Jord Prangsma

Atomically flat single-crystalline gold nanostructures for plasmonic nanocircuitry

Deep subwavelength integration of high-definition plasmonic nanostructures is of key importance in the development of future optical nanocircuitry for high-speed communication, quantum computation and lab-on-a-chip applications. To date, the experimental realization of proposed extended plasmonic networks consisting of multiple functional elements remains challenging, mainly because of the multi-crystallinity of commonly used thermally evaporated gold layers. This can produce structural imperfections in individual circuit elements that drastically reduce the yield of functional integrated nanocircuits. In this paper we demonstrate the use of large (>100 μm(2)) but thin (<80 nm) chemically grown single-crystalline gold flakes that, after immobilization, serve as an ideal basis for focused ion beam milling and other top-down nanofabrication techniques on any desired substrate. Using this methodology we obtain high-definition ultrasmooth gold nanostructures with superior optical properties and reproducible nano-sized features over micrometre-length scales. Our approach provides a possible solution to overcome the current fabrication bottleneck and realize high-definition plasmonic nanocircuitry.

Atomic-scale confinement of resonant optical fields.

In the presence of matter, there is no fundamental limit preventing confinement of visible light even down to atomic scales. Achieving such confinement and the corresponding resonant intensity enhancement inevitably requires simultaneous control over atomic-scale details of material structures and over the optical modes that such structures support. By means of self-assembly we have obtained side-by-side aligned gold nanorod dimers with robust atomically defined gaps reaching below 0.5 nm. The existence of atomically confined light fields in these gaps is demonstrated by observing extreme Coulomb splitting of corresponding symmetric and antisymmetric dimer eigenmodes of more than 800 meV in white-light scattering experiments. Our results open new perspectives for atomically resolved spectroscopic imaging, deeply nonlinear optics, ultrasensing, cavity optomechanics, as well as for the realization of novel quantum-optical devices.

Electrically-driven optical antennas

Researchers demonstrate an electrically driven nanoscale transmitter based on the broadband quantum shot noise of electrons tunnelling across a feed gap. Unlike radiowave antennas, so far optical nanoantennas cannot be fed by electrical generators. Instead, they are driven by light1 or indirectly via excited discrete states in active materials2,3 in their vicinity. Here we demonstrate the direct electrical driving of an in-plane optical antenna by the broadband quantum-shot noise of electrons tunnelling across its feed gap. The spectrum of the emitted photons is determined by the antenna geometry and can be tuned via the applied voltage. Moreover, the direction and polarization of the light emission are controlled by the antenna resonance, which also improves the external quantum efficiency by up to two orders of magnitude. The one-material planar design offers facile integration of electrical and optical circuits and thus represents a new paradigm for interfacing electrons and photons at the nanometre scale, for example for on-chip wireless communication and highly configurable electrically driven subwavelength photon sources.

Electrically Connected Resonant Optical Antennas

Electrically connected resonant optical antennas hold promise for the realization of highly efficient nanoscale electro-plasmonic devices that rely on a combination of electric fields and local near-field intensity enhancement. Here we demonstrate the feasibility of such a concept by attaching leads to the arms of a two-wire antenna at positions of minimal near-field intensity with negligible influence on the antenna resonance. White-light scattering experiments in accordance with simulations show that the optical tunability of connected antennas is fully retained. Analysis of the electric properties demonstrates that in the antenna gaps direct current (DC) electric fields of 10(8) V/m can consistently be achieved and maintained over extended periods of time without noticeable damage.

Increase of group delay and nonlinear effects with hole shape in subwavelength hole arrays

We investigate the influence of hole shape on the group delay of femtosecond laser pulses propagating through arrays of rectangular subwavelength holes in metal films. We find a pronounced dependence of the group delay on the aspect ratio of the holes in the arrays. The maximum group delay occurs near the cut-off frequency of the holes. These experimental results are found to be in good agreement with calculations. The slow propagation of light through the array gives rise to enhancement of the second harmonic generated in the structures. The observed behavior is consistent with the presence of a resonance at the cut-off frequency of the rectangular holes.

Characterization of Sierpinski carpet optical antenna at visible and near-infrared wavelengths

We present fabrication, characterization, and simulation results on an optical antenna inspired by the Sierpinski carpet fractal geometry for operation in the visible and near-infrared wavelength regions. Measurements and simulations of the far-field scattering efficiency indicate a broadband optical response. Two-photon photoluminescence images provide maps of the near-field intensity distribution, from which we extract an enhancement factor of ~70. To explore the effect of morphology on the optical response of a large assembly of particles, we also present results on an arbitrarily chosen pseudo-random configuration as well as a periodic array

Local investigation of the optical properties of subwavelength rectangular holes with a focused beam of electrons

The optical properties of rectangular subwavelength holes in a gold film are investigated using the light generated when a focused beam of electrons impinges on the sample close to the hole. Using this technique, multi-spectral maps of the holes are obtained with a resolution beyond the optical diffraction limit. The results show the influence of hole shape on the spectrum of locally scattered light. Rectangular holes of varying shape and size are investigated, and the spatial distribution of the polarization of the observed light is measured. The influence of neighbouring holes is investigated by measuring small clusters of holes.

A phased antenna array for surface plasmons

Surface plasmon polaritons are electromagnetic waves that propagate tightly bound to metal surfaces. The concentration of the electromagnetic field at the surface as well as the short wavelength of surface plasmons enable sensitive detection methods and miniaturization of optics. We present an optical frequency plasmonic analog to the phased antenna array as it is well known in radar technology and radio astronomy. Individual holes in a thick gold film act as dipolar emitters of surface plasmon polaritons whose phase is controlled individually using a digital spatial light modulator. We show experimentally, using a phase sensitive near-field microscope, that this optical system allows accurate directional emission of surface waves. This compact and flexible method allows for dynamically shaping the propagation of plasmons and holds promise for nanophotonic applications employing propagating surface plasmons.

Blinking statistics of colloidal quantum dots at different excitation wavelengths

In imaging applications the blinking of quantum dots is an ambiguous phenomenon. Although unwanted in conventional imaging, blinking is of significant relevance for super-resolution microscopy. Recent studies report on excitation-wavelength dependent quantum dot blinking, while other studies do not observe this effect. To investigate this disagreement we have systematically studied the effect of the excitation wavelength on blinking of CdSe/ZnS core–shell quantum dots that are commonly used in imaging applications. We recorded single quantum dot intensity traces for 14 different excitation wavelengths and determined for each excitation wavelength the probability to find short- ( 0.5 s) lasting bright state periods. This represents a systematic study of a larger set of excitation wavelengths than heretofore reported in the literature. For the quantum dots analyzed, we find minor variations in blinking with excitation wavelength. These variations do not follow a trend and do not correlate with features in the absorbance spectrum of the quantum dots. Our results show that in practice changing the excitation wavelength for CdSe/ZnS quantum dots does not allow optimization of blinking for e.g. super-resolution microscopy and that the effect of blinking as a function of excitation wavelength is not a salient parameter in imaging applications.

Microcantilever based distance control between a probe and a surface

We demonstrate a method to accurately control the distance between a custom probe and a sample on a {\mu}m to nm scale. The method relies on the closed-loop feedback on the angular deflection of an in-contact AFM microcantilever. High performance in stability and accuracy is achieved in this method by taking advantage of the small mechanical feedback path between surface and probe. We describe how internal error sources that find their origin in the microcantilever and feedback can be minimized to achieve an accurate and precise control up to 3 nm. In particular, we investigated how hysteresis effects in the feedback caused by friction forces between tip and substrate, can be minimized. By applying a short calibration procedure, distance control from contact to several micrometers probe-sample distance can be obtained with an absolute nanometer-scale accuracy. The method presented is compatible with any probe that can be fixed on a microcantilever chip and can be easily built into existing AFM systems.We demonstrate a method to control the distance between a custom probe and a sample on a μm to nm scale. The method relies on the closed-loop feedback on the angular deflection of an in-contact AFM microcantilever. High performance in stability and accuracy is achieved in this method by taking advantage of the small mechanical feedback path between surface and probe. We describe how internal error sources that find their origin in the microcantilever and feedback can be minimized to achieve an accurate and precise control up to 3 nm. In particular, we investigated how hysteresis effects in the feedback caused by friction forces between tip and substrate can be minimized. By applying a short calibration procedure, distance control from contact to several micrometers probe-sample distance can be obtained with an absolute nanometer-scale accuracy. The method presented is compatible with any probe that can be fixed on a microcantilever chip and can be easily built into existing AFM systems.