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Dive into the research topics where John E. Bercaw is active.

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Featured researches published by John E. Bercaw.


Archive | 1992

Selective Hydroxylation of Hydrocarbons by Platinum Salts in Aqueous Media: Direct Conversion of Ethanol to Ethylene Glycol

Jay A. Labinger; Andrew M. Herring; John E. Bercaw

Water-soluble organic compounds are hydroxylated by aqueous solutions of chloroplatinum(II) and chloroplatinum(IV) salts. p-Toluenesulfonic acid is converted stepwise to the corresponding alcohol and aldehyde, the first step being somewhat faster than the second. No further conversion to the carboxylic acid is observed. Ethanol shows substantial selectivity for attack at a C-H bond of the methyl group, affording ethylene glycol and 2-chloroethanol, as well as more expected products such as acetaldehyde and acetic acid. The origin of the unusual selectivity patterns is discussed in terms of the mechanism of activation of C-H bonds by Pt(II) species.


Archive | 2017

Olefin trimerization with titanium catalysts: MAO/silica-supported variants display higher productivities

John E. Bercaw; Dinesh C. Aluthge; Aaron Sattler; Jay A. Labinger


Archive | 2017

Co-supported tandem catalysts for production of linear low density polyethylene

Dinesh C. Aluthge; Aaron Sattler; John E. Bercaw; Jay A. Labinger


Archive | 2017

CO-SUPPORTED CATALYSTS FOR THE TANDEM TRIMERIZATION AND POLYMERIZATION OF ETHYLENE TO PRODUCE LINEAR LOW DENSITY POLYETHYLENE

Dinesh C. Aluthge; Aaron Sattler; Mamdouh A. Al-Harthi; Jay A. Labinger; John E. Bercaw


Archive | 2016

Ethylene and alpha olefin trimerization and tandem trimerization/polymerization of ethylene

John E. Bercaw; Loi Do; Aaron Sattler; Dinesh C. Aluthge; Jay A. Labinger; Mamdouh Al Harthi


Archive | 2016

Oligo or poly? A mechanistic interpretation of a switchable catalyst

Jay A. Labinger; John E. Bercaw; Emmanuelle Despagnet-Ayoub


Archive | 2016

Homogeneous Ta/Ir tandem catalytic alkane/alkene coupling

John E. Bercaw; Jay A. Labinger; David C. Leitch; Keith Steelman


Archive | 2015

Tandem catalytic processes for light alkane upgrading and ethylene polymerization

John E. Bercaw; David C. Leitch; Aaron Sattler; Jay A. Labinger


Archive | 2015

Linear low density polyethylenes using well defined tandem catalysts and a single monomer feed

John E. Bercaw; Jay A. Labinger; Aaron Sattler


Archive | 2014

N-Heterocyclic carbene group 4 transition metal catalysts: Synthesis and reactivity towards oligomerization/polymerization of α-olefins

Emmanuelle Despagnet-Ayoub; Jay A. Labinger; John E. Bercaw

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Jay A. Labinger

King Fahd University of Petroleum and Minerals

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Aaron Sattler

King Fahd University of Petroleum and Minerals

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Jay A. Labinger

King Fahd University of Petroleum and Minerals

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Alexander J. M. Miller

University of North Carolina at Chapel Hill

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Dinesh C. Aluthge

University of British Columbia

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David C. Leitch

University of British Columbia

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Dinesh C. Aluthge

University of British Columbia

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Mamdouh A. Al-Harthi

King Fahd University of Petroleum and Minerals

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Aaron D. Wilson

University of Colorado Boulder

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