.7-18.9 μm and examined other features at 17.4 and 6-9 μm. This method adds three new fullerene sources to the known sample, but it also calls into question three previous identifications. We confirm that the strong 11 μm features seen in some sources arise primarily from SiC, which may exist as a coating around carbonaceous cores and result from photo-processing. Spectra showing the 21 μm feature usually show the newly defined Class D PAH profile at 7-9 μm. These spectra exhibit unusual PAH profiles at 11-14 μm, with weak contributions at 12.7 μm, which we define as Class D1, or show features shifted to ~11.4, 12.4, and 13.2 μm, which we define as Class D2. Alkyne hydrocarbons match the 15.8 μm feature associated with 21 μm emission. Sources showing fullerene emission but no PAHs have blue colors in the optical, suggesting a clear line of sight to the central source. Spectra with 21 μm features and Class D2 PAH emission also show photometric evidence for a relatively clear line of sight to the central source. The multiple associations of the 21 μm feature with aliphatic hydrocarbons suggest that the carrier is related to this material in some way.