Jan Hoinkis

Emerging mitigation needs and sustainable options for solving the arsenic problems of rural and isolated urban areas in Latin America : A critical analysis

In this work, current information about the contamination of ground- and surface-water resources by arsenic from geogenic sources in Latin America is presented together with possible emerging mitigation solutions. The problem is of the same order of magnitude as other world regions, such as SE Asia, but it is often not described in English. Despite the studies undertaken by numerous local researchers, and the identification of proven treatment methods for the specific water conditions encountered, no technologies have been commercialized due to a current lack of funding and technical assistance. Emerging, low-cost technologies to mitigate the problem of arsenic in drinking water resources that are suitable for rural and urban areas lacking centralized water supplies have been evaluated. The technologies generally use simple and low-cost equipment that can easily be handled and maintained by the local population. Experiences comprise (i) coagulation/filtration with iron and aluminum salts, scaled-down for small community- and household-scale-applications, (ii) adsorption techniques using low-cost arsenic sorbents, such as geological materials (clays, laterites, soils, limestones), natural organic-based sorbents (natural biomass), and synthetic materials. TiO(2)-heterogeneous photocatalysis and zerovalent iron, especially using nanoscale particles, appear to be promising emergent technologies. Another promising innovative method for rural communities is the use of constructed wetlands using native perennial plants for arsenic rhizofiltration. Small-scale simple reverse osmosis equipment (which can be powered by wind or solar energy) that is suitable for small communities can also be utilized. The individual benefits of the different methods have been evaluated in terms of (i) size of the treatment device, (ii) arsenic concentration and distribution of species, chemical composition and grade of mineralization in the raw water, (iii) guidelines for the remaining As concentration, (iv) economical constrains, (v) complexity of installation and maintenance, and infrastructure constraints (e.g. electricity needs).

Pilot study on arsenic removal from groundwater using a small-scale reverse osmosis system — towards sustainable drinking water production

Arsenic contamination of groundwater is posing a serious challenge to drinking water supplies on a global scale. In India and Bangladesh, arsenic has caused the most serious public health issue in the world for nearly two decades. The aim of this work was to study an arsenic removal system based on reverse osmosis at pilot scale treating two different water sources from two different locations in the State of Bihar, India. For this purpose two villages, Bind Toli and Ramnagar in the Patna District were selected, both located very close to the river Ganga. The trials were conducted with aerated and non-aerated groundwater. It is the first time that the arsenic removal efficiency for aerated and non-aerated groundwater by reverse osmosis technology in combination with an energy-saving recovery system have been studied. As the principle of reverse osmosis requires a relatively high pressure, its energy demand is naturally high. By using an energy recovery system, this demand can be lowered, leading to an energy demand per liter permeate of 3-4Wh/L only. Due to high iron levels in the groundwater and as a consequence the precipitation of ferric (hydr)oxides, it was necessary to develop a granular media filter for the trials under aeration in order to protect the membrane from clogging. Two different materials, first locally available sand, and second commercially available anthracite were tested in the granular media filter. For the trials with aerated groundwater, total arsenic removal efficiency at both locations was around 99% and the arsenic concentration in permeate was in compliance with the WHO and National Indian Standard of 10μg/L. However, trials under anoxic conditions with non-aerated groundwater could not comply with this standard. Additionally a possible safe discharge of the reverse osmosis concentrate into an abandoned well was studied. It was observed that re-injection of reject water underground may offer a safe disposal option. However, long-term hydrogeological studies need to be conducted for confirmation.

Membrane bioreactors for water treatment

Membrane bioreactor (MBR) technology combines the biological degradation process with micro- and ultrafiltration and is widely regarded as an effective tool for water treatment and water reuse owing to its high-quality water product and low footprint. MBR technology–treated water is of high clarity and is significantly reduced in germs so that it is ideally suited for being discharged to sensitive receiving waters such as natural reserve areas or for being reused in a variety of applications such as irrigation or industrial processes. Aerobic MBRs, which make use of the aerobic-activated sludge process, are widely used to treat municipal and industrial wastewater, and a variety of membranes are commercially available. Because of their robustness and flexibility, submerged MBR systems are increasingly preferable. Because of increasing water scarcity, the aerobic MBR market is witnessing strong growth worldwide, particularly in large-scale applications. In addition to aerobic MBRs, anaerobic MBRs (AnMBR) have become the focus of attention in research and development because these systems have the ability to provide biogas for energy production. Membrane fouling and water flux decline are the most important issues in MBR application. In general, membrane fouling problems are more pronounced in AnMBRs; this hampers the widespread application of full-scale reactors. In addition to the common pressure-driven MBRs, the combination of forward osmosis and biological degradation has aroused the interest of researchers in recent years owing to its superior water quality and the fact that no pump energy is needed to drive the membrane separation process. This chapter highlights the fundamentals of MBRs. In addition, areas of application, factors affecting the process, and case studies of aerobic and AnMBR processes for water treatment and reuse in the laundry and food industry are addressed. The case studies demonstrate the technical benefits of MBR technology but also show the economical viability of this technology.

Iron-based subsurface arsenic removal technologies by aeration: A review of the current state and future prospects

Arsenic contamination in groundwater is a critical issue and one that raises great concern around the world as the cause of many negative health impacts on the human body, including internal and external cancers. There are many ways to remove or immobilize arsenic, including membrane technologies, adsorption, sand filtration, ion exchange, and capacitive deionization. These exhibit many different advantages and disadvantages. Among these methods, in-situ subsurface arsenic immobilization by aeration and the subsequent removal of arsenic from the aqueous phase has shown to be very a promising, convenient technology with high treatment efficiency. In contrast to most of other As remediation technologies, in-situ subsurface immobilization offers the advantage of negligible waste production and hence has the potential of being a sustainable treatment option. This paper reviews the application of subsurface arsenic removal (SAR) technologies as well as current modeling approaches. Unlike subsurface iron removal (SIR), which has proven to be technically feasible in a variety of hydrogeochemical settings for many years, SAR is not yet an established solution since it shows vulnerability to diverse geochemical conditions such as pH, Fe:As ratio, and the presence of co-ions. In some situations, this makes it difficult to comply with the stringent guideline value for drinking water recommended by the WHO (10 μg L-1). In order to overcome its limitations, more theoretical and experimental studies are needed to show long-term application achievements and help the development of SAR processes into state-of-the-art technology.

Novel low-fouling membranes from lab to pilot application in textile wastewater treatment

A novel antifouling coating based on the polymerization of a polymerisable bicontinuous microemulsion (PBM) was developed and applied for commercially available membranes for textile wastewater treatment. PBM coating was produced by polymerizing, on a polyethersulfone (PES) membrane, a bicontinuous microemulsion, realized by finely tuning its properties in terms of chemical composition and polymerization temperature. In particular, the PBM was prepared by using, as the surfactant component, inexpensive and commercially available dodecyltrimethylammonium bromide (DTAB). The coating exhibited a more hydrophilic and a smoother surface in comparison to uncoated PES surface, making the produced PBM membranes more resistant and less prone to be affected by fouling. The anti-fouling potential of PBM membranes was assessed by using humic acid (HA) as a model foulant, evaluating the water permeability decrease as an indicator of the fouling propensity of the membranes. PBM membrane performances in terms of dye rejection, when applied for model textile wastewater treatment, were also evaluated and compared to PES commercial ones. The PBM membranes were finally successfully scaled-up (total membrane area 0.33 m2) and applied in a pilot membrane bioreactor (MBR) unit for the treatment of real textile wastewater.

MBR and Integration With Renewable Energy Toward Suitable Autonomous Wastewater Treatment

Abstract Rapid population growth invokes the need for a vast amount of water conservation. Many centralized water treatment systems will reach their limits and face difficulties to provide clean industrial water to rural areas. The infrastructure for water distribution is dilapidated in many regions and only little of the wastewater is currently being recycled. One solution could be the expansion of decentralized membrane bioreactor (MBR) systems in peri-urban areas. MBR achieves excellent water qualities, whereas the comparatively high energy consumption is the main drawback. Therefore, MBR plants need to be optimized in their specific energy consumption to obtain a high degree of self-sufficiency for decentralized locations. There is a dire need for innovative controlling strategies and efficient coupling with energy supply systems through novel applications. This chapter will highlight the basic approaches to reduce the MBRs overall energy consumption and ways to establish sustainable, autonomous operations without sacrificing the process quality.

Solar powered nanofiltration for drinking water production from fluoride-containing groundwater – A pilot study towards developing a sustainable and low-cost treatment plant

The following paper summarizes the findings of a pilot study to develop a simple, low-cost, holistic water concept on fluoride removal from groundwater in rural communities of Tanzania; an ideal representative community for other areas in the world with similar problems. A small photovoltaic powered nanofiltration (NF) pilot plant was installed at a vocational training center in Boma Ng´ombe in northern Tanzania. The groundwater in this region is contaminated with fluoride at very high concentrations of up to 60 mg/L. The pilot plant was equipped with a single membrane module containing a spiral wound 4040 membrane NF90 of Dow Water & Process Solutions and was successfully operated over a nine-month period. The membrane removed more than 98% of fluoride. In fact, the fluoride concentration in the permeate was always less than 1 mg/L, which is in agreement with the WHO recommended standard (1.5 mg/L). Permeate was also used as weekly flush medium, so no chemical cleaning was required. Aside from permeate (drinking water) concentrate was also used for washing and flushing the toilets. In conclusion, the use of solar PV power (2.25 KWP) for approximately 2.5 h per day allowed producing about 240 L/h of permeate on average. Therefore, the sustainability of the process and suitability for the Tanzanian communities was proved.