Jixue Li

Electronic structure of Li(Co0.7−xAl0.3)MgxO2 studied by electron energy-loss spectroscopy

Electronic structure of Li(Co0.7−xAl0.3)MgxO2 (x=0.01, 0.03, and 0.05) is studied via electron energy-loss spectroscopy. Oxygen K edge and Co L2,3 edge were used to investigate the effect of Mg substitution on both the valence state of Co ion and the density of unoccupied states of O ion. A change in the ratio of the white lines of Co ion, L3/L2, is used to identify the change in the valence state in Co ion, which reveals that Mg substitution gives rise to an increase of the average valence of Co ion. This is a mixed valence state of Co3+ and Co4+ in Mg substitution materials. Relative lowering of the integrated intensity of prepeak in oxygen K edge with the Mg concentration connects with a lower covalency of the Co–O bond, which indicates a significant electron feeding back from Co 3d to O 2p. This makes the oxygen ions closer to the feature of closed shell, which helps electron hopping between Co3+ and Co4+ based on the double-exchange process.

Electron Crystallography in Mineralogy and Materials Science

The mineral aerinite is investigated by electron crystallography (NED and HREM). TEM results of aerinite are compared with X-ray and synchrotron powder diffraction data. Six selected area electron diffraction (SAED) patterns and two HREM images from Pb5MoO8 single crystals are used to solve their structure. The unit cell parameters of these crystals confirm the known powder diffraction data.