John C. Pearl

Mars Global Surveyor Thermal Emission Spectrometer experiment: Investigation description and surface science results

The Thermal Emission Spectrometer (TES) investigation on Mars Global Surveyor (MGS) is aimed at determining (1) the composition of surface minerals, rocks, and ices; (2) the temperature and dynamics of the atmosphere; (3) the properties of the atmospheric aerosols and clouds; (4) the nature of the polar regions; and (5) the thermophysical properties of the surface materials. These objectives are met using an infrared (5.8- to 50-μm) interferometric spectrometer, along with broadband thermal (5.1- to 150-μm) and visible/near-IR (0.3- to 2.9-μm) radiometers. The MGS TES instrument weighs 14.47 kg, consumes 10.6 W when operating, and is 23.6×35.5×40.0 cm in size. The TES data are calibrated to a 1-σ precision of 2.5−6×10−8 W cm−2 sr−1/cm−1, 1.6×10−6 W cm−2 sr−1, and ∼0.5 K in the spectrometer, visible/near-IR bolometer, and IR bolometer, respectively. These instrument subsections are calibrated to an absolute accuracy of ∼4×10−8 W cm−2 sr−1/cm−1 (0.5 K at 280 K), 1–2%, and ∼1–2 K, respectively. Global mapping of surface mineralogy at a spatial resolution of 3 km has shown the following: (1) The mineralogic composition of dark regions varies from basaltic, primarily plagioclase feldspar and clinopyroxene, in the ancient, southern highlands to andesitic, dominated by plagioclase feldspar and volcanic glass, in the younger northern plains. (2) Aqueous mineralization has produced gray, crystalline hematite in limited regions under ambient or hydrothermal conditions; these deposits are interpreted to be in-place sedimentary rock formations and indicate that liquid water was stable near the surface for a long period of time. (3) There is no evidence for large-scale (tens of kilometers) occurrences of moderate-grained (>50-μm) carbonates exposed at the surface at a detection limit of ∼10%. (4) Unweathered volcanic minerals dominate the spectral properties of dark regions, and weathering products, such as clays, have not been observed anywhere above a detection limit of ∼10%; this lack of evidence for chemical weathering indicates a geologic history dominated by a cold, dry climate in which mechanical, rather than chemical, weathering was the significant form of erosion and sediment production. (5) There is no conclusive evidence for sulfate minerals at a detection limit of ∼15%. The polar region has been studied with the following major conclusions: (1) Condensed CO2 has three distinct end-members, from fine-grained crystals to slab ice. (2) The growth and retreat of the polar caps observed by MGS is virtually the same as observed by Viking 12 Martian years ago. (3) Unique regions have been identified that appear to differ primarily in the grain size of CO2; one south polar region appears to remain as black slab CO2 ice throughout its sublimation. (4) Regional atmospheric dust is common in localized and regional dust storms around the margin and interior of the southern cap. Analysis of the thermophysical properties of the surface shows that (1) the spatial pattern of albedo has changed since Viking observations, (2) a unique cluster of surface materials with intermediate inertia and albedo occurs that is distinct from the previously identified low-inertia/bright and high-inertia/dark surfaces, and (3) localized patches of high-inertia material have been found in topographic lows and may have been formed by a unique set of aeolian, fluvial, or erosional processes or may be exposed bedrock.

Detection of Crystalline Hematite Mineralization on Mars by the Thermal Emission Spectrometer: Evidence for Near-surface Water

The Thermal Emission Spectrometer (TES) instrument on the Mars Global Surveyor (MGS) mission has discovered a remarkable accumulation of crystalline hematite (a-Fe2O3) that covers an area with very sharp boundaries approximately 350 by 350 -750 km in size centered near 28S latitude between 08 and 58W longitude (Sinus Meridiani). Crystalline hematite is uniquely identified by the presence of fundamental vibrational absorption features centered near 300, 450, and .525 cm21 and by the absence of silicate fundamentals in the 1000 cm 21 region. Spectral features resulting from atmospheric CO 2, dust, and water ice were removed using a radiative transfer model. The spectral properties unique to Sinus Meridiani were emphasized by removing the average spectrum of the surrounding region. The depth and shape of the hematite fundamental bands show that the hematite is crystalline and relatively coarse grained (.5-10 mm). Diameters up to and greater than hundreds of micrometers are permitted within the instrumental noise and natural variability of hematite spectra. Hematite particles ,5-10 mm in diameter (as either unpacked or hard-packed powders) fail to match the TES spectra. The spectrally derived areal abundance of hematite varies with particle size from ;10% (.30 mm diameter) to 40 - 60% (10 mm diameter). The hematite in Sinus Meridiani is thus distinct from the fine-grained (diameter ,5-10 mm), red, crystalline hematite considered, on the basis of visible, near-IR data, to be a minor spectral component in Martian bright regions like Olympus-Amazonis. Sinus Meridiani hematite is closely associated with a smooth, layered, friable surface that is interpreted to be sedimentary in origin. This material may be the uppermost surface in the region, indicating that it might be a late stage sedimentary unit or a layered portion of the heavily cratered plains units. We consider five possible mechanisms for the formation of coarse- grained, crystalline hematite. These processes fall into two classes depending on whether they require a significant amount of near-surface water: the first is chemical precipitation that includes origin by (1) precipitation from standing, oxygenated, Fe-rich water (oxide iron formations), (2) precipitation from Fe-rich hydrothermal fluids, (3) low-temperature dissolution and precipitation through mobile ground water leaching, and (4) formation of surface coatings, and the second is thermal oxidation of magnetite-rich lavas. Weathering and alteration processes, which produce nanophase and red hematite, are not consistent with the coarse, crystalline hematite observed in Sinus Meridiani. We prefer chemical precipitation models and favor precipitation from Fe-rich water on the basis of the probable association with sedimentary materials, large geographic size, distance from a regional heat source, and lack of evidence for extensive groundwater processes elsewhere on Mars. The TES results thus provide mineralogic evidence for probable large-scale water interactions. The Sinus Meridiani region may be an ideal candidate for future landed missions searching for biotic and prebiotic environments, and the physical characteristics of this site satisfy all of the engineering requirements for the missions currently planned.

An intercomparison of ground‐based millimeter, MGS TES, and Viking atmospheric temperature measurements: Seasonal and interannual variability of temperatures and dust loading in the global Mars atmosphere

During the period October 1997 to September 1999 we obtained and analyzed over 100 millimeter-wave observations of Mars atmospheric CO line absorption for atmospheric temperature profiles. These measurements extend through one full Mars year (solar longitudes LS of 190° in 1997 to 180° in 1999) and coincide with atmospheric temperature profile and dust column measurements from the Thermal Emission Spectrometer (TES) experiment on board the Mars Global Surveyor (MGS) spacecraft. A comparison of Mars atmospheric temperatures retrieved by these distinct methods provides the first opportunity to place the long-term (1982–1999) millimeter retrievals of Mars atmospheric temperatures within the context of contemporaneous, spatially mapped spacecraft observations. Profile comparisons of 0–30 km altitude atmospheric temperatures retrieved with the two techniques agree typically to within the 5 K calibration accuracy of the millimeter observations. At the 0.5 mbar pressure level (∼25 km altitude) the 30°N/30°S average for TES infrared temperatures and the disk-averaged millimeter temperatures are also well correlated in their seasonal and dust-storm-related variations over the 1997–1999 period. This period includes the Noachis Terra regional dust storm, which led to very abrupt heating (∼15 K at 0.5 mbar) of the global Mars atmosphere at LS = 224° in 1997 [Christensen et al., 1998; Conrath et al., this issue; Smith et al., this issue]. Much colder (10–20 K) global atmospheric temperatures were observed during the 1997 versus 1977 perihelion periods (LS = 200°–330°), consistent with the much (2 to 8 times) lower global dust loading of the atmosphere during the 1997 perihelion dust storm season versus the Viking period of the 1977a,b storms. The 1998–1999 Mars atmosphere revealed by both the millimeter and TES observations is also 10–15 K colder than presented by the Viking climatology during the aphelion season (LS = 0°–180°, northern spring/summer) of Mars. We reassess the observational basis of the Viking dusty-warm climatology for this season to conclude that the global aphelion atmosphere of Mars is colder, less dusty, and cloudier than indicated by the established Viking climatology even for the Viking period. We also conclude that Mars atmospheric temperatures exhibit their most significant interannual variations during the perihelion dust storm season (10–20 K for LS = 200°–340°) and during the post-aphelion northern summer season (5–10 K for LS = 100°–200°).

Thermal emission spectrometer experiment: Mars Observer mission

Thermal infrared spectral measurements will be made of the surface and atmosphere of Mars by the thermal emission spectrometer (TES) on board Mars Observer. By using these observations the composition of the surface rocks, minerals, and condensates will be determined and mapped. In addition, the composition and distribution of atmospheric dust and condensate clouds, together with temperature profiles of the CO2 atmosphere, will be determined. Broadband solar reflectance and thermal emittance measurements will also be made to determine the energy balance in the polar regions and to map the thermophysical properties of the surface. The specific science objectives of this investigation are to determine (1) the composition and distribution of surface materials, (2) the composition, particle size, and spatial and temporal distribution of suspended dust, (3) the location, temperature, height, and water abundance of H2O clouds, (4) the composition, seasonal behavior, total energy balance, and physical properties of the polar caps, and (5) the particle size distribution of rocks and fines on the surface. The instrument consists of three subsections: a Michelson interferometer, a solar reflectance sensor, and a broadband radiance sensor. The spectrometer covers the wavelength range from 6 to 50 μm (∼1600–200 cm−1) with nominal 5 and 10 cm−1 spectral resolution. The solar reflectance band extends from 0.3 to 2.7 μm; the broadband radiance channel extends from 5.5 to 100 μm. There are six 8.3-mrad fields of view for each sensor arranged in a 3 × 2 array, each with 3-km resolution at the nadir. Uncooled deuterated triglycine sulphate (DTGS) pyroelectic detectors provide a signal-to-noise ratio (SNR) of over 500 at 10 μm for daytime spectral observations at a surface temperature of 270 K. The SNR of the albedo and thermal bolometers will be approximately 2000 at the peak signal levels expected. The instrument is 23.6 × 35.5 × 40.0 cm, with a mass of 14.4 kg and an average power consumption of 14.5 W. The approach will be to measure the spectral properties of thermal energy emitted from the surface and atmosphere. Emission phase angle studies and day-night observations will be used to separate the spectral character of the surface and atmosphere. The distinctive thermal infrared spectral features present in minerals, rocks, and condensates will be used to determine the mineralogic and petrologic character of the surface and to identify and study aerosols and volatiles in the atmosphere.

Investigation of the Martian environment by infrared spectroscopy on Mariner 9

Abstract The infrared spectroscopy experiment on Mariner 9 provides extensive information on the Martian environment, including spatial, diurnal, and secular dependences of atmospheric and surface parameters. Measurements obtained during and after the planet-wide dust storm indicate that large diurnal variations in atmospheric temperature existed up to at least 30 km; winds inferred from the temperature fields show a strong tidal component and significant ageostrophic behavior. With the dissipation of the dust, the maximum in the atmospheric temperature field moved from approximately latitude -60° and late afternoon local time to near the subsolar point in latitude and time. Analysis of spectral features due to the atmospheric dust indicates a SiO 2 content of 60 ± 10%, implying that substantial geochemical differentiation has occurred. Water vapor estimates indicate abundances of 10–20 precipitable micrometers, less than has been inferred by ground-based methods in similar phases of previous Martian seasons. Between November 1971 and April 1972 no gross latitudinal or temporal dependence in the water vapor distribution has been detected from the south polar region to the equator. Water vapor has not been detected over the north polar regions. Surface pressure mapping has been carried out from which topographic relief of nearly two pressure scale heights is inferred. Extensive regions have been found where the surface pressure exceeds the triple-point pressure of water.

Infrared Observations of the Jovian System from Voyager 1

The infrared spectroscopy and radiometry investigation has obtained spectra of Jupiter and its satellites between approximately 180 and 2500 cm–1 with a spectral resolution of 4.3 cm–1. The Jupiter spectra show clear evidence of H2, CH4 C2H2, C2H6, CH3D, NH3, PH3, H2O, and GeH4. A helium concentration of 0.11 � 0.03 by volume is obtained. Meridional temperature cross sections show considerable structure. At high latitudes, the stratosphere is warmer in the north than in the south. The upper troposphere and lower stratosphere are locally cold over the Great Red Spot. Amalthea is warmer than expected. Considerable thermal structure is observed on Io, including a relatively hot region in the vicinity of a volcanic feature.

Thermal Emission Spectrometer results: Mars atmospheric thermal structure and aerosol distribution

Infrared spectra returned by the Thermal Emission Spectrometer (TES) are well suited for retrieval of the thermal structure and the distribution of aerosols in the Martian atmosphere. Combined nadir- and limb-viewing spectra allow global monitoring of the atmosphere up to 0.01 mbar (65 km). We report here on the atmospheric thermal structure and the distribution of aerosols as observed thus far during the mapping phase of the Mars Global Surveyor mission. Zonal and temporal mean cross sections are used to examine the seasonal evolution of atmospheric temperatures and zonal winds during a period extending from northern hemisphere mid-summer through vernal equinox (L, = 104°-360°). Temperature maps at selected pressure levels provide a characterization of planetary-scale waves. Retrieved atmospheric infrared dust opacity maps show the formation and evolution of regional dust storms during southern hemisphere summer. Response of the atmospheric thermal structure to the changing dust loading is observed. Maps of water-ice clouds as viewed in the thermal infrared are presented along with seasonal trends of infrared water-ice opacity. Uses of these observations for diagnostic studies of the dynamics of the atmosphere are discussed.

Infrared Observations of the Saturnian System from Voyager 2

During the passage of Voyager 2 through the Saturn system, infrared spectral and radiometric data were obtained for Saturn, Titan, Enceladus, Tethys, Iapetus, and the rings. Combined Voyager 1 and Voyager 2 observations of temperatures in the upper troposphere of Saturn indicate a seasonal asymmetry between the northern and southern hemispheres, with superposed small-scale meridional gradients. Comparison of high spatial resolution data from the two hemispheres poleward of 60� latitude suggests an approximate symmetry in the small-scale structure, consistent with the extension of a symmetric system of zonal jets into the polar regions. Longitudinal variations of 1 to 2 K are observed. Disk- averaged infrared spectra of Titan show little change over the 9-month interval between Voyager encounters. By combining Voyager 2 temperature measurements with ground-based geometric albedo determinations, phase integrals of 0.91 � 0.13 and 0.89 � 0.09 were derived for Tethys and Enceladus, respectively. The subsolar point temperature of dark material on Iapetus must exceed 110 K. Temperatures (and infrared optical depths) for the A and C rings and for the Cassini division are 69 � 1 K (0.40 � 0.05), 85 � 1 K (0.10 � 0.03), and 85 � 2 K (0.07 � 0.04), respectively.

Mars Global Surveyor Thermal Emission Spectrometer (TES) observations of dust opacity during aerobraking and science phasing

The Mars Global Surveyor (MGS) arrived at Mars in September 1997 near Marss southern spring equinox and has now provided monitoring of conditions in the Mars atmosphere for more than half a Mars year. The large majority of the spectra taken by the Thermal Emission Spectrometer (TES) are in a nadir geometry (downward looking mode) where Mars is observed through the atmosphere. Most of these contain the distinct spectral signature of atmospheric dust. For these nadirgeometry spectra we retrieve column-integrated infrared aerosol (dust) opacities. TES observations during the aerobraking and science-phasing portions of the MGS mission cover the seasonal range Ls = 184°–28°. Excellent spatial coverage was obtained in the southern hemisphere. Northern hemisphere coverage is generally limited to narrow strips taken during the periapsis pass but is still very valuable. At the beginning of the mission the 9-μm dust opacity at midsouthern latitudes was low (0.15–0.25). As the season advanced through southern spring and into summer, TES observed several regional dust storms (including the Noachis dust storm of November 1997) where peak 9-μm dust opacities approached or exceeded unity, as well as numerous smaller local storms. Both large and small dust storms exhibited significant changes in both spatial coverage and intensity over a timescale of a day. Throughout southern spring and summer the region at the edge of the retreating southern seasonal polar ice cap was observed to be consistently more dusty than other latitudes.

Infrared observations of the neptunian system.

The infrared interferometer spectrometer on Voyager 2 obtained thermal emission spectra of Neptune with a spectral resolution of 4.3 cm-1. Measurements of reflected solar radiation were also obtained with a broadband radiometer sensitive in the visible and near infrared. Analysis of the strong C2H2 emission feature at 729 cm-1 suggests an acetylene mole fraction in the range between 9 x 10-8 and 9 x 10-7. Vertical temperature profiles were derived between 30 and 1000 millibars at 70� and 42�S and 30�N. Temperature maps of the planet between 80�S and 30�N were obtained for two atmospheric layers, one in the lower stratosphere between 30 and 120 millibars and the other in the troposphere between 300 and 1000 millibars. Zonal mean temperatures obtained from these maps and from latitude scans indicate a relatively warm pole and equator with cooler mid-latitudes. This is qualitatively similar to the behavior found on Uranus even though the obliquities and internal heat fluxes of the two planets are markedly different. Comparison of winds derived from images with the vertical wind shear calculated from the temperature field indicates a general decay of wind speed with height, a phenomenon also observed on the other three giant planets. Strong, wavelike longitudinal thermal structure is found, some of which appears to be associated with the Great Dark Spot. An intense, localizd cold region is seen in the lower stratosphere, which does not appear to be correlated with any visible feature. A preliminary estimate of the effective temperature of the planet yields a value of 59.3 � 1.0 kelvins. Measurements of Triton provide an estimate of the daytime surface temperature of 38+3-4 kelvins.