John T. Cheney

A petrogenetic grid for pelitic schists in the system SiO2-Al2O3-FeO-MgO-K2O-H2O

A quantitative petrogenetic grid for pelitic schists in the system KFMASH that includes the phases garnet, chlorite, biotite, chloritoid, cordierite, staurolite, talc, kyanite, andalusite, sillimanite, and pyrophyllite (with quartz, H2O and muscovite or K-feldspar in excess) is presented. The grid is based on thermodynamic data of Berman et al. (1985) and Berman (1988) for endmember KFASH and KMASH equilibria and natural Fe-Mg partitioning for the KFMASH system. Calculation of P-T slopes and the change in Fe/(Fe+Mg) along reactions in the KFMASH system were made using the Gibbs method. In addition, the effect on the grid of MnO and CaO is evaluated quantitatively. The resulting grid is consistent with typical Buchan and Barrovian parageneses at medium to high grades. At low grades, the grid predicts an extensive stability field for the paragenesis chloritoid+biotite which arises because of the unusual facing of the reaction chloritoid+biotite + quartz+H2O = garnet+chlorite+muscovite, which proceeds to the right with increasing T in the KFMASH system. However, the reaction proceeds to the left with increasing T in the MnKFASH system so the assemblage chloritoid + biotite is restricted to bulk compositions with high Fe/(Fe+Mg+Mn). Typical metapelites will therefore contain garnet+chlorite at low grades rather than chloritoid + biotite.

ON THE LOSS OF 40AR* FROM MUSCOVITE DURING POLYMETAMORPHISM

Abstract Recent laser studies have documented 40Ar concentration gradients in micas that correspond to age variations of tens to hundreds of millions of years. A fundamental problem to interpretation of such variations is to evaluate whether they represent loss via lattice diffusion or, alternatively, loss during chemical reactions and deformation. New data of this study and comparisons with previous work suggest that muscovite is far less prone to lose accumulated 40Ar via lattice diffusion during overprinting events than has been inferred previously. Kyanite-muscovite assemblages in Proterozoic schist along the eastern flank of the Green Mountain massif, central Vermont Appalachians, formed during Proterozoic metamorphism at ca. 1.1 Ga and were remetamorphosed in the greenschist facies during both Taconian (ca. 465 Ma) and Acadian (ca. 390 Ma) events. The overprinting events resulted in deformation of earlier kyanite and muscovite, growth of chemically and isotopically distinct rims on earlier muscovite, and growth of neoblastic muscovite and chloritoid, with each event at inferred minimum temperatures of ca. 425°C. Laser spot analyses of the Grenville muscovite range from 988 ± 11 Ma in the centers of porphyroclasts to 397 ± 7 Ma along rims. Ages younger than 750 Ma occur only on the deformed edges of porphyroclasts and in highly deformed areas within crystals. Parts of early-formed muscovite that escaped late deformation and chemical reaction seem remarkably retentive of accumulated 40Ar; laser spot analyses along the outer 100 μm of an undeformed growth face yield ages close to the timing of Proterozoic metamorphism and cooling. The present study suggests episodic heating events are ineffective for producing measurable, diffusive argon loss along the edges of large muscovite crystals (ca. 1 mm in diameter), particularly in comparison with deformation and reaction mechanisms, and are unlikely to result in complete 40 Ar 39 Ar age resetting of such crystals. The results of this study further emphasize that the argon diffusivity in muscovite is lower than commonly considered in previous work.

Aragonite pseudomorphs in high-pressure marbles of Syros, Greece

Numerous rod-shaped calcite crystals occur in the blueschist to eclogite facies marbles of Syros, Greece. The rods show a shape-preferred orientation, and the long axes of the rods are oriented at a large angle to foliation. The crystals also have a crystallographic-preferred orientation: calcite c-axes are oriented parallel to the long axes of the rods. Based on their chemical composition, shape, and occurrence in high-pressure marbles, these calcite crystals are interpreted as topotactic pseudomorphs after aragonite that developed a crystallographic-preferred orientation during peak metamorphism. This interpretation is consistent with deformation of aragonite by dislocation creep, which has been observed in laboratory experiments but has not been previously reported on the basis of field evidence. Subsequent to the high-pressure deformation of the aragonite marbles, the aragonite recrystallized statically into coarse rod-shaped crystals, maintaining the crystallographic orientation developed during deformation. During later exhumation, aragonite reverted to calcite, and the marbles experienced little further deformation, at least in the pseudomorph-rich layers. Some shearing of pseudomorph-bearing marble layers did occur and is indicated by twinning of calcite and by a variable inclination of the pseudomorphs relative to foliation.

Monazite ages in the Chesham Pond Nappe, SW New Hampshire, U.S.A.: Implications for assembly of central New England thrust sheets

Abstract Four distinct generations of monazite growth have been identified in samples from the Chesham Pond Nappe, and three (monazite compositional domains 2, 3, and 4) have been correlated with both temperature and mineral assemblage. Domain 1 cores were interpreted previously to be detrital relics or vestiges of an earlier Acadian metamorphism. The four monazite domains have been dated by in situ isotope and chemical methods; the following are chemical ages of each domain (weighted average ±2 standard errors of the mean): 400 ± 10 Ma (domain 1); 381 ± 8 Ma (domain 2); 372 ± 6 Ma (domain 3); 352 ± 14 Ma (domain 4). Heating and cooling rates derived from combining monazite ages, monazite thermometry, and 40Ar/39Ar closure temperatures are approximately 10.15 °C/m.y. for heating from 470 to 740 °C, approximately 8 °C/m.y. for cooling from 740 to 375 °C, and approximately 1.2 °C/m.y for cooling from 375 to 150 °C. Temperature-time paths calculated with monazite ages and monazite thermometry indicate that (1) plutonism at ca. 400 Ma was the likely heat source for the formation of monazite domain 1 and (2) monazite domains 2.4 were produced during a regional low-pressure, high-temperature metamorphism active between 380.350 Ma. The regional metamorphism is ascribed to lithospheric mantle delamination, followed by asthenospheric mantle upwelling, which heated a wide area of the Merrimack basin (southwestern New Hampshire, central Massachusetts, central Connecticut) to temperatures in excess of 725 °C. Monazite ages in the Chesham Pond Nappe and adjacent structural units to the west constrain the commencement of nappe overthrusting to roughly 355 Ma.

Advances in the geology of the Tobacco Root Mountains, Montana, and their implications for the history of the northern Wyoming province

Integrated studies by Keck Geology Consortium participants have generated many new insights into the Precambrian geology of the Tobacco Root Mountains. We have clarifi ed the tectonic setting and origin of two suites of metamorphic rocks: (1) a quartzofeldspathic gneiss complex with associated metasupracrustal rocks (the combined Indian Creek and Pony–Middle Mountain Metamorphic Suites) that originated in a continental arc setting between 3.35 and 3.2 Ga with subsequent sedimentation and (2) mafi c metavolcanic rocks with intercalated metasedimentary rocks (the Spuhler Peak Metamorphic Suite) from a suprasubduction zone ophiolite or backarc basin possibly of Proterozoic age. A poorly preserved metamorphic event at 2.45 Ga affected the former but not the latter, as did the intrusion of rift-related mafi c dikes and sills at 2.06 Ga. Both suites were amalgamated, metamorphosed to at least upper amphibolite facies, subjected to simple shear strain and folded into mapand outcrop-scale sheath folds, and tectonically unroofed during the period 1.78 to 1.71 Ga. We name this event the Big Sky orogeny. The Proterozoic geology of the Tobacco Root Mountains can be integrated with coeval features of the geology of the northern Wyoming province to outline a northeast-trending, southeast-vergent belt as the Big Sky orogen. The Big Sky orogen consists of a metamorphic hinterland fl anked to the southeast by a foreland of discrete ductile shear zones cutting older basement, and to the northwest by arc-related metaplutonic bodies and the trace of a fossil subduction zone in the upper mantle. Archean blocks to the north of the Big Sky orogen may have been accreted as allochthonous terranes during collision and convergence. The remarkable synchroneity of collision along the Big Sky orogen with tectonism in the Trans-Hudson orogen along the eastern margin of the Wyoming province and in the Cheyenne belt to the south of the province raise profound but unanswered questions about the process by which the Wyoming province was added to the rest of the ancestral North American craton.

Paleoproterozoic Metamorphism in the Northern Wyoming Province: Implications for the Assembly of Laurentia

U‐Pb ages measured on zircons from the Tobacco Root Mountains and monazite from the Highland Mountains indicate that the northwestern Wyoming province experienced an episode of high‐grade metamorphism at ∼1.77 Ga. Leucosome emplaced in Archean gneisses from the Tobacco Root Mountains contains a distinctive population of zircons with an age of 1.77 Ga but also contains zircons to ∼3.5 Ga; it is interpreted to have been derived primarily by anatexis of nearby Archean schist. A granulite facies mafic dike that cuts across Archean gneissic banding in the Tobacco Root Mountains contains two distinct populations of zircons. A group of small (<50 μm) nonprismatic grains is interpreted to be metamorphic and yields an age of 1.76 Ga; a group of slightly larger prismatic grains yields an age of 2.06 Ga, which is interpreted to be the time of crystallization of the dike. Monazite from a leucogranite from the Highland Mountains yields a well‐defined age of 1.77 Ga, which is interpreted as the time of partial melting and emplacement of the leucogranite. These results suggest that the northwestern Wyoming province, which largely lies within the western part of the Great Falls tectonic zone, experienced a metamorphic maximum at 1.77 Ga. This age is ∼100 m.yr. younger than the proposed time of Wyoming‐Hearne collision in the central Great Falls tectonic zone (1.86 Ga) and suggests that the northwestern Wyoming province may have been involved in a separate, younger collisional event at ∼1.77 Ga. An event at this time is essentially coeval with collisions proposed for the eastern and southeastern margins of the province and suggests a multiepisodic model for the incorporation of the Wyoming craton into Laurentia.

Single-crystal 40Ar/39Ar age variation in muscovite of the Gassetts Schist and associated gneiss, Vermont Appalachians

Abstract An exposure near Gassetts, Vermont, contains lithologies varying from staurolite-kyanite grade aluminous schists with paragonitic muscovite to potassic gneiss with phengitic muscovite. Singlecrystal laser fusion 40Ar/39Ar ages for paragonitic and phengitic muscovite yield similar distributions with ranges between 366 ± 4 and 326 ± 4 Ma. Intracrystalline ages vary from ca. 394 ± 4 to 330 ± 4 Ma. Thus, we find that the intracrystalline (core-rim) age distribution of relatively large, single crystals essentially encompasses the range of ages obtained through total fusion of smaller crystals, consistent with models for development of diffusion profiles and 40Ar-closure during cooling with a diffusion dimension controlled by the physical grain size. However, some of the larger crystals studied, particularly those with prominent microscopic defects (features readily evident such as internal grain boundaries and twin planes), yield relatively young ages and lack significant core-rim age discordance. Furthermore, the overall distribution of single-crystal ages in the two samples is bimodal, and we suggest that this age distribution reflects metamorphic deformation and recrystallization event(s) superimposed on early generation muscovite. Thus, the mean age of muscovite in these samples (typical of K/Ar and 40Ar/39Ar incremental heating analysis of bulk mineral separates) has little relationship to any single, hypothetical closure temperature. In view of the similar results we obtain for muscovite of contrasting composition, the net effects of variations in grain size, deformational character, and growth history are interpreted to be more important in forming the observed variations in age than are the chemical substitutions in these samples.

Proterozoic Metamorphism of the Tobacco Root Mountains, Montana

Textures and mineral assemblages of metamorphic rocks of the Tobacco Root Mountains are consistent with metamorphism of all rocks during the Big Sky orogeny (1.77 Ga) at relatively high pressure (P >1.0 GPa) followed by differential Cheney, J.T., Brady, J.B., Tierney, K.A., DeGraff, K.A., Mohlman, H.K., Frisch, J.D., Hatch, C.E., Steiner, M.L., Carmichael, S.K., Fisher, R.G.M., Tuit, C.B., Steffen, K.J., Cady, P., Lowell, J., Archuleta, L.L., Hirst, J., Wegmann, K.W., and Monteleone, B., 2004, Proterozoic metamorphism of the Tobacco Root Mountains, Montana, in Brady, J.B., Burger, H.R., Cheney, J.T., and Harms, T.A., eds., Precambrian geology of the Tobacco Root Mountains, Montana: Boulder, Colorado, Geological Society of America Special Paper 377, p. 105–129. For permission to copy, contact editing@geosociety.org.

40Ar/39Ar ages of metamorphic rocks from the Tobacco Root Mountains region, Montana

Measurements of 60 single-grain, UV laser microprobe 40 Ar/ 39 Ar total gas ages for hornblende from metamorphic rocks of the Tobacco Root Mountains in southwest Montana yield a mean age of 1.71 ± 0.02 Ga. Measurements of 40 Ar/ 39 Ar step-heating plateau ages of three bulk hornblende samples from the Tobacco Root Mountains metamorphic rocks average 1.70 ± 0.02 Ga. We believe that these and the K/Ar or 40 Ar/ 39 Ar ages reported by previous workers are cooling ages from a 1.78 to 1.72 Ga, upper-amphibolite to granulite facies, regional metamorphism (Big Sky orogeny) that affected the northwestern portion of the Wyoming province, including the Tobacco Root Mountains and adjacent ranges. Based on the 40 Ar/ 39 Ar data, this 1.78–1.72 Ga metamorphism must have achieved temperatures greater than ~500 °C to reset the hornblende 40 Ar/ 39 Ar ages of samples from the Indian Creek Metamorphic Suite, which was previously metamorphosed at 2.45 Ga, and of the crosscutting metamorphosed mafi c dikes and sills (MMDS), which were intruded at 2.06 Ga. Biotite and hornblende from the Tobacco Root Mountains appear to give the same 40 Ar/ 39 Ar or K/Ar age (within uncertainty), indicating that the rocks cooled rapidly through the interval from 500 to 300 °C. This is consistent with a model of the Big Sky orogeny that includes late-stage tectonic denudation that leads to decompression and rapid cooling. A similar cooling history is suggested by our data for the Ruby Range. Three biotite samples from the Ruby Range yield 40 Ar/ 39 Ar step-heating plateau ages with a mean of 1.73 ± 0.02 Ga, identical to the best-estimate (near-plateau) age for a hornblende from the same rocks. Two samples of the orthoamphibole, gedrite, from the Tobacco Root Mountains were studied, but did not have enough K to yield a reliable 40 Ar/ 39 Ar age. Several biotite and three hornblende samples from the region yield 40 Ar/ 39 Ar dates signifi cantly younger than 1.7 Ga. We believe these samples were partially reset during contact metamorphism by Cretaceous (75 Ma) intrusive rocks. Hydrothermal alteration associated with ca. 1.4 Ga rifting led to growth of muscovite with that age in the Ruby Range, but this alteration was apparently not hot enough to reset biotite and hornblende ages there.

Metamorphic style and development of the blueschist- to eclogite-facies rocks, Cyclades, Greece

The island of Syros, Greece is part of the Attic-Cycladic blueschist belt, formed during Mesozoic Eurasia-Africa subduction. The rocks of Syros can be broadly divided into three tectono-stratigraphic units: (I) metamorphosed sedimentary and volcanic rocks (marble-schist sequence), (II) remnants of oceanic crust with fault-bounded packages of blueschist/eclogite-facies mafic rocks and serpentinite (mafic-ultramafic rocks) and (III) the Vari gneiss, which is a tectonic klippe. Low-temperature, high-pressure assemblages are found on several islands in the Cyclades. The best preserved of these rocks are on Syros and Sifnos islands. Mineral compositions and peak metamorphic assemblages are similar on both islands. Both islands are considered to share similar P-T histories with highest-pressure mineral assemblages reflecting conditions of at least 15 kbar and about 500°C.