João Trabucho-Alexandre

Intercontinental correlation of organic carbon and carbonate stable isotope records: evidence of climate and sea-level change during the Turonian (Cretaceous)

Carbon (δ13Corg, δ13Ccarb) and oxygen (δ18Ocarb) isotope records are presented for an expanded Upper Cretaceous (Turonian–Coniacian) hemipelagic succession cored in the central Bohemian Cretaceous Basin, Czech Republic. Geophysical logs, biostratigraphy and stable carbon isotope chemostratigraphy provide a high‐resolution stratigraphic framework. The δ13Ccarb and δ13Corg profiles are compared, and the time series correlated with published coeval marine and non‐marine isotope records from Europe, North America and Japan. All previously named Turonian carbon isotope events are identified and correlated at high‐resolution between multiple sections, in different facies, basins and continents. The viability of using both carbonate and organic matter carbon isotope chemostratigraphy for improved stratigraphic resolution, for placing stage boundaries, and for intercontinental correlation is demonstrated, but anchoring the time series using biostratigraphic data is essential. An Early to Middle Turonian thermal maximum followed by a synchronous episode of stepped cooling throughout Europe during the Middle to Late Turonian is evidenced by bulk carbonate and brachiopod shell δ18Ocarb data, and regional changes in the distribution and composition of macrofaunal assemblages. The Late Turonian Cool Phase in Europe was coincident with a period of long‐term sea‐level fall, with significant water‐mass reorganization occurring during the mid‐Late Turonian maximum lowstand. Falling Δ13C (δ13Ccarb – δ13Corg) trends coincident with two major cooling pulses, point to pCO2 drawdown accompanying cooling, but the use of paired carbon isotopes as a high‐resolution pCO2 proxy is compromised in the low‐carbonate sediments of the Bohemian Basin study section by diagenetic overprinting of the δ13Ccarb record. Carbon isotope chemostratigraphy is confirmed as a powerful tool for testing and refining intercontinental and marine to terrestrial correlations.

Natural fractures in a United Kingdom shale reservoir analog, Cleveland Basin, northeast England

Faults and fractures within the well-exposed Lower Jurassic Cleveland Ironstone and Whitby Mudstone Formations may provide insights into the tectonic history of gas-prospective, Mississippian shale in northern England. Subvertical opening mode fractures occur throughout the Cleveland Basin. Bed-parallel fractures, some of which contain blocky calcite fills, occur preferentially within well-bedded, clay-rich mudstones of the Cleveland Ironstone and Whitby Mudstone Formations at Jet Wyke and Port Mulgrave. Subvertical fractures display abutting or curving-parallel relationships with under- and overlying bed-parallel fractures. Together, these observations suggest that bed-parallel fractures, at times, acted as free surfaces. Some bed-parallel fractures curve toward and branch from calcite-filled fault slip surfaces, indicating that bed-parallel fracturing and normal faulting were synchronous, occurring within a regional stress field with vertical maximum principal stress. This apparent paradox can be explained by normal compaction, followed by cementation and coupling between pore pressure and minimum horizontal stress driven by poroelastic deformation or incipient slip along critically stressed normal faults, causing elevation of horizontal stress in excess of the vertical stress within clay-rich units. Propagation of bed-parallel fractures was enhanced by dilatational strains adjacent to normal fault planes. Bed-parallel fractures have not been observed within more -rich units at the top of the Whitby Mudstone Formation at Whitby East Cliff, or within well-bedded, clay-rich shale at Saltwick Nab. This observation is consistent with the lack of normal faulting at Saltwick Nab, and the Whitby Mudstone Formation having been drained by structural and/or stratigraphical juxtaposition against permeable Middle Jurassic sandstones at both these localities.

More gaps than shale: erosion of mud and its effect on preserved geochemical and palaeobiological signals

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