John Southon

IntCal04 terrestrial radiocarbon age calibration, 0-26 cal kyr BP.

A new calibration curve for the conversion of radiocarbon ages to calibrated (cal) ages has been constructed and internationally ratified to replace IntCal98, which extended from 0-24 cal kyr BP (Before Present, 0 cal BP = AD 1950). The new calibration data set for terrestrial samples extends from 0-26 cal kyr BP, but with much higher resolution beyond 11.4 cal kyr BP than IntCal98. Dendrochronologically-dated tree-ring samples cover the period from 0-12.4 cal kyr BP. Beyond the end of the tree rings, data from marine records (corals and foraminifera) are converted to the atmospheric equivalent with a site-specific marine reservoir correction to provide terrestrial calibration from 12.4-26.0 cal kyr BP. A substantial enhancement relative to IntCal98 is the introduction of a coherent statistical approach based on a random walk model, which takes into account the uncertainty in both the calendar age and the 14C age to calculate the underlying calibration curve (Buck and Blackwell, this issue). The tree-ring data sets, sources of uncertainty, and regional offsets are discussed here. The marine data sets and calibration curve for marine samples from the surface mixed layer (Marine04) are discussed in brief, but details are presented in Hughen et al. (this issue a). We do not make a recommendation for calibration beyond 26 cal kyr BP at this time; however, potential calibration data sets are compared in another paper (van der Plicht et al., this issue).

Forcing of the cold event of 8,200 years ago by catastrophic drainage of Laurentide lakes

The sensitivity of oceanic thermohaline circulation to freshwater perturbations is a critical issue for understanding abrupt climate change. Abrupt climate fluctuations that occurred during both Holocene and Late Pleistocene times have been linked to changes in ocean circulation, but their causes remain uncertain. One of the largest such events in the Holocene occurred between 8,400 and 8,000 calendar years ago,, (7,650–7,200 14C years ago), when the temperature dropped by 4–8 °C in central Greenland and 1.5–3 °C at marine, and terrestrial, sites around the northeastern North Atlantic Ocean. The pattern of cooling implies that heat transfer from the ocean to the atmosphere was reduced in the North Atlantic. Here we argue that this cooling event was forced by a massive outflow of fresh water from the Hudson Strait. This conclusion is based on our estimates of the marine 14C reservoir for Hudson Bay which, in combination with other regional data, indicate that the glacial lakes Agassiz and Ojibway, (originally dammed by a remnant of the Laurentide ice sheet) drained catastrophically ∼8,470 calendar years ago; this would have released >1014 m3 of fresh water into the Labrador Sea. This finding supports the hypothesis,, that a sudden increase in freshwater flux from the waning Laurentide ice sheet reduced sea surface salinity and altered ocean circulation, thereby initiating the most abrupt and widespread cold event to have occurred in the past 10,000 years.

Deglacial changes in ocean circulation from an extended radiocarbon calibration

Temporal variations in the atmospheric concentration of radiocarbon sometimes result in radiocarbon-based age-estimates of biogenic material that do not agree with true calendar age. This problem is particularly severe beyond the limit of the high-resolution radiocarbon calibration based on tree-ring data, which stretches back only to, about 11.8 kyr before present (BP), near the termination of the Younger Dryas cold period. If a wide range of palaeoclimate records are to be exploited for better understanding the rates and patterns of environmental change during the last deglaciation, extending the well-calibrated radiocarbon timescale back further in time is crucial. Several studies attempting such an extension, using uranium/thorium-dated corals and laminae counts in varved sediments, show conflicting results. Here we use radiocarbon data from varved sediments in the Cariaco basin, in the southern Caribbean Sea, to construct an accurate and continuous radiocarbon calibration for the period 9 to 14.5 kyr BP, nearly 3,000 years beyond the tree-ring-based calibration. A simple model compared to the calculated atmospheric radiocarbon concentration and palaeoclimate data from the same sediment core suggests that North Atlantic Deep Water formation shut down during the Younger Dryas period, but was gradually replaced by an alternative mode of convection, possibly via the formation of North Atlantic Intermediate Water.

Quantification of soil production and downslope creep rates from cosmogenic 10Be accumulations on a hillslope profile

Average soil transport rates over a period of ∼3500 yr on a convex soil-mantled hillslope have been quantified using a mass-balance model that incorporates the soil concentration of the cosmogenic isotope 10 Be. The 10 Be model results support the assumption used in most geomorphic models that the soil creep rate is proportional to surface gradient. The predicted diffusion coefficient is 360 ±55 cm 3 ⋅ yr -1 ⋅ cm -1 contour length and the average rate of soil production is 0.026 ±0.007 cm/yr. Within the uncertainty of this technique, the data do not reject G. K. Gilbert9s hypothesis that some hillslopes may exist in a condition of dynamic equilibrium with a uniform soil production rate. However, the model does not require an assumption of dynamic equilibrium and may be an approach that uniquely allows the quantification of a local soil-production rate law.

Reservoir Ages in Eastern Pacific Coastal and Estuarine Waters

We have refined marine reservoir age estimates for eastern Pavific Coastal waters with radiocarbon measurements of mollusk shells collected prior to 1950. We have also investigated interspecific variability in 14C ages for historic and ancient shells from San Francisco Bay.

Isotopic evidence for the contemporary origin of high-molecular weight organic matter in oceanic environments

Abstract Previous work has suggested that apparent old 14C ages for oceanic DOC are the result of mixing of different organic carbon fractions. This report provides direct evidence for a contemporary 14C age of a high-molecular-weight (HMW) fraction of colloidal organic carbon (≥10 kD). Colloidal organic matter, COM10 (from 10 kDaltons (kD) to 0.2 μm), isolated from the upper water column of the Gulf of Mexico and the Middle Atlantic Bight (MAB) region, generally has a contemporary age (i.e., younger than a few decades), while COM1 (from 1 kD to 0.2 μm), is apparently old: 380–4500 y b P. Thus, BMW COM10 (3–5% of DOC) from the upper water column is derived from living particulate organic matter (POM) and cycles rapidly, while a significant fraction of low-molecular-weight (≤1 kD) DOM is likely more refractory, and cycles on much longer time scales. The presence of pigment biomarker compounds in COM1 from the upper water column points to selected phytoplankton species as one of the sources of COM. Terrestrial carbon as another source of COM is suggested from the inverse correlation between Δ14C and δ13C values, as well as the increasing δ13C values with increasing salinity. 234Th-derived turnover times of COM10 and COM1 from both the Gulf of Mexico and MAB are consistently short, 1–20 and 3–30 days, respectively. These short residence times support the hypothesis that 14C ages of colloidal fractions of DOC are the result of COM fractions being a mixture of several endmembers with fast and slow turnover rates.

Millennial-scale storminess variability in the northeastern United States during the Holocene epoch

For the purpose of detecting the effects of human activities on climate change, it is important to document natural change in past climate. In this context, it has proved particularly difficult to study the variability in the occurrence of extreme climate events, such as storms with exceptional rainfall. Previous investigations have established storm chronologies using sediment cores from single lakes, but such studies can be susceptible to local environmental bias. Here we date terrigenous inwash layers in cores from 13 lakes, which show that the frequency of storm-related floods in the northeastern United States has varied in regular cycles during the past 13,000 years (13 kyr), with a characteristic period of about 3 kyr. Our data show four peaks in storminess during the past 14 kyr, approximately 2.6, 5.8, 9.1 and 11.9 kyr ago. This pattern is consistent with long-term changes in the average sign of the Arctic Oscillation, suggesting that modulation of this dominant atmospheric mode may account for a significant fraction of Holocene climate variability in North America and Europe.

LLNL/UC AMS facility and research program

Abstract The Lawrence Livermore National Laboratory (LLNL) and the University of California (UC) now have in operation a large AMS spectrometer built as part of a new multiuser laboratory centered on an FN tandem. AMS measurements are expected to use half of the beam time of the accelerator. LLNL use of AMS is in research on consequences of energy usage. Examples include global warming, geophysical site characterization, radiation biology and dosimetry, and study of mutagenic and carcinogenic processes. UC research activities are in clinical applications, archaeology and anthropology, oceanography, and geophysical and geochemical research. Access is also possible for researchers outside the UC system. The technological focus of the laboratory is on achieving high rates of sample throughput, unattended operation, and advances in sample preparation methods. Because of the expected growth in the research programs and the other obligations of the present accelerator, we are designing a follow-on dedicated facility for only AMS and microprobe analysis that will contain at least two accelerators with multiple spectrometers.

The Keck Carbon Cycle AMS laboratory, University of California, Irvine: Initial operation and a background surprise

A new radiocarbon accelerator mass spectrometry (AMS) laboratory for carbon cycle studies has been established at the University of California, Irvine. The 0.5MV AMS system was installed in mid-2002 and has operated routinely since October of that year. This paper briefly describes the spectrometer and summarizes lessons learned during the first year of operation. In the process of setting up the system, we identified and largely suppressed a previously unreported (super 14) C AMS background: charge exchange tails from (super 14) N beams derived from nitrogen-containing molecular ions produced near the entrance of the accelerator.

Estimation of stratospheric input to the Arctic troposphere: 7Be and 10Be in aerosols at Alert, Canada

Concentrations of 7Be and 210Pb in 2 years of weekly high-volume aerosol samples collected at Alert, Northwest Territories, Canada, showed pronounced seasonal variations. We observed a broad winter peak in 210Pb concentration and a spring peak in 7Be. These peaks were similar in magnitude and duration to previously reported results for a number of stations in the Arctic Basin. Beryllium 10 concentrations (determined only during the first year of this study) were well correlated with those of 7Be; the atom ratio 10Be/7Be was nearly constant at 2.2 throughout the year. This relatively high value of 10Be/7Be indicates that the stratosphere must constitute an important source of both Be isotopes in the Arctic troposphere throughout the year. A simple mixing model based on the small seasonal variations of 10Be/7Be indicates an approximately twofold increase of stratospheric influence in the free troposphere in late summer. The spring maxima in concentrations of both Be isotopes at the surface apparently reflect vertical mixing in rather than stratospheric injections into the troposphere. We have merged the results of the Be-based mixing model with weekly O3 soundings to assess Arctic stratospheric impact on the surface O3 budget at Alert. The resulting estimates indicate that stratospheric inputs can account for a maximum of 10–15% of the O3 at the surface in spring and for less during the rest of the year. These estimates are most uncertain during the winter. The combination of Be isotopic measurements and O3 vertical profiles could allow quantification of the contributions of O3 from the Arctic stratosphere and lower latitude regions to the O3 budget in the Arctic troposphere. Although at present the lack of a quantitative understanding of the temporal variation of O3 lifetime in the Arctic troposphere precludes making definitive calculations, qualitative examples of the power of this approach are given.