John Kuna Raj

Historical variations of Bera Lake (Malaysia) sediments geochemistry using radioisotopes and sediment quality indices.

The Bera Lake basin is a lacustrine mire system and the largest natural lake in Peninsular Malaysia. Three cores were collected from the lake sediments in order to assess sediment quality and ecological risks for aquatic life and human health. An index analysis approach (Cf, Cd, Er, and IR) and fallout 210Pb and 137Cs radioisotopes were applied to assess the impacts of environmental evolutionary changes. Sediment chronology was determined using the Constant Rate of Supply model with the resultant ages verified by 137Cs horizons. Although the general contamination factors indicate low risk conditions in Bera Lake the risks associated with individual layers ranged from moderate to considerable. Five deforestation phases can be identified in the dated sediment cores with distinct variations in heavy metal influxes since 1972. These phases are in excellent agreement with the dates of land clearance and development projects undertaken over the past four decades. This study has highlighted the capability of contamination factors and chronological methods in environmental evolutionary studies where catchments have experienced extensive land use changes. The destiny of heavy metal influxes into a lake can also be revealed using this methodology.

Effects of Lateral Variation in Vegetation and Basin 'Dome' Shape on Tropical Lowland Peat Stabilisation in the Kota Samarahan-Asajaya Area, West Sarawak, Malaysia

Field surveys indicate lateral variation in peat humilIcation levels (von Post) in dominantly occurring fibric, fibric to hemic, sapric and hemic to sapric peats across a gradient from the margin towards the centre of tropical lowland peat domes. Cement-peat stabilisation can be enhanced by adding mineral soil fillers (silt, clays and line sands) obtained from Quaternary floodplain deposits and residual soil (weathered schist). The unconfined compressive strength (UCS) of the stabilised cement-mineral soil filler-peat mix increases with the increased addition of selected mineral soil filler. Lateral variation in the stabilised peat strength (UCS) in the top 0 to 0.5 m layer was found from the margin towards the centre of the tropical lowland peat dome. The variations in the UCS of stabilised tropical lowland peats along a gradient from the periphery towards the centre of the peat dome are most likely caused by a combination of factors due to variations in the mineral soil or ash content of the peat and horizontal zonation or lateral variation in the dominant species of the plant assemblages (due to successive vegetation zonation of the peat swamp forest from the periphery towards the centre of the tropical lowland peat dome).

Sedimentation rates in Bera Lake (Peninsular Malaysia) using 210Pb and 137Cs radioisotopes

The evolutionary environmental history of Bera Lake was studied using the fallout radioisotopes137Cs and 210Pb. 317Cs horizons in the all ten studied cores showed a constant rate of 210Pb supply along all distinctive layers in each core. The lithology of layers significantly affected the variation of 210Pb value with depth. The chronology of Bera Lake sediment was conducted using the Constant Rate of Supply (CRS) model. The 1963 fallout maximum 137Cs from atmospheric testing of nuclear weapons found in all selected master cores at the depth of 40 cm. The mean pre-1950 sediment accumulation rate was ranged between 0.06 ± 0.02 and 0.16 ± 0.2 g cm−2 y−1. Environmental impacts of five deforestation projects performed from 1972 to 1995 at the catchment area, contributed significantly toward increasing the sedimentation rate within Bera Lake. Besides the 137Cs horizons, the charcoal horizon at the lower contact of white sandy mud revealed the datum of maximum deforestation in the study area. 210Pb dates using the CRS model correlated historical sediment fluxes to anthropogenic changes in Bera Lake catchment area. Organicrich sediments deposited mostly at the top of the Bera Lake sediment columns with a mean rate of 0.2 ± 0.1 g cm−2 y−1 since 1994. High biomass productivity of mature oil palm plantations, which were developed in the catchment area, dictated organic-rich deposit distribution. This study highlighted capability of radioisotopes to reconstruct long-term (100–150 years) history of a natural lake at a tropical area where surrounding catchment has extensively deforested over the recent decades.

An Evaluation of Bera Lake (Malaysia) Sediment Contamination Using Sediment Quality Guidelines

Bera Lake is known as the first RAMSAR site and is the largest natural lake in Malaysia. Sediment quality guidelines (SQGs) and Geoaccumulation index were used to evaluate Bera Lake sediment contamination. Five undisturbed cores were collected from Bera Lake sediment. Major and trace levels of elements were determined for 132 subsamples using an inductively coupled plasma mass spectrometry (ICP-MS). The results marked two major groups of metallic elements bonded to the terrestrial and organic-rich sediments. Terrestrial sediments were strongly associated with accumulation of Li, Al, Pb, Cu, Cr, Na, Mg, Sr, and K during main fluxes of metals. However, a strong positive correlation was obtained between Fe, Mn, As, Zn, Cu, Ni, Ca, and Cd elements and TOC and TN. The Mn/Fe ratio revealed a long-term redox and acidic condition at Bera Lake. Geoaccumulation index for all individual metals has classified Bera Lake sediment as low to moderately polluted. However, elemental values when compared with thresholds limits of SQG indicated that Bera Lake sediments were contaminated by arsenic and iron. Results prove that deforestation during the five phases of land developments since 1972 has significantly contributed to the existence of metals fluxes into the area.

Distribution, classification, petrological and related gochemical (SRA) characteristics of a tropical lowland peat dome in the Kota Samarahan-Asajaya area, West Sarawak, Malaysia

Petrographic studies indicate that lateral variations in the decomposition levels of peat are associated with the predominantly occurring peat macerals. Source Rock Analyzer (SRA) results indicate lateral variation in peat organic matter types from type II to III and back again to type II, occurring laterally within the top 0-m to 0.5-m layer at the basin margin to the midsection and further towards the near-center areas of the peat dome. This variation is most likely caused by a combination of factors: (a) Horizontal zonation and lateral variation of the dominant species of plant assemblages (b) Fibric (marginal) peats and hemic to sapric peats associated with type II organic matter (kerogen). Sample organic matter (coal-equivalent kerogen) typing indicates that the relative abundance of phytoclasts and palynomorphs generally supports the organic matter classification obtained by the SRA method. Lateral variations in the peat organic matter types may support the lateral vegetation variation concept. The classification of peat organic matter types (interpreted from visual analyses of palynological slides) occurring from the basin periphery to the mid-section and further towards the basin center yields organic matter of type II to type III and mixed types II to III (coal kerogen-equivalent), respectively.

Failure mechanisms in weathered meta-sedimentary rocks

The weathering profile of the extended cut slope within the quartz mica schist along Pos Selim Highway in Perak State, Malaysia shows three broad morphological zones; bedrock zone, intermediate zone, and residual soil zone. Further thinner horizons within these broad morphological zones were differentiated based on differences particularly in textures and structures of original bedrock and degree of preservation of the constituent minerals. Both large and small scale discontinuities observed in the schist provide slip surfaces for failures, and field investigation showed evidence of failures in this extended cut slope. The implications of the micro-structures revealed through petrography showed shearing components along planes of weakness. From the determined index properties of the weathered profile, the quartz mica schist is not suitable for structural support. This is also evidenced by the high values of sand over silt and clay deduced from the sieve analysis. In the bedrock zone, weathering manifests itself by opening up of discontinuities within the rock mass rather than weakening of the material itself. From the kinematic analyses carried out on the rock cuts, there are possibilities of wedge, planar and toppling failures across this extended cut slope.

Influence of discontinuities on the stability of cut slopes in weathered meta-sedimentary rocks

The meta-sedimentary rocks along Pos Selim Highway in Perak State, Malaysia showed a gradational weathering profile based on differences particularly in textures, hardness, lateral changes in colour and consistency of material extension. Both large and small scale discontinuities observed in the investigated rocks reduce the physical and mechanical properties of the rocks, and provide slip surfaces for failures. Rock and soil samples were tested using established standards to determine their characteristics and responses under a wide variety of disturbances. Kinematic analyses were also carried out to determine the modes and likely modes of failures. Petrographic analyses revealed associated micro-structures, and the implications of these micro-structures showed shearing components along planes of weakness. From the determined index properties of the tested soil samples, the weathered quartz mica schist is not suitable for structural support. Further study involving unconsolidated undrained direct shear box tests carried out under total stress, revealed a non-uniform response of the rocks to shearing disturbance along discontinuity planes, and the rate and depth of deformation. The shear strength components of the investigated rocks were thereby prescribed in terms of cohesion and friction angle. From the kinematic analyses across this extended cut slope, there are possibilities of wedge and planar failures.