Jessica R. Creveling

The sea-level fingerprints of ice-sheet collapse during interglacial periods

Studies of sea level during previous interglacials provide insight into the stability of polar ice sheets in the face of global climate change. Commonly, these studies correct ancient sea-level highstands for the contaminating effect of isostatic adjustment associated with past ice age cycles, and interpret the residuals as being equivalent to the peak eustatic sea level associated with excess melting, relative to present day, of ancient polar ice sheets. However, the collapse of polar ice sheets produces a distinct geometry, or fingerprint, of sea-level change, which must be accounted for to accurately infer peak eustatic sea level from site-specific residual highstands. To explore this issue, we compute fingerprints associated with the collapse of the Greenland Ice Sheet, West Antarctic Ice Sheet, and marine sectors of the East Antarctic Ice Sheet in order to isolate regions that would have been subject to greater-thaneustatic sea-level change for all three cases. These fingerprints are more robust than those associated with modern melting events, when applied to infer eustatic sea level, because: (1) a significant collapse of polar ice sheets reduces the sensitivity of the computed fingerprints to uncertainties in the geometry of the melt regions; and (2) the sea-level signal associated with the collapse will dominate the signal from steric effects. We evaluate these fingerprints at a suite of sites where sea-level records from interglacial marine isotopes stages (MIS) 5e and 11 have been obtained. Using these results, we demonstrate that previously discrepant estimates of peak eustatic sea level during MIS5e based on sealevel markers in Australia and the Seychelles are brought into closer accord.

Mechanisms for oscillatory true polar wander

Palaeomagnetic studies of Palaeoproterozoic to Cretaceous rocks propose a suite of large and relatively rapid (tens of degrees over 10 to 100 million years) excursions of the rotation pole relative to the surface geography, or true polar wander (TPW). These excursions may be linked in an oscillatory, approximately coaxial succession about the centre of the contemporaneous supercontinent. Within the framework of a standard rotational theory, in which a delayed viscous adjustment of the rotational bulge acts to stabilize the rotation axis, geodynamic models for oscillatory TPW generally appeal to consecutive, opposite loading phases of comparable magnitude. Here we extend a nonlinear rotational stability theory to incorporate the stabilizing effect of TPW-induced elastic stresses in the lithosphere. We demonstrate that convectively driven inertia perturbations acting on a nearly prolate, non-hydrostatic Earth with an effective elastic lithospheric thickness of about 10 kilometres yield oscillatory TPW paths consistent with palaeomagnetic inferences. This estimate of elastic thickness can be reduced, even to zero, if the rotation axis is stabilized by long-term excess ellipticity in the plane of the TPW. We speculate that these sources of stabilization, acting on TPW driven by a time-varying mantle flow field, provide a mechanism for linking the distinct, oscillatory TPW events of the past few billion years.

Phosphorus sources for phosphatic Cambrian carbonates

The fossilization of organic remains and shell material by calcium phosphate minerals provides an illuminating, but time-bounded, window into Ediacaran–Cambrian animal evolution. For reasons that remain unknown, phosphatic fossil preservation declined significantly through Cambrian Series 2. Here, we investigate the phosphorus (P) sources for phosphatic Cambrian carbonates, presenting sedimentological, petrographic, and geochemical data from the Cambrian Series 2–3 Thorntonia Limestone, Australia, some of the youngest Cambrian strata to display exceptional phosphatic preservation of small shelly fossils. We find that within Thorntonia sediments, phosphate was remobilized by organic decay and bacterial iron reduction, with subsequent reprecipitation largely as apatite within the interiors of small shelly fossils. We discuss the merits of bioclastic-derived, organic matter–bound, or iron-bound P as potential sources to these strata. Petrographic observations suggest that the dissolution of phosphatic skeletal material did not provide the P for fossil preservation. In contrast, high organic carbon contents imply significant organic fluxes of P to Thorntonia sediments. Sedimentology and iron-speciation data indicate that phosphorus enrichment occurred during times of expanded anoxic, ferruginous conditions in subsurface water masses, suggesting that phosphorus adsorption to iron minerals precipitating from the water column provided a second significant P source to Thorntonia sediments. Simple stoichiometric models suggest that, by themselves, neither organic carbon burial nor an iron shuttle can account for the observed phosphorus enrichment. Thus, we infer that both processes were necessary for the observed phosphorus enrichment and subsequent fossil preservation in the Thorntonia Limestone.

Time-dependent rotational stability of dynamic planets with elastic lithospheres

True polar wander (TPW), a reorientation of the rotation axis relative to the solid body, is driven by mass redistribution on the surface or within the planet and is stabilized by two aspects of the planets viscoelastic response: the delayed viscous readjustment of the rotational bulge and the elastic stresses in the lithosphere. The latter, following Willemann (1984), is known as remnant bulge stabilization. In the absence of a remnant bulge, the rotation of a terrestrial planet is said to be inherently unstable. Theoretical treatments have been developed to treat the final (equilibrium) state in this case and the time-dependent TPW toward this state, including nonlinear approaches that assume slow changes in the inertia tensor. Moreover, remnant bulge stabilization has been incorporated into both equilibrium and linearized, time-dependent treatments of rotational stability. We extend the work of Ricard et al. (1993) to derive a nonlinear, time-dependent theory of TPW that incorporates stabilization by both the remnant bulge and viscous readjustment of the rotational bulge. We illustrate the theory using idealized surface loading scenarios applied to models of both Earth and Mars. We demonstrate that the inclusion of remnant bulge stabilization reduces both the amplitude and timescale of TPW relative to calculations in which this stabilization is omitted. Furthermore, given current estimates of mantle viscosity for both planets, our calculations indicate that departures from the equilibrium orientation of the rotation axis in response to forcings with timescale of 1 Myr or greater are significant for Earth but negligible for Mars.

Cap carbonate platform facies model, Noonday Formation, SE California

The Neoproterozoic outcrop belt of the Death Valley region, California, preserves an oblique cross section of the Noonday Formation, a mixed carbonate-siliciclastic platform that hosts distinctive basal Ediacaran cap carbonate−affiliated sedimentary structures, stromatolite textures, and δ^(13)C_(carb) values. The Noonday platform encompasses two depositional sequences that reveal two cycles of relative sea-level change within strata conventionally considered to record a single, rapid, postglacial sea-level rise. In updip localities, facies of the first depositional sequence record the transition from a carbonate ramp to a stromatolite-bearing, “tubestone”-textured, reef-rimmed platform; downdip, localities seaward of the reefal escarpment variably preserve a thin and condensed onlapping foreslope wedge. Base-level fall exposed the reef crest to karstic dissolution and propagated submarine incised valleys into the seaward margin of the reef. Overlying strata record the backfilling of a submarine incised valley and reestablishment of a back-stepping, carbonate-dominated ramp prior to a second subaerial exposure event that defines the contact between the Noonday and Johnnie formations. We address the relative contributions of syndepositional tectonism and recovery from low-latitude deglaciation in dictating Noonday platform architecture and the intra−Noonday Formation sequence boundary. Noonday Formation deposition coincided with extension of the Laurentian margin during disaggregation of the Rodinian supercontinent. Within this framework, previous work has suggested that the intra−Noonday Formation sequence boundary records growth faulting that reinforced differential topography, uplifting reef-rimmed horsts—exposing the reef crest to karstic dissolution—and downdropping grabens. However, we trace the intra−Noonday Formation sequence boundary seaward of the reef crest and demonstrate that, for a time, wave base was situated downdip of the reef escarpment on putatively downdropped fault blocks. Thus, if the Noonday margin were undergoing extension, then the creation of the intra−Noonday Formation sequence boundary required a concomitant decrease in accommodation due, perhaps, to postglacial isostatic uplift attendant with low-latitude deglaciation. We speculate that Noonday Formation sequence architecture records (1) immediate deglacial flooding, (2) shoaling and exposure due to isostatic rebound induced by either a hiatus in meltwater flux or rapid ice-sheet collapse against a background of global deglaciation, and (3) resumed flooding following complete deglaciation. As rift-related tectonism could amplify or counter glacial isostasy, inferences of the amplitude of local postglacial sea-level change will require robust estimates of syndepositional extension across the Noonday margin.

TAPHONOMY OF CAMBRIAN PHOSPHATIC SMALL SHELLY FOSSILS

ABSTRACT Small shelly fossils are preserved as apatite steinkerns in the Cambrian Series 2–3 Thorntonia Limestone, Australia. Petrological observations indicate that phosphorus delivered to Thorntonia sediment was remobilized before precipitating in microenvironments defined by the matrix-filled interiors of small, mostly conical skeletons. A previous geochemical study concluded that both organic matter and iron oxides sourced phosphorus to Thorntonia sediments, and that anoxia governed phosphorus remobilization within the sediment column. This contribution asks: What factors allowed for the selective preservation of skeleton interiors, and what biases result from this preservation? We find that small shells physically trapped phosphorus-laden pore waters, creating local conditions where kinetic barriers to apatite precipitation could be overcome. Only a subset of Thorntonia Limestone skeletons is preserved by apatite, showing evidence of selectivity with respect to shell size, shape, and orientation. Both the biological and physical factors that govern phosphorus remineralization and precipitation have changed through time, accounting for the opening and closing of the Ediacaran-Cambrian phosphatization taphonomic window. The opening of this window may have required a global increase in phosphate delivery to the oceans.

Pyrite-walled tube structures in a Mesoproterozoic sediment-hosted metal sulfide deposit

Unusual decimeter-scale structures occur in the sediment-hosted Black Butte Copper Mine Project deposit within lower Mesoproterozoic strata of the Belt Supergroup, Montana. These low domal and stratiform lenses are made up of millimeter-scale, hollow or mineral-filled tubes bounded by pyrite walls. X-ray micro−computed tomography (micro-CT) shows that the tube structures are similar to the porous fabric of modern diffuse hydrothermal vents, and they do not resemble textures associated with the mineralization of known microbial communities. We determined the sulfur isotopic composition of sulfide minerals with in situ secondary ion mass spectrometry (SIMS) and of texture-specific sulfate phases with multicollector−inductively coupled plasma−mass spectrometry (MC-ICP-MS). The sedimentological setting, ore paragenesis, sulfur isotope systematics, and porosity structure of these porous precipitates constrain the site of their formation to above the sediment-water interface where metalliferous hydrothermal fluids vented into the overlying water column. These data constrain the geochemistry of the Mesoproterozoic sediment-water interface and the site of deposition for copper-cobalt-silver mineralization. Metals in the hydrothermal fluids titrated sulfide in seawater to create tortuous fluid-flow conduits. Pyrite that precipitated at the vent sites exhibits large sulfur isotope fractionation (>50‰), which indicates a close association between the vents and sulfate-reducing microbiota. In the subsurface, base metal sulfides precipitated from sulfide formed during the reduction of early diagenetic barite, also ultimately derived from seawater. This model suggests dynamic bottom-water redox conditions at the vent site driven by the interplay between sulfate-reducing organisms and metalliferous fluid effluence.