Jennifer L. Schaefer
Cornell University
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Publication
Featured researches published by Jennifer L. Schaefer.
Advanced Materials | 2014
Samanvaya Srivastava; Jennifer L. Schaefer; Zichao Yang; Zhengyuan Tu; Lynden A. Archer
Polymer-particle composites are used in virtually every field of technology. When the particles approach nanometer dimensions, large interfacial regions are created. In favorable situations, the spatial distribution of these interfaces can be controlled to create new hybrid materials with physical and transport properties inaccessible in their constituents or poorly prepared mixtures. This review surveys progress in the last decade in understanding phase behavior, structure, and properties of nanoparticle-polymer composites. The review takes a decidedly polymers perspective and explores how physical and chemical approaches may be employed to create hybrids with controlled distribution of particles. Applications are studied in two contexts of contemporary interest: battery electrolytes and electrodes. In the former, the role of dispersed and aggregated particles on ion-transport is considered. In the latter, the polymer is employed in such small quantities that it has been historically given titles such as binder and carbon precursor that underscore its perceived secondary role. Considering the myriad functions the binder plays in an electrode, it is surprising that highly filled composites have not received more attention. Opportunities in this and related areas are highlighted where recent advances in synthesis and polymer science are inspiring new approaches, and where newcomers to the field could make important contributions.
Journal of Materials Chemistry | 2012
Yingying Lu; Surya S. Moganty; Jennifer L. Schaefer; Lynden A. Archer
This publication was based on work supported in part by Award No. KUS-C1-018-02, made by King Abdullah University of Science and Technology (KAUST) and by the National Science Foundation, Award No. DMR-1006323. Facilities available through the Cornell Center for Materials Research(CCMR),National Science Foundation Award No. DMR-1120296, were also used for this study.
Applied Nanoscience | 2012
Jennifer L. Schaefer; Yingying Lu; Surya S. Moganty; Praveen Agarwal; N. Jayaprakash; Lynden A. Archer
From aqueous liquid electrolytes for lithium–air cells to ionic liquid electrolytes that permit continuous, high-rate cycling of secondary batteries comprising metallic lithium anodes, we show that many of the key impediments to progress in developing next-generation batteries with high specific energies can be overcome with cleaver designs of the electrolyte. When these designs are coupled with as cleverly engineered electrode configurations that control chemical interactions between the electrolyte and electrode or by simple additives-based schemes for manipulating physical contact between the electrolyte and electrode, we further show that rechargeable battery configurations can be facilely designed to achieve desirable safety, energy density and cycling performance.
Journal of Materials Chemistry | 2011
Jennifer L. Schaefer; Surya S. Moganty; Dennis A. Yanga; Lynden A. Archer
This work was supported by Award No. KUS-C1-018-02, made by King Abdullah University of Science and Technology (KAUST), and by the National Science Foundation, Award No. DMR-1006323. JLN also acknowledges support from the Materials for a Sustainable Future IGERT program, NSF grant # DGE-0903653.
Langmuir | 2017
Laura C. Merrill; Jennifer L. Schaefer
Magnesium batteries are a promising alternative to lithium-ion batteries due to the widespread abundance of magnesium and its high specific volumetric energy capacity. Ethereal solvents such as tetrahydrofuran (THF) are commonly used for magnesium-ion electrolytes due to their chemical compatibility with magnesium metal, but the volatile nature of THF is a concern for practical application. Herein, we investigate magnesium bis(hexamethyldisilazide) plus aluminum chloride (Mg(HMDS)2-AlCl3) electrolytes in THF, diglyme, and tetraglyme at varying temperature. We find that, despite the higher thermal stability of the glyme-based electrolytes, THF-based electrolytes have better reversibility at room temperature. Deposition/stripping efficiency is found to be a strong function of temperature. Diglyme-based Mg(HMDS)2-AlCl3 electrolytes are found to not exchange as quickly as THF and tetraglyme, stabilizing AlCl2+ and facilitating undesired aluminum deposition. Raman spectroscopy, 27Al NMR, and mass spectrometry are used to identify solution speciation.
Microscopy and Microanalysis | 2015
Vladimir P. Oleshko; Andrew A. Herzing; Jenny Kim; Jennifer L. Schaefer; Christopher L. Soles; Jared J. Griebel; Woo Jin Chung; Adam G. Simmonds; Jeffrey Pyun
Li-S rechargeable batteries are considered to be a promising light-weight, low-cost, and environmentally friendly candidate for next generation energy storage owing to high theoretical specific capacity of 1,672 mAh/g and high specific energy of 2,567 Wh/kg, which is 5 times that of current Li-ion technology. However, practical use of Li-S batteries remains limited because they suffer from gradual capacity fading caused by insulating properties of sulfur and polysulfide shuttle. Recently, poly(sulfur-random-(1,3diisopropenylbenzene) (poly(S-r-DIB)) copolymers have been introduced for their use as active materials in cathodes for Li-S batteries, and were found to be capable of realizing enhanced capacity retention (1005 mAh/g at 100 cycles) and a five-fold increase in lifetime (over 500 cycles) as compared to conventional sulfur-carbon cathodes [1, 2]. These materials are typically organized in a rough hierarchical 3D architecture which contains multiple components and is quite challenging to understand and characterize.
Journal of the American Chemical Society | 2014
Rachna Khurana; Jennifer L. Schaefer; Lynden A. Archer; Geoffrey W. Coates
Chemistry of Materials | 2013
Jennifer L. Schaefer; Dennis A. Yanga; Lynden A. Archer
Chemistry of Materials | 2012
Surya S. Moganty; Samanvaya Srivastava; Yingying Lu; Jennifer L. Schaefer; Salmaan A. Rizvi; Lynden A. Archer
MRS Communications | 2015
Vladimir P. Oleshko; Jenny Kim; Jennifer L. Schaefer; Steven D. Hudson; Christopher L. Soles; Adam G. Simmonds; Jared J. Griebel; Richard S. Glass; Kookheon Char; Jeffrey Pyun