Jingyue Fang

The Raman redshift of graphene impacted by gold nanoparticles

The influence of gold nanoparticles (GNPs) on graphene was studied by Raman spectroscopy. It was found that the contact of GNPs could induce the whole Raman spectrum of graphene to redshift. And the shift of the 2D peak is more obvious than that of the G peak. A model of local strain was brought forward to explain the shift of Raman spectrum, which comes from the charges transfer between the GNPs and graphene. The observation of the Raman shifts helps us to gain more physical insights into the graphene-related systems.

The nonlinear optical properties of coupling and decoupling graphene layers

Third-order optical nonlinearities of graphene from monolayer to multilayers were investigated in the femtosecond regime, and the contribution of interlayer coupling to the nonlinearities was studied. The nonlinear refractive index γ of the order of 10−9 cm2/W and the nonlinear absorption coefficient β of 10−6 cm/W were obtained. By systematically investigating the nonlinear optical properties with the number of layers and comparing the coupling graphene with the decoupling superimposed graphene, we found that the coupling of interlayers has large effect upon the nonlinear refraction. These results provide an effective approach for developing graphene-based nonlinear photonic devices.

Current induced doping in graphene-based transistor with asymmetrical contact barriers

The metal/graphene contacts play a very important role in the performance of graphene-based devices. We report here a unique observation of current-induced doping in graphene transistors. The charge carrier type and the concentration in graphene can be manipulated by the current flowing through the graphene device, arising from the asymmetrical metal/graphene barriers between the source and drain electrodes and the accompanied current crowding effect.

All-carbon based graphene field effect transistor with graphitic electrodes fabricated by e-beam direct writing on PMMA

A so called all-carbon based graphene field effect transistor (GFET) in which the electrodes are composed of graphite-like nano-sheets instead of metals in the traditional devices is fabricated by one-step e-beam direct writing (EBDW). It is also found that the graphite-like nano-sheets in electrodes are perpendicular to the channel graphene, which is confirmed by the transmission electron microscopy (HRTEM). The one-step fabrication of the carbonaceous electrodes is more convenient and lower-cost comparing to the preparation of traditional metal electrodes and can be applied to many other nano-electronic devices.

Experimental study of plasmon in a grating coupled graphene device with a resonant cavity

Plasmon was probed from graphene which was grown by chemical vapor deposition using terahertz time-domain spectroscopy at room temperature. Graphene was laid on a resonant cavity, and metal grating was then deposited on top of them. For the THz light polarized along the grid fingers, the optical conductivity of graphene changed from Drude response into strongly Lorentz behavior with a peak formed in the THz-region. These experimental results are highly consistent with the theoretical prediction of a single layer graphene. It confirms that the graphene plasmon frequency can be tuned by the length of grating. Moreover, the extinction in the transmission of single-layer graphene can also be increased beyond 60%.

Compound parabolic concentrator applied as receiving antenna in scattering optical communication

The two-dimensional (2D) compound parabolic concentrators (CPC) characteristics are analyzed. It is shown that CPCs height is taller and its light collecting ability is stronger with the CPCs field of view decreasing when the bottom radius is unchanged. According to the ZEMAX analysis, CPC is good at collecting optical signal, and the antenna combining CPC with hemispherical lens can gather more optical signal than a single CPC or CPCs combined in series. The light propagation of scattering optical communication based on multiple scattering is simulated by Monte Carlo method, and the results show that using CPC as receiving antenna can strengthen communication systems signal collecting ability and increase its communication distance.

Optical property of nanocomposite of mesoporous silica thin films incorporated with gold nanoparticles

Amino-functionalized mesoporous silica thin films (MTFs) are produced using surface active agent F127, and then gold nanoparticles are introduced into the pore channels to prepare the Au/SiO2 nanocomposite. After assembling the gold, the amino-functionalized MTF undergoes some shrinkage but remains a periodic structure as demonstrated by X-ray diffraction (XRD) patterns. The nanocomposite shows an acute characteristic diffraction peak assigned to (111) plane of the face-centered-cubic structure of gold, indicating that gold nanoparticles crystallize well and grow in a preferred orientation in the pore channels. The surface plasma resonance (SPR) absorption peak near 570 nm undergoes a red-shift accompanied by a strengthening of intensity when HAuCl4 is used to react with the amino groups on the internal pore surfaces for 4, 6, and 8 h. The simulative results are consistent with the experimental ones shows that the absorption property of the Au/SiO2 nanocomposite is influenced by the dipping time, which affects the size and volume fraction of embedded gold nanoparticles.

Observation of complete space-charge-limited transport in metal-oxide-graphene heterostructure

The metal-oxide-graphene heterostructures have abundant physical connotations. As one of the most important physical properties, the electric transport property of the gold-chromium oxide-graphene heterostructure has been studied. The experimental measurement shows that the conductive mechanism is dominated by the space-charge-limited transport, a kind of bulk transport of an insulator with charge traps. Combining the theoretical analysis, some key parameters such as the carrier mobility and trap energy also are obtained. The study of the characteristics of the metal-oxide-graphene heterostructures is helpful to investigate the graphene-based electronic and photoelectric devices.

Optical Nonlinearity of Mesoporous Silica Thin Films Embedded with Gold Nanoparticles

The mesoporous silica thin films (MSTFs) synthesized by evaporation-induced self-assembly were loaded with gold nanoparticles (GNPs). The TEM and XRD characterizations showed that the template of MSTF possessed a well-ordered mesostructure, and GNPs can be well crystallized in the thin film by neutralization and hydrogen-reduction reactions. The z-scan technique was used for studying the nonlinear optical properties of the GNPs/MSTF nanocomposite. The results showed that this kind of material was possessed of a relatively feeble nonlinear absorption but an obvious nonlinear refraction. The nonlinear refractive index was estimated to be 7.9 × 10−11 cm2/W and the theoretical fitting well matched with the measured data.