João Paulo C. Trigueiro

Layer-by-layer assembled films of multi-walled carbon nanotubes with chitosan and cellulose nanocrystals

Chitosan solutions and cellulose nanocrystal suspensions were used to produce highly stable aqueous dispersions of multi-walled carbon nanotubes (MWCNTs). The different MWCNT dispersions, presenting positive and negative charges, were used to prepare multilayered hybrid thin films through electrostatic layer-by-layer (LBL) self-assembly. The MWCNTs are well dispersed and homogeneously distributed on each layer of chitosan and cellulose nanocrystals of the films. The nanotubes are densely packed in each multilayer, forming a random network. The surface of the LBL film exhibited a uniform and relatively smooth surface with a mean roughness value of ∼5.8±0.4nm. Electrochemical characterization revealed a decrease in two orders of magnitude in the film resistance as the number of bilayers increased from 5 to 20, which is a consequence of an increase in the amount of conductive material (MWCNT). The thin films with up to 20 bilayers exhibited transmittance higher than 90% in the visible range. The results presented in this work demonstrate the viability of the LBL technique for the deposition of active materials using the biopolymer pair chitosan/cellulose nanocrystals. The obtained films can be employed for the design of transparent and biocompatible carbon nanostructured based electrodes.

Otimização do processo de dispersão de nanotubos de carbono em poliuretano termorrígido

Neste trabalho foi desenvolvido um processo empregando misturador de alto cisalhamento e moinho de rolos para dispersar MWCNTs (multiwalled carbon nanotubes) puros e modificados em poliol visando a preparacao de concentrados de 3% em massa. Condicoes otimizadas no trabalho permitiram a obtencao de suspensoes com menor numero e tamanho de agregados de MWCNTs. Compositos contendo 0,5% em massa de MWCNTs foram preparados por diluicao dos concentrados em poliol usando mistura mecânica seguida de cura. Resultados de microscopia indicaram que as melhores dispersoes foram obtidas com os MWCNTs modificados, os quais permitiram um aumento na tensao na ruptura, no alongamento e uma melhor preservacao da estabilidade termica. Alem disso, valores de condutividade eletrica sugerem que o composito possa ser empregado para dissipacao eletrostatica. Dessa forma, os resultados obtidos demonstram que a modificacao covalente da superficie dos MWCNTs e a utilizacao de estrategias eficientes de dispersao sao essenciais para melhorar as propriedades finais dos nanocompositos.

Hybrid MoS2/h-BN Nanofillers As Synergic Heat Dissipation and Reinforcement Additives in Epoxy Nanocomposites

Two-dimensional (2D) nanomaterials as molybdenum disulfide (MoS2), hexagonal boron nitride (h-BN), and their hybrid (MoS2/h-BN) were employed as fillers to improve the physical properties of epoxy composites. Nanocomposites were produced in different concentrations and studied in their microstructure, mechanical and thermal properties. The hybrid 2D mixture imparted efficient reinforcement to the epoxy leading to increases of up to 95% in tensile strength, 60% in ultimate strain, and 58% in Youngs modulus. Moreover, an enhancement of 203% in thermal conductivity was achieved for the hybrid composite as compared to the pure polymer. The incorporation of MoS2/h-BN mixture nanofillers in epoxy resulted in nanocomposites with multifunctional characteristics for applications that require high mechanical and thermal performance.

Princípio e utilização da técnica de efeito miragem de concentração

The aim of this work is to present the theoretical and experimental aspects of the mirage effect technique. We are especially interested in the concentration mirage effect, which is a powerful tool in the study of electrochemical reactions that produce ionic movements close to electrodes and to get some fundamental information on mass transport and charge transfer during electrochemical processes. Limitations of this technique are discussed as well as the recent attempts to overcome them.