Jongyeol Lee

Electrical characteristics of pentacene-based thin film transistor with conducting poly(3,4-ethylenedioxythiophene) electrodes

This is a report on the fabrication and electrical characteristics of an all-organic-based thin film transistor that uses conducting poly(3,4-ethylenedioxythiophene) (PEDOT) as electrodes. The conducting PEDOT layers as source, drain, and gate electrodes were patterned by using photolithography. The poly(vinyl cinnamate) (PVCN) was spin coated and cross-linked as a gate insulator. The pentacene as an active layer was vapor deposited onto the PVCN layer. In order to compare the characteristics of the pentacene-based organic thin film transistor (OTFT) with PEDOT electrodes, we fabricated another pentacene-based OTFT using a Si-based pattern with Au electrodes. The electrical characteristics of the devices, such as charge carrier mobility (μ), threshold voltage (Vth), and on/off current ratio (Ion∕off), were measured from its current-voltage (I-V) characteristic curves. The μ, Vth, and Ion∕off of the pentacene-based OTFT with PEDOT electrodes were ∼2.3×10−3cm2∕Vs, 4V, and ∼100, respectively. We evaluated th...

Initial effects of thinning on soil carbon storage and base cations in a naturally regenerated Quercus spp. forest in Hongcheon, Korea

Thinning can affect soil carbon (C) and base cation balances by reducing tree density and altering microclimate and organic matter budget; however, the subsequent changes in soil C and base cation contents after thinning are not well elucidated. Thus, this study investigated the effects of thinning on C storages in soil (at 0–10 cm, 10–20 cm, and 20–30 cm depths) and forest floor and concentrations of soil exchangeable base cations (Ca2+, Mg2+, K+, and Na+). Thinning treatments of different intensities based on the removed basal area (no thinning: control, 15% thinning: T15, and 30% thinning: T30) were applied to a naturally regenerated 31 to 40-year-old Quercus spp. forest. Soil C concentrations at 10–20 cm and 20–30 cm depths were significantly higher in T15 and T30 than in the control after 39 months, but not after 4 months. T15 and T30 treatments seemed to increase soil C storage at 0–30 cm after 39 months, but did not significantly change forest floor C storage after 4 and 39 months. Concentrations of exchangeable K+ of T15 and exchangeable base cations except for Ca2+ of T30 depth were significantly lower than those of the control at 0–10 cm after 4 months, but not after 39 months. This study shows that thinning treatments on a naturally regenerated Quercus spp. forest could increase soil C concentration after a few years but temporally decrease concentrations of soil exchangeable base cations.

Estimating the Changes in Forest Carbon Dynamics of Pinus densiflora and Quercus variabilis Forests in South Korea under the RCP 8.5 Climate Change Scenario

Forests contain a huge amount of carbon (C) and climate change could affect forest C dynamics. This study was conducted to predict the C dynamics of Pinus densiflora and Quercus variabilis forests, which are the most dominant needleleaf and broadleaf forests in Korea, using the Korean Forest Soil Carbon (KFSC) model under the two climate change scenarios (2012−2100; Constant Temperature (CT) scenario and Representative Concentration Pathway (RCP) 8.5 scenario). To construct simulation unit, the forest land areas for those two species in the 5th National Forest Inventory (NFI) data were sorted by administrative district and stand age class. The C pools were initialized at 2012, and any disturbance was not considered during the simulation period. Although the forest C stocks of two species generally increased over time, the forest C stocks under the RCP 8.5 scenario were less than those stocks under the CT scenario. The C stocks of P. densiflora forests increased from 260.4 Tg C in 2012 to 395.3 (CT scenario) or 384.1 Tg C (RCP 8.5 scenario) in 2100. For Q. variabilis forests, the C stocks increased from 124.4 Tg C in 2012 to 219.5 (CT scenario) or 204.7 (RCP 8.5 scenario) Tg C in 2100. Compared to 5th NFI data, the initial value of C stocks in dead organic matter C pools seemed valid. Accordingly, the annual C sequestration rates of the two species over the simulation period under the RCP 8.5 scenario (65.8 and 164.2 g C m yr for P. densiflora and Q. variabilis) were lower than those values under the CT scenario (71.1 and 193.5 g C m yr for P. densiflora and Q. variabilis). We concluded that the C sequestration potential of P. densiflora and Q. variabilis forests could be decreased by climate change. Although there were uncertainties from parameters and model structure, this study could contribute to elucidating the C dynamics of South Korean forests in future.

Estimating the age-dependent changes in carbon stocks of Scots pine (Pinus sylvestris L.) stands in Turkey

Abstract• Key messageSimulated and observed carbon stocks in Scots pine forests varied considerably with stand age. The contribution of biomass to the total forest carbon stocks increased and that of dead organic matter decreased with increasing stand age.• Context Understanding changes in forest carbon stocks over time is important to estimate carbon inventory. Although Scots pine (Pinus sylvestris L.) is a main species in Turkey, studies on such changes are still lacking.• Aims We aimed to estimate the changes in carbon stocks, with stand age, of Scots pine stands in Turkey using field work data and a forest carbon model (FBDC model).• Methods Biomass and dead organic matter carbon stocks were investigated to adjust the forest carbon model and to verify the model estimates. Forest carbon stocks with regards to stand age were simulated.• Results The simulated carbon stocks were generally in clear agreement with the observed values on a stand scale. Changes in simulated and observed carbon stocks of biomass and dead organic matter varied with stand age. The contribution of biomass to total forest carbon stocks increased, and that of dead organic matter decreased, with increasing stand age.• Conclusion We found that the carbon stocks in each pool and their contribution to the total forest carbon stocks varied with stand age. Our results are expected to contribute to the understanding of annual changes in the carbon stocks of Turkish forests.

Desertification monitoring by LANDSAT TM satellite imagery

The desertification tendency of the Qubqi Desert in China for 10 years was investigated using vegetation and soil change indices extracted from seven LANDSAT TM images. To identify the desertification tendency, two methods were applied. In the first, the desertification extent and tendency were determined by classifying the land cover into the following four categories using the Normalized Difference Vegetation Index (NDVI): floating desert area, half-fixed sand area, fixed sand area, and grassland. In the second, the degree of desertification was classified using the Modified Soil Adjusted Vegetation Index (MSAVI): primitive state, latent state, slight desertification, medium desertification, and high-degree desertification. The study results demonstrated that expansion of desertification was mostly clear in the eastern Qubqi and the neighboring farming land area.

Estimating the effect of abandoning coppice management on carbon sequestration by oak forests in Turkey with a modeling approach

A significant area of the oak forests in Turkey has been historically managed by short-rotation coppicing for wood production. Coppice management was almost abandoned in Turkey in 2006 and so investigating its impact on forest carbon (C) sequestration has become an important issue. Therefore, we investigated the net effect of this change in management on C sequestration by oak forests in Turkey using field measurement data and a forest C model (Forest Biomass and Dead organic matter Carbon (FBDC) model). The FBDC model estimated the annual forest C dynamics and considered the effect of the substitution of wood for fossil fuels under two management scenarios over a 100-year period: (1) abandoning coppice (no management) and (2) continuing coppice (20-year-interval harvest). The field measurement data were used to parameterize the FBDC model to the study sites and to verify the simulated C stocks. Continuing coppice management constrained an increase in the C stocks (116.0-140.3 Mg C ha-1) and showed a mean annual C sequestration of 0.6 Mg C ha-1 yr-1 if wood was substituted for fossil fuels. In contrast, abandoning coppicing practices increased the level of forest C stocks (128.1-236.2 Mg C ha-1), enhancing the mean annual C sequestration to 1.1 Mg C ha-1 yr-1. Accordingly, the abandonment of coppice management increased the mean annual C sequestration by 0.5 Mg C ha-1 yr-1 in the long-term. However, sensitivity analysis showed a possibility of a larger difference in C sequestration between the two scenarios due to a decrease in the stand productivity by repeated coppices and a high likelihood of a lower substitution effect. The verification supported the scientific reliability of the simulation results. Our study can provide a scientific basis for enhancing C sequestration in coppice forests.

Organic perylene single crystal based field-effect transistor

We report on the fabrication and characteristics of organic field-effect transistors (OFETs) using a single crystal of perylene. Perylene single crystals were relatively fast grown in furnace with flowing nitrogen gas. The OFETs were prepared by placing a perylene single crystal flake onto SiO2/Si or polymer insulator/Si substrates. The field-effect mobility of the perylene based OFETs temperature. was measured to be 1.6 times 10-4cm2 /Vs at room