Jianing Pei

Design and synthesis of solution processable small molecules towards high photovoltaic performance

We successfully synthesized a series of novel symmetrical solution processable small molecules (APPM, AAPM and ATPM) consisting of the electron-accepting moiety (2-pyran-4-ylidenemalononitrile) (PM) and the electron-donating moiety (triphenylamine) linked by different electron-donating moieties (phenothiazine, triphenylamine and thiophene) through a Suzuki coupling reaction. Differential scanning calorimetry (DSC) measurement indicates that APPM and AAPM shows relatively high glass-transition temperature of ca. 137 °C and 163 °C, while the melting point of ATPM is at ca. 164 °C. UV-vis absorption spectra show that the combination of the PM moiety with moieties with a gradually increased electron-donating ability results in an enhanced intramolecular charge transfer (ICT) transition, which leads to an extension of the absorption spectral range and a reduction of the band gap of the molecules. Both cyclic voltammetry measurement and theoretical calculations displayed that the highest occupied molecular orbital (HOMO) energy levels of the molecules could be fine-tuned by changing the electron-donating ability of the electron-donating moieties. The bulk heterojunction (BHJ) photovoltaic devices with a structure of ITO/PEDOT/PSS/small molecules/PCBM/LiF/Al were fabricated by using the small molecules as donors and (6,6)-phenyl C61-butyric acid methyl ester (PCBM) as acceptor. Power conversion efficiencies (PCE) of 0.65%, 0.94% and 1.31% were achieved for the photovoltaic devices based on APPM/PCBM, AAPM/PCBM and ATPM/PCBM under simulated AM 1.5 illumination (100 mW cm−2), respectively. The open circuit voltage of 1.0 V obtained from the device based on ATPM/PCBM is one of the highest values for organic solar cells based on solution processable small molecules.

A low band gap donor–acceptor copolymer containing fluorene and benzothiadiazole units: synthesis and photovoltaic properties

A new low band gap copolymer containing dialkylfluorene and 4,7-dithienyl-2,1,3-benzothiadiazole (TBT), poly(fluorenevinylene-alt-4,7-dithienyl-2,1,3-benzothiadiazole) (PF-TBT) was synthesized by Heck cross-coupling polymerization. The copolymer is soluble in common organic solvents such as chloroform, tetrahydrofuran and chlorobenzene. The TGA result indicated that the copolymer possesses good thermal stability. The absorption, electrochemical and photovoltaic properties of PF-TBT were investigated and compared with those of poly(fluorenevinylene-alt-4,7-diphenyl-2,1,3-benzothiadiazole) (PF-DBT) whose structure is similar to PF-TBT. The copolymer exhibited a broad absorption band with an absorption edge close to 700 nm and an optical band gap of 1.82 eV. Cyclic voltammetry studies indicated that the relatively low HOMO energy level assured a higher open circuit voltage (Voc) when PF-TBT is used as the donor material in a photovoltaic cell. The bulk heterojunction (BHJ) solar cell using PF-TBT as the donor and [6,6]-phenyl C61-butyric acid methyl ester (PCBM) as the acceptor with the structure of ITO/PEDOT : PSS/copolymer : PCBM/LiF/Al, exhibited a Voc of 0.86 V, short-circuit current density (Jsc) of 3.97 mA cm−2, fill factor (FF) of 0.35, and a power conversion efficiency (PCE) of 1.18% under one sun of AM 1.5 solar simulator illumination (100 mW cm−2).