John B. Corliss

Submarine Thermal Springs on the Galápagos Rift

The submarine hydrothermal activity on and near the Gal�pagos Rift has been explored with the aid of the deep submersible Alvin. Analyses of water samples from hydrothermal vents reveal that hydrothermal activity provides significant or dominant sources and sinks for several components of seawater; studies of conductive and convective heat transfer suggest that two-thirds of the heat lost from new oceanic lithosphere at the Gal�pagos Rift in the first million years may be vented from thermal springs, predominantly along the axial ridge within the rift valley. The vent areas are populated by animal communities. They appear to utilize chemosynthesis by sulfur-oxidizing bacteria to derive their entire energy supply from reactions between the seawater and the rocks at high temperatures, rather than photosynthesis.

Ridge crest hydrothermal activity and the balances of the major and minor elements in the ocean: The Galapagos data

Samples collected by the deep submersible “Alvin” from four hot spring fields (T = 3–13°C) on the crest of the Galapagos spreading ridge show pronounced and varied compositional anomalies. If it is assumed that these have a general significance, that they are associated with hydrothermal reactions between seawater and basalt wherever new oceanic crust is being produced then global fluxes can be computed. These are large. For Mg and SO4 they balance the river input. For Li and Rb they exceed it by factors of between five and ten. Calcium is supplied at a rate equivalent to that of non-carbonate Ca from the continents. The additions of K, Ba and Si are between one third and two thirds of the river load. There are large positive and negative anomalies for Cl and Na indicating that substantial amounts of Cl may be taken up by the newly formed crust and transported deep into the subduction zones. Where there are data in common, the field measurements agree with the experimental findings at low (<5) water/rock ratios.

On the formation of metal-rich deposits at ridge crests

Data from the hot springs at the Galapagos spreading center (T = 3–13°C) show depletions of the exiting waters in Cu, Ni, Cd, Se, Cr and U relative to ambient seawater. Manganese is strongly enriched. Iron shows highly variable behavior between vent fields but is in general low. The data confirm the occurrence of extensive subsurface mixing between the primary high-temperature, acid, reducing hydrothermal fluids and “groundwater”. The composition of the latter is indistinguishable from that of the free water column adjacent to the ridge axis. The final solutions are on the boundary between those forming MnO2 crusts and those producing iron-manganese rich sediments. The suite of metal rich deposits observed at ridge crests — Mn-O, Fe-Mn-O, Fe-S — can be explained as the manifestation of the degree of subsurface mixing, decreasing from 100 : <1 to <1 : 1 across the series (assuming an end-member temperature of 350°C).

The chemistry of hydrothermal mounds near the Galapagos Rift

Abstract Samples dredged from the sediment mounds have a unique chemistry and mineralogy which reveals details of the hydrothermal processes that produce these deposits. The mounds form primarily by deposition of Fe, Mn and Si from hydrothermal fluids which circulate through the basalt crust and the overlying sediments. The Mn, Fe and Si are strongly fractionated in the process; the Fe and Si precipitate within the mounds under slightly reducing conditions as nontronite, while the Mn is deposited as Mn oxyhydroxides at the seawater-sediment interface. The nontronite is exceptionally well crystallized, and contains less than 200 ppm Al. The Mn minerals, todorokite and birnessite, also have exceptional crystallinity and the distribution of trace elements Cu, Ni, Zn, Co, Ca and Ba in these phases agrees with predictions made on the basis of models of their crystal structure. The environment of deposition which produces this suite of minerals — slow percolation of hydrothermal fluids through pelagic sediments — may not be unique to the Galapagos Rift, as the same suite of minerals has been found in similar setting in the Gulf of Aden and on the Mid-Atlantic Ridge.

Origin of Metalliferous Sediments from the Pacific Ocean

Sediments from near the basement of a number of Deep Sea Drilling Project (DSDP) sites, from the Bauer Deep, and from the East Pacific Rise have unusually high transition metal-to-aluminum ratios. Similarities in the chemical, isotopic, and mineralogical compositions of these deposits point to a common origin. All the sediments studied have rare-earth-element (REE) patterns strongly resembling the pattern of sea water, implying either that the REEs were coprecipitated with ferromanganese hydroxyoxides (hydroxyoxides denote a mixture of unspecified hydrated oxides and hydroxides), or that they are incorporated in small concentrations of phosphatic fish debris found in all samples. Oxygen isotopic data indicate that the metalliferous sediments are in isotopic equilibrium with sea water and are composed of varying mixtures of two end-member phases with different oxygen isotopic compositions: an iron-manganese hydroxyoxide and an iron-rich montmorillonite. A low-temperature origin for the sediments is supported by mineralogical analyses by x-ray diffraction which show that goethite, iron-rich montmorillonite, and various manganese hydroxyoxides are the dominant phases present. Sr87/Sr86 ratios for the DSDP sediments are indistinguishable from the Sr87/Sr86 ratio in modern sea water. Since these sediments were formed 30 to 90 m.y. ago, when sea water had a lower Sr87/Sr86 value, the strontium in the poorly crystalline hydroxyoxides must be exchanging with interstitial water in open contact with sea water. In contrast, uranium isotopic data indicate that the metalliferous sediments have formed a closed system for this element. The sulfur isotopic compositions suggest that sea-water sulfur dominates these sediments with little or no contribution of magmatic or bacteriologically reduced sulfur. In contrast, ratios of lead isotopes in the metalliferous deposits resemble values for oceanic tholeiite basalt, but are quite different from ratios found in authigenic marine manganese nodules. Thus, lead in the metalliferous sediments appears to be of magmatic origin. The combined mineralogical, isotopic, and chemical data for these sediments suggest that they formed from hydrothermal solutions generated by the interaction of sea water with newly formed basalt crust at mid-ocean ridges. The crystallization of solid phases took place at low temperatures and was strongly influenced by sea water, which was the source for some of the elements found in the sediments.

History of metalliferous sedimentation at deep sea drilling site 319 in the South Eastern Pacific

Abstract Marked variations in the chemical and mineralogical composition of sediments at Site 319 have occurred during the 15 M.y. history of sedimentation at this site. The change in composition through time parallels the variability observed in surface sediments from various parts of the Nazca Plate and can be related to variations in the proportion of hydrothermal, hydrogenous, detrital and biogenous phases reaching this site at different times. Metal accumulation rates at Site 319 reach a maximum near the basement for most elements, suggesting a strong hydrothermal contribution during the early history of this site. The hydrothermal contribution decreased rapidly as Site 319 moved away from the spreading center, although a subtle increase in this source is detectable about the time spreading began on the East Pacific Rise. The most recent sedimentation exhibits a strong detritalhydrogenous influence. Post-depositional diagenesis of amorphous phases has converted them to ironrich smectite and well-crystallized goethite without significantly altering the bulk composition of the sediment.

Fractionation and mantle heterogeneity in basalts from the Peru-Chile Trench

Abstract Five separate exposures of oceanic basalts were dredged in the vicinity of the Peru-Chile Trench between 9° and 27°S latitude. Each dredge is dominated by abundant pillow basalts. Approximately ten of the most unaltered, glassy and fine-grained samples were selected for detailed chemical and petrographic analyses from each dredge area. All basalts recovered in the Peru-Chile Trench are olivine and quartz-normative tholeiites that are believed to have formed at the now extinct Galapagos Rise 30–50 m.y. ago. Detailed chemical analyses of the basalts, including major and selected trace and rare earth elements, indicate that considerable compositional variability exists both within each of the dredged areas as well as between areas. Most of the inherent chemical variability observed within particular basement sections appears consistent with the concept of temporal evolution of magma bodies at a former spreading center by shallow-level fractional crystallization involving primarily plagioclase and olivine. In contrast, important chemical differences between the dredged areas suggest compositional heterogeneities in the mantle source regions. Our results indicate that although shallow-level fractionation has brought about large changes in composition of basalts in each area, compositional trends are distinct and appear to reflect original mantle-derived compositional differences.

Metallogenesis in Southeast Pacific Ocean: Nazca Plate Project: ABSTRACT

The Nazca Plate Project is a detailed and systematic geological, geochemical, and geophysical investigation of a distinct and tectonically active lithospheric plate of the southeast Pacific Ocean basin. Major tectonic boundaries of the Nazca plate are defined by the East Pacific Rise on the west, along which new oceanic crust of basalt is being generated; the Peru-Chile Trench on the east, where older oceanic crust is being consumed by subduction beneath the overriding South American plate; and the Galapagos spreading center and the Chile Rise on the north and south, respectively. The motion of this plate relative to the Pacific plate is estimated to be eastward at more than 16 cm/yr, as documented by stratigraphic, structural, paleontologic, magnetic, and seismic evidenc . Normal sediments of the deep-sea floor cover basaltic basement rocks over much of the plate, but are locally dominated by a metal-rich component on and near the East Pacific Rise and within the Bauer Deep. These metalliferous sediments, which are composed of crystalline ferromanganese hydroxyoxides (goethite, psilomelane, etc) and Fe-montmorillonite, contain anomalously high concentrations of Fe, Mn, Cu, Ni, Zn, and other transition metals. Elemental abundances and ratios, extraordinary high rates of sedimentation, lead-isotope ratios, and statistical analysis of the data suggest that Fe, Mn, Cu, and possibly other metals were deposited by hydrothermal fluids emanating from sources of basaltic magmatism along the East Pacific Rise. However, isotopic abundances of O, Sr, S, and C and di tribution patterns of the rare-earth elements imply that deposition of the metalliferous sediments occurred at normally low temperatures of the ocean floor and that the nonmetallic components were derived from and/or equilibrated with seawater.