Jeffrey M. Guevremont

Enhancement of Engine Oil Wear and Friction Control Performance through Titanium Additive Chemistry

Traditionally, wear protection and friction modification by engine oil is provided by zinc dithiophosphate (ZDDP) or other phosphorus compounds. These additives provide effective wear protection and friction control on engine parts through formation of a glassy polyphosphate antiwear film. However, the deposition of phosphorus species on automotive catalytic converters from lubricants has been known for some time to have a detrimental effect of poisoning the catalysts. To mitigate the situation, the industry has been making every effort to find ZDDP-replacement additives that are friendly to catalysts. Toward this goal we have investigated a titanium additive chemistry as a ZDDP replacement. Fully formulated engine oils incorporating this additive component have been found to be effective in reducing wear and controlling friction in a high-frequency reciprocating rig (HFRR), 4-ball bench wear, Sequence IIIG, and Sequence IVA engine tests. Surface analysis of the tested parts by Auger electron spectroscopy, secondary ion mass spectrometry (SIMS), and X-ray photoelectron spectroscopy (XPS) have shown that Ti species have been incorporated into the wear tracks and can only be found on the wear tracks. We used synchrotron based near edge X-ray absorption fine structure (NEXAFS) to investigate the chemical bonding mechanism of the Ti additive with the metal surface that affects the wear improvement mechanism. We postulate that Ti provides antiwear enhancement through inclusion in the metal/metal oxide structure of the ferrous surface by forming FeTiO3.

An Investigation of Hydraulic Motor Efficiency and Tribological Surface Properties

Hydraulic motor efficiency does not depend upon viscosity alone. Under low-speed, high-torque conditions, hydraulic motors operate in the boundary regime and, therefore, surface interactions of lubricant additives can affect friction and efficiency. This article presents an investigation of boundary film formation, friction, and surface topography in benchtop tribometers and hydraulic motors. Fluids investigated included those with varied antiwear packages (zinc dialkyldithiophosphate [ZDDP], ashless) and friction modifiers (with and without) and base oil (Group I, Group III). The mechanical efficiencies of geroler, axial piston, bent-axis, and radial piston motors were measured under low-speed, high-torque conditions. The addition of a friction modifier to an ashless hydraulic fluid increased the efficiency of the motors at low speed. Energy-dispersive X-ray spectroscopy (EDX) analysis of motor surfaces after testing revealed the presence of tribochemical films from the hydraulic fluid additives. In benchtop tribometer testing, the friction modifier reduced friction significantly but also increased wear. This could be related to surface competition of the friction modifier and antiwear chemistries, as evidenced by the reduced concentration of phosphorus on the surface. These findings are significant because they provide insights toward the development of fluids that can enhance motor efficiency but also demonstrates the need for a well-balanced additive package so that improved motor efficiency can be achieved without affecting other important properties of the fluid.

Effects of Gear Oil Properties on Pitting Life in Rolling Four-Ball Test Configuration

There is a connection between the efficiency of oils and their wear and/or surface damage protective properties, an area not so well described in the literature. One such damage mode is macroscale contact fatigue on gear tooth flank surfaces, also called pitting. The present study is aimed at investigating the correlation between gear oils’ physical properties, important in terms of gear transmission losses, and pitting life. Eight gear oils were formulated giving different combinations of base oil, viscosity, and concentration of friction modifiers. All eight oils also contained an additive package designed to meet GL-5 specifications. This study consists of three parts. In the first, the oils’ physical properties were measured using a set of bench tests. In the second, the pitting lives of the oils were evaluated using rolling four-ball tests. The third part deals with the correlation between the measured physical properties of the oils and their pitting lives. This is achieved through multiple linear regression, with a view to finding the salient properties that have a significant influence on pitting life. The results show that gear oils’ physical properties do have a large influence on the pitting lives. Oil properties that lower interfacial tangential stresses are beneficial in enhancing pitting life.

Tribological Film Formation in Hydraulic Motors

This paper presents an investigation of the tribological films formed in hydraulic motors. Hydraulic motors convert the fluid power energy produced by positive displacement pumps into rotary motion. Earlier research found that the efficiency of this energy transformation can be enhanced by reducing boundary friction. In order to study the nature of the boundary films formed in an orbital motor, a prototype ashless hydraulic fluid was evaluated in a low-speed high-torque dynamometer. The resulting tribofilm was probed via Energy Dispersive X-Ray Spectroscopy. The results reveal that increasing the hydraulic system temperature raised the relative phosphorus level of the tribofilm.Copyright