John Lee Grenfell

The response of atmospheric chemistry on earthlike planets around F, G and K Stars to small variations in orbital distance

Abstract One of the prime goals of future investigations of extrasolar planets is to search for life as we know it. The Earths biosphere is adapted to current conditions. How would the atmospheric chemistry of the Earth respond if we moved it to different orbital distances or changed its host star? This question is central to astrobiology and aids our understanding of how the atmospheres of terrestrial planets develop. To help address this question, we have performed a sensitivity study using a coupled radiative–convective photochemical column model to calculate changes in atmospheric chemistry on a planet having Earths atmospheric composition, which we subjected to small changes in orbital position, of the order of 5–10% for a solar-type G2V, F2V, and K2V star. We then applied a chemical source-sink analysis to the biomarkers in order to understand how chemical processes affect biomarker concentrations. We start with the composition of the present Earth, since this is the only example we know for which a spectrum of biomarker molecules has been measured. We then investigate the response of the biomarkers to changes in the input stellar flux. Computing the thermal profile for atmospheres rich in H 2 O, CO 2 and CH 4 is a major challenge for current radiative schemes, due, among other things, to lacking spectroscopic data. Therefore, as a first step, we employ a more moderate approach, by investigating small shifts in planet–star distance and assuming an earthlike biosphere. To calculate this shift we assumed a criteria for complex life based on the Earth, i.e. the earthlike planetary surface temperature varied between 0xa0°C T surface 2 at its present-day level. In reality, the CO 2 cycle (not presently included in our model) would likely lead to atmospheric CO 2 stabilising at higher levels than considered in our runs near our quoted “outer” boundaries. The biomarkers H 2 O, CH 4 and CH 3 Cl varied by factors 0.08, 17, and 16, respectively in the total column densities on moving outwards for the solar case. Whereas H 2 O decreased moving outwards due to cooling hence enhanced condensation in the troposphere, CH 4 and CH 3 Cl increased associated with a slowing in H 2 O+O 1 D→2OH, hence less OH, an important sink for these two compounds. Ozone changes were smaller, around a 10% increase on moving outwards partly because cooler temperatures led to a slowing in the reaction between O 3 and O 1 D. We also considered changes in species which impact ozone—the so-called family species (and their reservoirs), which can catalytically destroy ozone. Hydrochloric acid (HCl), for example, is a chlorine reservoir (storage) molecule, which increased by a factor 64 in the mid-stratosphere (32xa0km) on moving outwards for the solar case. For the F2V and K2V stars, similar sources and sinks dominated the chemical biomarker budget as for the solar case and column trends were comparable.

On the protection of extrasolar Earth-like planets around K/M stars against galactic cosmic rays

Previous studies have shown that extrasolar Earth-like planets in close-in habitable zones around M-stars are weakly protected against galactic cosmic rays (GCRs), leading to a strongly increased particle flux to the top of the planetary atmosphere. Two main effects were held responsible for the weak shielding of such an exoplanet: (a) For a close-in planet, the planetary magnetic moment is strongly reduced by tidal locking. Therefore, such a close-in extrasolar planet is not protected by an extended magnetosphere. (b) The small orbital distance of the planet exposes it to a much denser stellar wind than that prevailing at larger orbital distances. This dense stellar wind leads to additional compression of the magnetosphere, which can further reduce the shielding efficiency against GCRs. In this work, we analyse and compare the effect of (a) and (b), showing that the stellar wind variation with orbital distance has little influence on the cosmic ray shielding. Instead, the weak shielding of M star planets can be attributed to their small magnetic moment. We further analyse how the planetary mass and composition influence the planetary magnetic moment, and thus modify the cosmic ray shielding efficiency. We show that more massive planets are not necessarily better protected against galactic cosmic rays, but that the planetary bulk composition can play an important role.

AstRoMap European Astrobiology Roadmap

Abstract The European AstRoMap project (supported by the European Commission Seventh Framework Programme) surveyed the state of the art of astrobiology in Europe and beyond and produced the first European roadmap for astrobiology research. In the context of this roadmap, astrobiology is understood as the study of the origin, evolution, and distribution of life in the context of cosmic evolution; this includes habitability in the Solar System and beyond. The AstRoMap Roadmap identifies five research topics, specifies several key scientific objectives for each topic, and suggests ways to achieve all the objectives. The five AstRoMap Research Topics are •u2002Research Topic 1: Origin and Evolution of Planetary Systems •u2002Research Topic 2: Origins of Organic Compounds in Space •u2002Research Topic 3: Rock-Water-Carbon Interactions, Organic Synthesis on Earth, and Steps to Life •u2002Research Topic 4: Life and Habitability •u2002Research Topic 5: Biosignatures as Facilitating Life Detection It is strongly recommended that steps be taken towards the definition and implementation of a European Astrobiology Platform (or Institute) to streamline and optimize the scientific return by using a coordinated infrastructure and funding system. Key Words: Astrobiology roadmap—Europe—Origin and evolution of life—Habitability—Life detection—Life in extreme environments. Astrobiology 16, 201–243.

Co-Evolution of Atmospheres, Life, and Climate

After Earths origin, our host star, the Sun, was shining 20-25% less brightly than today. Without greenhouse-like conditions to warm the atmosphere, our early planet would have been an ice ball, and life may never have evolved. But life did evolve, which indicates that greenhouse gases must have been present on early Earth to warm the planet. Evidence from the geological record indicates an abundance of the greenhouse gas CO(2). CH(4) was probably present as well; and, in this regard, methanogenic bacteria, which belong to a diverse group of anaerobic prokaryotes that ferment CO(2) plus H(2) to CH(4), may have contributed to modification of the early atmosphere. Molecular oxygen was not present, as is indicated by the study of rocks from that era, which contain iron carbonate rather than iron oxide. Multicellular organisms originated as cells within colonies that became increasingly specialized. The development of photosynthesis allowed the Suns energy to be harvested directly by life-forms. The resultant oxygen accumulated in the atmosphere and formed the ozone layer in the upper atmosphere. Aided by the absorption of harmful UV radiation in the ozone layer, life colonized Earths surface. Our own planet is a very good example of how life-forms modified the atmosphere over the planets lifetime. We show that these facts have to be taken into account when we discover and characterize atmospheres of Earth-like exoplanets. If life has originated and evolved on a planet, then it should be expected that a strong co-evolution occurred between life and the atmosphere, the result of which is the planets climate.

Potential biosignatures in super-Earth atmospheres II. Photochemical responses.

Spectral characterization of super-Earth atmospheres for planets orbiting in the habitable zone of M dwarf stars is a key focus in exoplanet science. A central challenge is to understand and predict the expected spectral signals of atmospheric biosignatures (species associated with life). Our work applies a global-mean radiative-convective-photochemical column model assuming a planet with an Earth-like biomass and planetary development. We investigated planets with gravities of 1g and 3g and a surface pressure of 1 bar around central stars with spectral classes from M0 to M7. The spectral signals of the calculated planetary scenarios have been presented by in an earlier work by Rauer and colleagues. The main motivation of the present work is to perform a deeper analysis of the chemical processes in the planetary atmospheres. We apply a diagnostic tool, the Pathway Analysis Program, to shed light on the photochemical pathways that form and destroy biosignature species. Ozone is a potential biosignature for complex life. An important result of our analysis is a shift in the ozone photochemistry from mainly Chapman production (which dominates in Earths stratosphere) to smog-dominated ozone production for planets in the habitable zone of cooler (M5-M7)-class dwarf stars. This result is associated with a lower energy flux in the UVB wavelength range from the central star, hence slower planetary atmospheric photolysis of molecular oxygen, which slows the Chapman ozone production. This is important for future atmospheric characterization missions because it provides an indication of different chemical environments that can lead to very different responses of ozone, for example, cosmic rays. Nitrous oxide, a biosignature for simple bacterial life, is favored for low stratospheric UV conditions, that is, on planets orbiting cooler stars. Transport of this species from its surface source to the stratosphere where it is destroyed can also be a key process. Comparing 1g with 3g scenarios, our analysis suggests it is important to include the effects of interactive chemistry.

Exoplanet Biosignatures: A Review of Remotely Detectable Signs of Life

Abstract In the coming years and decades, advanced space- and ground-based observatories will allow an unprecedented opportunity to probe the atmospheres and surfaces of potentially habitable exoplanets for signatures of life. Life on Earth, through its gaseous products and reflectance and scattering properties, has left its fingerprint on the spectrum of our planet. Aided by the universality of the laws of physics and chemistry, we turn to Earths biosphere, both in the present and through geologic time, for analog signatures that will aid in the search for life elsewhere. Considering the insights gained from modern and ancient Earth, and the broader array of hypothetical exoplanet possibilities, we have compiled a comprehensive overview of our current understanding of potential exoplanet biosignatures, including gaseous, surface, and temporal biosignatures. We additionally survey biogenic spectral features that are well known in the specialist literature but have not yet been robustly vetted in the context of exoplanet biosignatures. We briefly review advances in assessing biosignature plausibility, including novel methods for determining chemical disequilibrium from remotely obtainable data and assessment tools for determining the minimum biomass required to maintain short-lived biogenic gases as atmospheric signatures. We focus particularly on advances made since the seminal review by Des Marais et al. The purpose of this work is not to propose new biosignature strategies, a goal left to companion articles in this series, but to review the current literature, draw meaningful connections between seemingly disparate areas, and clear the way for a path forward. Key Words: Exoplanets—Biosignatures—Habitability markers—Photosynthesis—Planetary surfaces—Atmospheres—Spectroscopy—Cryptic biospheres—False positives. Astrobiology 18, 663–708.

3D climate modeling of Earth-like extrasolar planets orbiting different types of host stars

Abstract The potential habitability of a terrestrial planet is usually defined by the possible existence of liquid water on its surface, since life as we know it needs liquid water at least during a part of its life cycle. The potential presence of liquid water on a planetary surface depends on many factors such as, most importantly, surface temperatures. The properties of the planetary atmosphere and its interaction with the radiative energy provided by the planets host star are thereby of decisive importance. In this study we investigate the influence of different main-sequence stars (F, G, and K-type stars) upon the climate of Earth-like extrasolar planets and their potential habitability by applying a state-of-the-art three-dimensional (3D) Earth climate model accounting for local and dynamical processes. The calculations have been performed for planets with Earth-like atmospheres at orbital distances (and corresponding orbital periods) where the total amount of energy received from the various host stars equals the solar constant. In contrast to previous 3D modeling studies, we include the effect of ozone radiative heating upon the vertical temperature structure of the atmospheres. The global orbital mean results obtained have been compared to those of a one-dimensional (1D) radiative convective climate model to investigate the approximation of global mean 3D results by those of 1D models. The different stellar spectral energy distributions lead to different surface temperatures and due to ozone heating to very different vertical temperature structures. As previous 1D studies we find higher surface temperatures for the Earth-like planet around the K-type star, and lower temperatures for the planet around the F-type star compared to an Earth-like planet around the Sun. However, this effect is more pronounced in the 3D model results than in the 1D model because the 3D model accounts for feedback processes such as the ice-albedo and the water vapor feedback. Whether the 1D model may approximate the global mean of the 3D model results strongly depends on the choice of the relative humidity profile in the 1D model, which is used to determine the water vapor profile. Hence, possible changes in the hydrological cycle need to be accounted for when estimating the potential habitability of an extrasolar planet.

The unstable CO2 feedback cycle on ocean planets

Ocean planets are volatile-rich planets, not present in our Solar system, which are thought to be dominated by deep, global oceans. This results in the formation of high-pressure water ice, separating the planetary crust from the liquid ocean and, thus, also from the atmosphere. Therefore, instead of a carbonate-silicate cycle like on the Earth, the atmospheric carbon dioxide concentration is governed by the capability of the ocean to dissolve carbon dioxide (CO2). In our study, we focus on the CO2 cycle between the atmosphere and the ocean which determines the atmospheric CO2 content. The atmospheric amount of CO2 is a fundamental quantity for assessing the potential habitability of the planets surface because of its strong greenhouse effect, which determines the planetary surface temperature to a large degree. In contrast to the stabilizing carbonate-silicate cycle regulating the long-term CO2 inventory of the Earth atmosphere, we find that the CO2 cycle feedback on ocean planets is negative and has strong destabilizing effects on the planetary climate. By using a chemistry model for oceanic CO2 dissolution and an atmospheric model for exoplanets, we show that the CO2 feedback cycle can severely limit the extension of the habitable zone for ocean planets.

Response of Atmospheric Biomarkers to NOx-Induced Photochemistry Generated by Stellar Cosmic Rays for Earth-like Planets in the Habitable Zone of M Dwarf Stars

Understanding whether M dwarf stars may host habitable planets with Earth-like atmospheres and biospheres is a major goal in exoplanet research. If such planets exist, the question remains as to whether they could be identified via spectral signatures of biomarkers. Such planets may be exposed to extreme intensities of cosmic rays that could perturb their atmospheric photochemistry. Here, we consider stellar activity of M dwarfs ranging from quiet up to strong flaring conditions and investigate one particular effect upon biomarkers, namely, the ability of secondary electrons caused by stellar cosmic rays to break up atmospheric molecular nitrogen (N(2)), which leads to production of nitrogen oxides (NO(x)) in the planetary atmosphere, hence affecting biomarkers such as ozone (O(3)). We apply a stationary model, that is, without a time dependence; hence we are calculating the limiting case where the atmospheric chemistry response time of the biomarkers is assumed to be slow and remains constant compared with rapid forcing by the impinging stellar flares. This point should be further explored in future work with time-dependent models. We estimate the NO(x) production using an air shower approach and evaluate the implications using a climate-chemical model of the planetary atmosphere. O(3) formation proceeds via the reaction O+O(2)+M→O(3)+M. At high NO(x) abundances, the O atoms arise mainly from NO(2) photolysis, whereas on Earth this occurs via the photolysis of molecular oxygen (O(2)). For the flaring case, O(3) is mainly destroyed via direct titration, NO+O(3)→NO(2)+O(2), and not via the familiar catalytic cycle photochemistry, which occurs on Earth. For scenarios with low O(3), Rayleigh scattering by the main atmospheric gases (O(2), N(2), and CO(2)) became more important for shielding the planetary surface from UV radiation. A major result of this work is that the biomarker O(3) survived all the stellar-activity scenarios considered except for the strong case, whereas the biomarker nitrous oxide (N(2)O) could survive in the planetary atmosphere under all conditions of stellar activity considered here, which clearly has important implications for missions that aim to detect spectroscopic biomarkers.

Atmospheric effects of stellar cosmic rays on Earth-like exoplanets orbiting M-dwarfs

M-dwarf stars are generally considered favourable for rocky planet detection. However, such planets may be subject to extreme conditions due to possible high stellar activity. The goal of this work is to determine the potential effect of stellar cosmic rays on key atmospheric species of Earth-like planets orbiting in the habitable zone of M-dwarf stars and show corresponding changes in the planetary spectra. We build upon the cosmic rays model scheme of Grenfell et al. (2012), who considered cosmic ray induced NOx production, by adding further cosmic ray induced production mechanisms (e.g. for HOx) and introducing primary protons of a wider energy range (16 MeV - 0.5 TeV). Previous studies suggested that planets in the habitable zone that are subject to strong flaring conditions have high atmospheric methane concentrations, while their ozone biosignature is completely destroyed. Our current study shows, however, that adding cosmic ray induced HOx production can cause a decrease in atmospheric methane abundance of up to 80%. Furthermore, the cosmic ray induced HOx molecules react with NOx to produce HNO