Jizu Chen

Physicochemical characteristics and sources of atmospheric dust deposition in snow packs on the glaciers of western Qilian Mountains, China

Wind-blown dust derived from the arid and semi-arid regions is an important atmospheric component affecting the Earths radiation budget. Dust storms are prevailing in central Asia. Deposition of atmospheric dust in snow was measured on Glacier No.12 (5040 m a.s.l.) in the Laohugou Basin and Shiyi Glacier (4510 m a.s.l.) in the Yeniugou Basin, of western Qilian Mountains, China, mainly focusing on dust concentration and size distribution, chemistry, SEM–EDX analysis and Nd–Sr isotopic composition. An analysis of spatial distribution of dust concentration and size distribution in the snow cover at two sites suggests that deposition of dust in western Qilian Mountains is different between sites as the environment changes from west to east. Mean mass concentration of dust with 0.57 < d<40 μm in the snow is 3461 μg kg−1 on Glacier No.12 and 2876 μg kg−1 on Shiyi Glacier, respectively. Annual flux of dust deposition to western Qilian Mountains has a range of 143.8–207.6 μg cm−2 yr−1 for particles with 0.57 < d<40 μm. Dust layers in the snowpit contain Ca- and Na-rich materials typically found in Asian dust particles. Number–size distribution indicated that most of the dust diameter is <2.0 μm, implying the significant influences of finer particles to alpine glacier regions of central Asia. Volume size distributions of dust particles showed single-modal structures having volume median diameters from 3 to 22 μm, which is comparable to the results of dust deposition on glaciers of the adjacent Tianshan Mountains in western China. SEM–EDX analysis suggested that dust particles were mainly composed of mineral particles, besides some fly ash particles and soot. EDX shows that mineral particles contain Si-, Al-, Ca-, K-, and Fe-rich materials, such as quartz, albite, aluminate, etc. The Nd–Sr isotopic composition of insoluble particles in two glaciers showed that Badain Jaran Desert and Qaidam Basin were the most possible source regions of dust in the western Qilian Mountains. Physicochemical constituents of dust indicated that the snowpack was influenced by both local atmospheric environment, e.g. local dust, and anthropogenic activities in central Asia.

Physicochemical impacts of dust particles on alpine glacier meltwater at the Laohugou Glacier basin in western Qilian Mountains, China.

This work discusses the temporal variation of various physicochemical species in the meltwater runoff of Laohugou Glacier No. 12 (4260 ma.s.l.) in central Asia, and their correlation with dust particles, based on a two-year field observation in summer 2012 and 2013, mainly focusing on dust concentration and size distribution, meltwater chemistry, particles SEM-EDX analysis in the meltwater, and MODIS atmospheric optical depth fields around the Qilian Mountains in central Asia. We find that, the volume-size distribution of dust particles in the meltwater is mainly composed of three parts, which includes fine aerosol particles (with diameter of 0~3.0 μm, mainly PM 2.5), atmospheric dust (with diameter of 3.0~20 μm), and local dust particles (20~100 μm), respectively. Comparison of dust particles in the snowpack and meltwater runoff indicates that, large part of dust particles in the meltwater may have originated from atmospheric dust deposition to the snow and ice on the glacier, and transported into the meltwater runoff. Moreover, temporal variation of dust and major ions (especially crustal species) is very similar with each other, showing great influence of dust particles to the chemical constituents of the glacier meltwater. SPM and TDS implied significant influences of dust to the physical characteristics of the glacier meltwater. Results showed that, accelerated glacier melting may affect physicochemical characteristics of the meltwater at an alpine basin under global warming. MODIS atmospheric optical depth (AOD) fields derived using the Deep Blue algorithm, showed great influence of regional dust transportation over western Qilian Mountains in springtime. SEM-EDX analysis shows that dust particles in the glacier meltwater contain Si-, Al-, Ca-, K-, and Fe-rich materials, such as quartz, albite, aluminate, and fly ash, similar to that deposited in snowpack. These results showed great and even currently underestimated influences of atmospheric dust deposition to glacier meltwater physicochemistry at an alpine basin in central Asia.

Water-soluble elements in snow and ice on Mt. Yulong

Melting of high-elevation glaciers can be accelerated by the deposition of light-absorbing aerosols (e.g., organic carbon, mineral dust), resulting in significant reductions of the surface albedo on glaciers. Organic carbon deposited in glaciers is of great significance to global carbon cycles, snow photochemistry, and air-snow exchange processes. In this work, various snow and ice samples were collected at high elevation sites (4300-4850masl) from Mt. Yulong on the southeastern Tibetan Plateau in 2015. These samples were analyzed for water-soluble organic carbon (DOC), total nitrogen (TN), and water-soluble inorganic ions (WSIs) to elucidate the chemical species and compositions of the glaciers in the Mt. Yulong region. Generally, glacial meltwater had the lowest DOC content (0.39mgL-1), while fresh snow had the highest (2.03mgL-1) among various types of snow and ice samples. There were obvious spatial and temporal trends of DOC and WSIs in glaciers. The DOC and TN concentrations decreased in the order of fresh snow, snow meltwater, snowpit, and surface snow, resulting from the photolysis of DOC and snows quick-melt effects. The surface snow had low DOC and TN depletion ratios in the melt season; specifically, the ratios were -0.79 and -0.19mgL-1d-1, respectively. In the winter season, the ratios of DOC and TN were remarkably higher, with values of -0.20mgL-1d-1 and -0.08mgL-1d-1, respectively. A reduction of the DOC and TN content in glaciers was due to snows quick melt and sublimation. Deposition of these light-absorbing impurities (LAPs) in glaciers might accelerate snowmelt and even glacial retreat.

Analyses of 210Pb concentrations in surface air and in rain water at the central Guizhou, China

Samples of surface air and rain water were collected at the Mt. Guanfeng site located at Guiyang, China. The monthly mean 210Pb concentrations in surface air exhibited a U-pattern with high values appearing in winter and low values in summer and early autumn. The annual mean of 210Pb concentrations in surface air was estimated to be 2.7 ± 0.6 mBq m-3, which was at least four times higher than the annual mean reported from a large number of monitoring stations located throughout the world. The amounts of enriched Uranium in soil at the region could significantly contribute a great deal of release of 222Rn that decay to 210Pb which gets attached to the atmospheric aerosols. The site was under the influence of a monsoon climate. The distribution of monthly mean of 210Pb concentrations in surface air correlates well with the reciprocal of monthly average of observed air temperature and rainfall. The partition coefficients of 210Pb between rain water-surface air in the winter and spring were larger than those in the summer and autumn. The type and duration of rain depending on season played key roles for the changes of partition coefficients, although the rain amount is important.

Characteristics of black carbon in snow from Laohugou No. 12 glacier on the northern Tibetan Plateau

Black carbon (BC) emitted from the incomplete combustion of biomass and fossil fuel impacts the climate system, cryospheric change, and human health. This study documents black carbon deposition in snow from a benchmark glacier on the northern Tibetan Plateau. Significant seasonality of BC concentrations indicates different input or post-depositional processes. BC particles deposited in snow had a mass volume median diameter slightly larger than that of black carbon particles typically found in the atmosphere. Also, unlike black carbon particles in the atmosphere, the particles deposited in snow did not exhibit highly fractal morphology by Scanning Transmission Electron Microscope. Footprint analysis indicated BC deposited on the glacier in summer originated mainly from Central Asia; in winter, the depositing air masses generally originated from Central Asia and Pakistan. Anthropogenic emissions play an important role on black carbon deposition in glacial snow, especially in winter. The mass absorption efficiency of BC in snow at 632nm exhibited significantly seasonality, with higher values in summer and lower values in winter. The information on black carbon deposition in glacial snow provided in this study could be used to help mitigate the impacts of BC on glacier melting on the northern Tibetan Plateau.

Variations of the alpine precipitation from an ice core record of the Laohugou glacier basin during 1960-2006 in western Qilian Mountains, China

The net accumulation record of ice core is one of the most reliable indicators for reconstructing precipitation changes in high mountains. A 20.12 m ice core was drilled in 2006 from the accumulation zone of Laohugou Glacier No.12 in the northeastern Tibetan Plateau, China. We obtained the precipitation from the ice core net accumulation during 1960–2006, and found out the relationship between Laohugou ice core record and other data from surrounding sites of the northeastern Tibetan Plateau. Results showed that during 1960–2006, the precipitation in the high mountains showed firstly an increasing trend, while during 1980 to 2006 it showed an obvious decreasing trend. Reconstructed precipitation change in the Laohugou glacier basin was consistent with the measured data from the nearby weather stations in the lower mountain of Subei, and the correlation coefficient was 0.619 (P<0.001). However, the precipitation in the high mountain was about 3 times more than that of the lower mountain. The precipitation in Laohugou Glacier No.12 of the western Qilian Mountains corresponded well to the net accumulation of Dunde ice core during the same period, tree-ring reconstructed precipitation, the measured data of multiple meteorological stations in the northeastern Tibetan Plateau, and also the changes of adjacent PDSI drought index. Precipitation changes of the Laohugou glacier basin and other sites of the northeastern Tibetan Plateau had significantly positive correlation with ENSO, which implied that the regional alpine precipitation change was very likely to be influenced by ENSO.

Review of pre-processing technologies for ice cores

High-resolution ice core records covering long time spans enable reconstruction of the past climatic and environmental conditions allowing the investigation of the earth system’s evolution. Preprocessing of ice cores has direct impacts on the data quality control for further analysis since the conventional ice core processing is time-consuming, produces qualitative data, leads to ice mass loss, and leads to risks of potential secondary pollution. However, over the past several decades, preprocessing of ice cores has received less attention than the improvement of ice drilling, the analytical methodology of various indices, and the researches on the climatic and environmental significance of ice core records. Therefore, this papers reviews the development of the processing for ice cores including framework, design as well as materials, analyzes the technical advantages and disadvantages of the different systems. In the past, continuous flow analysis (CFA) has been successfully applied to process the polar ice cores. However, it is not suitable for ice cores outside polar region because of high level of particles, the memory effect between samples, and the filtration before injection. Ice core processing is a subtle and professional operation due to the fragility of the nonmetallic materials and the random distribution of particles and air bubbles in ice cores, which aggravates uncertainty in the measurements. The future developments of CFA are discussed in preprocessing, memory effect, challenge for brittle ice, coupling with real-time analysis and optimization of CFA in the field. Furthermore, non-polluting cutters with many different configurations could be designed to cut and scrape in multiple directions and to separate inner and outer portions of the core. This system also needs to be coupled with streamlined operation of packaging, coding, and stacking that can be implemented at high resolution and rate, avoiding manual intervention. At the same time, information of the longitudinal sections could be scanned and identified, and then classified to obtain quantitative data. In addition, irregular ice volume and weight can also be obtained accurately. These improvements are recorded automatically via user-friendly interfaces. These innovations may be applied to other paleomedias with similar features and needs.

Variations of Laohugou Glacier No. 12 in the western Qilian Mountains, China, from 1957 to 2015

Glaciers were solid reservoirs and important water resources in western China, but they were retreating significantly in context of global warming. Laohugou Glacier No. 12 was the largest valley glacier in Qilian Mountains. In this study, realtime kinematic (RTK) data, topographic map and WorldView-2 satellite imagery were used to measure changes in terminus, extent and volume of Laohugou Glacier No. 12. Results showed that Laohugou Glacier No. 12 was shrinking significantly since 1957. From 1960 to 2015, the terminus reduction of Laohugou Glacier No. 12 was 402.96 m (3.99%) in total, and glacier length decreased to 9.7 km from 10.1 km. Reduction of glacier area and volume were the most obvious. From 1957 to 2015, glacier area and volume decreased by 1.54 km2 (7.03%) and 0.1816 km3, respectively. Reduction trend of terminus and area was slowing in 1950 -1980s, even stable for a period in the mid-1980s, and then accelerated. Ice core analysis result and nearly meteorological station data shown an increasing trend of temperature in 1957 -2015, it was a main reason of continuous retreating of Laohugou Glacier No.12.

Sedimentary records of polycyclic aromatic hydrocarbons in China: A comparison to the worldwide

ABSTRACT This review focuses on the sedimentary records of polycyclic aromatic hydrocarbons (PAHs) in China and the worldwide. We provide a global image of sedimentary record of PAHs in different regions, including their contents, vertical profiles, and possible sources. Generally, historical PAHs recorded in China, dominated by biomass burning and domestic coal combustion, are moderate on the global scale with an upward trend while elevated levels of historical PAHs are usually found in developed countries with a downward trend. This review ends with some concerns about historical PAHs in sediments and some directions deserved further efforts.