Jiwen Hu

Simple approach towards fabrication of highly durable and robust superhydrophobic cotton fabric from functional diblock copolymer

We report here a simple and reproducible strategy for fabricating highly durable and robust superhydrophobic cotton fabrics (SCFs) from a series of functional diblock copolymers. These diblock copolymers consisted of both poly(glycidyl methacrylate) (PGMA) and poly(2,2,2-trifluoroethyl methacrylate) (PTFEMA) blocks that were synthesized via sequential atom transfer radical polymerization (ATRP). While the PTFEMA block provides the low surface free energy, the PGMA block serves as an anchor and forms covalent bonds with the surfaces of cotton fibers. These covalent bonds are formed via the epoxy ring-opening reaction between the epoxy groups of the PGMA block and the hydroxyl groups on the surface of the cotton fiber, and self-crosslinking of epoxy groups from PGMA chains. Structures exhibiting nano- and microscale roughness were created in one-step by combining copolymer-based nanobumps onto surfaces of micro-sized fibers of the cotton fabric, as confirmed by SEM and AFM analysis. The modified cotton fabrics show excellent water repellency with water contact angles (WCAs) of ∼163° and water sliding angles (WSAs) of ∼3° under optimized conditions. Since the low-fluorinated PTFEMA chains are chemically bound to the cotton fibers, the SCFs possess long-term stability, ultra-high durability and robustness. In particular, these SCFs withstood mechanical abrasion by sandpaper, strong laundering conditions, ultrasonication treatment in tetrahydrofuran (THF) or trifluorotoluene (TFT), soaking in a wide range of organic solvents, as well as acidic and basic aqueous solutions, exposure to UV-irradiation and even refluxing in TFT or THF.

Hierarchical interfacial assembly of ABC triblock copolymer.

Hierarchical assembly, allowing molecular order and structural control at multilength scales, is the basis of life itself and may be used in the fabrication of future electronic, optical, and other devices. Despite its importance, hierarchical assembly has been seldom practiced for block copolymers in solvents. This paper reports a method for the two-tier assembly of block copolymers. At tier 1, an ABC triblock copolymer is self-assembled into spherical or cylindrical micelle-like aggregates in decahydronaphthalene (DN) with the B block making up the insoluble core and the A and C blocks making up the soluble corona. At tier 2, the aggregates are further assembled by adsorption via the Pickering effect on surfaces of droplets of methanol that is immiscible with DN, has been added into the DN aggregate solution, and solubilizes the C block but not the A and B blocks. While the final 3-D shape of the hierarchically assembled block copolymer is invariably spherical, the 2-D morphologies are different being o...

Fabrication of fluorinated raspberry particles and their use as building blocks for the construction of superhydrophobic films to mimic the wettabilities from lotus leaves to rose petals

Reported herein is the preparation of poly((glycidyl methacrylate)-co-(ethylene glycol dimethacrylate)) raspberry-like colloidal particles (also denoted as RPs) bearing micro-/nano-scale surface roughness and the fabrication of superhydrophobic films with tunable adhesion derived from the RPs after their fluorination. The RPs were prepared via the one-pot dispersion polymerization of glycidyl methacrylate (GMA) and ethylene glycol dimethacrylate (EGDMA). The size and the surface roughness of the RPs can be readily tuned by adjusting the polymerization parameters, including the temperature, the feed monomer mole ratio, the initiator concentration, and so on. A possible mechanism of the formation of RPs was proposed according to the morphological evolution observed during the polymerization process as monitored via transmission electron microscopy (TEM), scanning electron microscopy (SEM), and size variation as evaluated with dynamic light scattering (DLS) measurements. Fluorinated RPs (also denoted as FRPs) with various fluorination degrees were further prepared by reaction between the epoxy groups of the RPs and the thiol group of perfluorodecanethiol (PFDT). The raspberry-like morphology of the FRPs was maintained as confirmed via SEM observation. By only changing the surface chemistry rather than the roughness, superhydrophobic films with tunable superhydrophobic properties capable of mimicking wettabilities ranging from those of lotus leaves to those of rose petals were easily prepared by drop-casting dispersions of FRPs onto glass substrates.

Bi-functional random copolymers for one-pot fabrication of superamphiphobic particulate coatings

Random bi-functional copolymers bearing fluorinated units and sol–gel forming units were prepared and used together with silica particles in a one-pot process for preparing superamphiphobic coatings. The copolymers P(FOEA-r-IPSMA) were prepared by atom transfer radical polymerization (ATRP) of 2-(perfluorooctyl)ethyl acrylate (FOEA) and 3-(triisopropyloxy)silylpropyl methacrylate (IPSMA). The uniform silica particles were prepared using a modified Stober process. Stirring P(FOEA-r-IPSMA), silica, water, and HCl together with substrates triggered the sol–gel reactions of the IPSMA units. These involved first the hydrolysis of IPSMA to yield silanol groups and then the condensation of the IPSMA silanol groups among themselves, and with silanol groups on silica or glass surfaces or with hydroxyl groups on cotton or filter paper. At optimized mass ratios of P(FOEA-r-IPSMA) to silica, the resultant coatings consisted of lightly covered silica particles that were embedded in a crosslinked P(FOEA-r-IPSMA) film. By optimizing the molar ratio between FOEA and IPSMA in P(FOEA-r-IPSMA), the rough particulate coatings on cotton, filter paper, and glass plates exhibited superamphiphobicity. More importantly, the particulate coatings were resistant to solvent extraction and NaOH etching.

Novel aramid nanofiber-coated polypropylene separators for lithium ion batteries

Aramid nanofiber (ANF)-coated separators were successfully prepared by the dip-coating of a cationized polypropylene (PP) porous separator in an ANF dispersion in DMSO. The ANFs were successfully coated onto the surface of the cationized PP separator as demonstrated by FT-IR and XPS measurements and the ANFs could be directly observed on the surface of the composite separator via SEM and AFM. The ANF-based coating layers became more uniform and denser as more dip-coating cycles were employed. The gas permeabilities of the separators were strongly influenced by the concentrations of the ANF dispersion and the number of dip-coating cycles. The porosity decreased and a narrower pore size distribution was obtained after the ANFs were coated onto the cationized PP separator. The ANF-coated separators were found to exhibit higher dimensional stabilities than the pristine PP separator. The separators exhibited almost identical endothermic peaks in the DSC experiment and a similar shrink temperature in the DMA experiment but the ANF-coated separator exhibited a higher rupture temperature. The ANF-coated separator retained a comparable mechanical strength with that of the pristine PP separator. The ANF coating layer was mechanically stable and durable in the electrolyte. The ANF-coated separator exhibited comparable C-rate performance and cycling performance in LMO/Li cell systems to that of the PDA–PP separator, and showed significantly better C-rate performance and cycling performance than that of the pristine PP separator. The ANF-coated PP separators exhibited improved safety in a hot oven test in comparison with the pristine PP separator. Thus the ANF-coated separators have great potential for use in lithium ion batteries.

pH-Responsive Nanoemulsions for Controlled Drug Release

Three ternary graft copolymers bearing polystyrene (PS), poly(ethylene glycol) methyl ether (MPEG), and poly(acrylic acid) (PAA) side chains were synthesized and characterized. At pH = 7.4, these copolymers stabilized doxorubicin (DOX)-containing benzyl benzoate (BBZ) nanoemulsion droplets in water and formed a compact polymer layer to inhibit DOX release. Upon lowering the solution pH to 5.0, the AA groups dissociated less and became less soluble. Moreover, the neutralized AA groups formed presumably H-bonded complexes with the EG units, reducing the solubility of the EG units. This dual action drastically shifted the hydrophilic and hydrophobic balance of the copolymer and caused the original stabilizing polymer layer to rupture and the nanoemulsion droplets to aggregate, releasing DOX. The rate and extent of DOX release could be increased by matching the numbers of PAA and MPEG chains per graft copolymer. In addition, these nanoemulsions were not toxic and entered human carcinoma cells, releasing DOX there. Thus, these nanoemulsions have potential as drug delivery vehicles.

A large sample of low surface brightness disc galaxies from the SDSS – I. The sample and the stellar populations

We present the properties of a large sample (12 282) of nearly face-on low surface brightness (LSB) disc galaxies selected from the main galaxy sample of SDSS-DR4. These properties include B-band central surface brightness μ 0 (B), scalelengths h, integrated magnitudes, colours and distances D. This sample has μ 0 (B) values from 22 to 24.5 mag arcsec -2 with a median value of 22.42 mag arcsec -2 , and disc scalelengths ranging from 2 to 19 kpc. They are quite bright with M B taking values from -18 to -23 mag with a median value of -20.08 mag. There exist clear correlations between log h and M B , log h and log D, log D and M B . However, no obvious correlations are found between μ 0 (B) and log h, colours, etc. The correlation between colours and log h is weak even though it exists. Both the optical-optical and optical-NIR colour-colour diagrams indicate that most of them have a mixture of young and old stellar populations. They also satisfy colour-magnitude relations, which indicate that brighter galaxies tend generally to be redder. The comparison between the LSBGs and a control sample of nearly face-on disc galaxies with higher surface brightness (HSB) with μ 0 (B) from 18.5 to 22 mag arcsec -2 show that, at a given luminosity or distance, the observed LSB galaxies tend to have larger scalelengths. These trends could be seen gradually by dividing both the LSBGs and HSBGs into two subgroups according to surface brightness. A volume-limited subsample was extracted to check the incompleteness of surface brightness. The only one of the property relations having an obvious change is the relation of log h versus μ 0 (B), which shows a correlation in this subsample.

Amylose-directed synthesis of CuS composite nanowires and microspheres

Reported are the synthesis and characterization of CuS composite nanowires and microspheres in the presence of amylose. The preparation involved first the complexation of amylose with Cu(2+) of CuCl(2) at 70°C. Cu(2+) complexation was confirmed by a conductivity reduction of CuCl(2) after amylose addition. Also, the aggregation state of the amylose changed after Cu(2+) as revealed by transmission electron microscopy (TEM) and dynamic light scattering (DLS). At the Cu(2+) to α-D-glucopyranosyl unit molar ratio r of 0.70 and 1.41, the amylose aggregated into microspheres that were approximately 150 and 250 nm in diameter. Adding sodium thiosulfate resulted in the production of an amorphous precipitate consisting presumably of CuS(2)O(3). At r=0.70 and 1.41, CuS(2)O(3) precipitated inside the template of Cu(2+)/amylose microspheres as nanoparticles, while a twisted nanowire-like structure was produced at r=0.92. CuS(2)O(3) decomposed under heating at 100 °C to yield crystalline CuS nanoparticles.

A large sample of low surface brightness disc galaxies from the SDSS – II. Metallicities in surface brightness bins

We study the spectroscopic properties of a large sample of low surface brightness galaxies (LSBGs) [with B-band central surface brightness μ0(B) > 22 mag arcsec −2 ] selected from the Sloan Digital Sky Survey Data Release 4 (SDSS-DR4) main galaxy sample. A large sample of disc-dominated high surface brightness galaxies [HSBGs, with μ0(B) < 22 mag arcsec −2 ] are also selected for comparison simultaneously. To study them in more details, these sample galaxies are further divided into four subgroups according to μ0(B) (in units of mag arcsec −2 ): very low surface brightness galaxies (vLSBGs) (24.5–22.75), intermediate low surface brightness galaxies (iLSBGs) (22.75–22.0), intermediate high surface brightness galaxies (iHSBGs) (22.0–21.25) and very high surface brightness galaxies (vHSBGs) (<21.25). The diagnostic diagram from spectral emission-line ratios shows that the active galactic nucleus fractions of all the four subgroups are small (<9 per cent). The 21 032 star-forming galaxies with good-quality spectroscopic observations are further selected for studying their dust extinction, strong-line ratios, metallicities and stellar mass–metallicity relations. The vLSBGs have lower extinction values and have less metal-rich and massive galaxies than the other subgroups. The oxygen abundances of our LSBGs are not as low as those of the H II regions in LSBGs studied in literature, which could be because our samples are more luminous, and because of the different metallicity calibrations used. We find a correlation between 12 + log(O/H) and μ0(B) for vLSBGs, iLSBGs and iHSBGs but show that this could be a result of correlation between μ0(B) and stellar mass and the well-known mass–metallicity relation. This large sample shows that LSBGs span a wide range in metallicity and stellar mass, and they lie nearly on the stellar mass versus metallicity and N/O versus O/H relations of normal galaxies. This suggests that LSBGs and HSBGs have not had dramatically different star formation and chemical enrichment histories.

GRB 070518: a gamma-ray burst with optically dim luminosity

We present our optical observations of the GRB 070518 afterglow obtained at the 0.8-m Tsinghua University-National Astronomical Observatory of China Telescope (TNT) at Xinglong Observatory. Our follow-up observations were performed from 512 s after the burst trigger. With the upper limit of redshift ~0.7, GRB 070518 is found to be an optically dim burst. The spectra indices β ox of optical to X-ray are slightly larger than 0.5, which implies that the burst might be a dark burst. The extinction A V of the host galaxy is 3.2 mag, inferred from the X-ray hydrogen column density with Galactic extinction law, and 0.3 mag with the Small Magellanic Cloud extinction law. Also, it is similar to three other low-redshift optically dim bursts, which belong to X-ray rich gamma-ray bursts or X-ray flashes and have mid-term duration (T 90 < 10, except for GRB 070419A, T 90 £= 116 s). Moreover, its R-band afterglow flux is well fitted by a single power law with an index of 0.87. The optical afterglow and the X-ray afterglow in the normal segment might have the same mechanism, as they are consistent with the prediction of the classical external shock model. Besides, GRB 070518 agrees with the Amati relation under reasonable assumptions. The Ghirlanda relation is also tested with the burst.