Jordi Ortín

Preisach modeling of hysteresis for a pseudoelastic Cu-Zn-Al single crystal

Stress‐strain trajectories associated with pseudoelastic behavior of a Cu‐19.4 Zn‐13.1 Al (at. %) single crystal at room temperature have been determined experimentally. For a constant cross‐head speed the trajectories and the associated hysteresis behavior are perfectly reproducible; the trajectories exhibit memory properties, dependent only on the values of return points, where transformation direction is reverted. An adapted version of the Preisach model for hysteresis has been implemented to predict the observed trajectories, using a set of experimental first‐order reversal curves as input data. Explicit formulas have been derived giving all trajectories in terms of this data set, with no adjustable parameters. Comparison between experimental and calculated trajectories shows a much better agreement for descending than for ascending paths, an indication of a dissymmetry between the dissipation mechanisms operative in forward and reverse directions of martensitic transformation.

Hysteresis in shape-memory alloys

We present an overview of hysteresis phenomena in the martensitic transformation, and their relevance in the thermomechanical behaviour of shape-memory alloys. The first part of the paper introduces the concept of hysteresis, and the related phenomena of branching, dissipation and memory. The second part deals with revising some aspects of the thermomechanical behaviour of shape-memory alloys, emphasizing the hysteretic behaviour of single crystals and polycrystals under different driving conditions. The last part of the work is dedicated to the problem of modelling hysteresis phenomena in shape-memory alloys. Our focus is on phenomenological approaches which, as shown in the paper, account for the memory properties observed in hysteretic trajectories and open the possibility of deriving a generic energy balance for systems with hysteresis.

Low viscosity contrast fingering in a rotating Hele-Shaw cell

We study the fingering instability of a circular interface between two immiscible liquids in a radial Hele-Shaw cell. The cell rotates around its vertical symmetry axis, and the instability is driven by the density difference between the two fluids. This kind of driving allows studying the interfacial dynamics in the particularly interesting case of an interface separating two liquids of comparable viscosity. An accurate experimental study of the number of fingers emerging from the instability reveals a slight but systematic dependence of the linear dispersion relation on the gap spacing. We show that this result is related to a modification of the interface boundary condition which incorporates stresses originated from normal velocity gradients. The early nonlinear regime shows nearly no competition between the outgrowing fingers, characteristic of low viscosity contrast flows. We perform experiments in a wide range of experimental parameters, under conditions of mass conservation (no injection), and characterize the resulting patterns by data collapses of two characteristic lengths: the radius of gyration of the pattern and the interface stretching. Deep in the nonlinear regime, the fingers which grow radially outwards stretch and become gradually thinner, to a point that the fingers pinch and emit drops. We show that the amount of liquid emitted in the first generation of drops is a constant independent of the experimental parameters. Further on there is a sharp reduction of the amount of liquid centrifugated, punctuated by periods of no observable centrifugation.

Radial displacement of a fluid annulus in a rotating Hele-Shaw cell

The radial displacement of a fluid annulus in a rotating circular Hele–Shaw cell has been investigated experimentally. It has been found that the flow depends sensitively on the wetting conditions at the outer interface. Displacements in a prewet cell are well described by Darcy’s law in a wide range of experimental parameters, with little influence of capillary effects. In a dry cell, however, a more careful analysis of the interface motion is required; the interplay between a gradual loss of fluid at the inner interface, and the dependence of capillary forces at the outer interface on interfacial velocity and dynamic contact angle, result in a constant velocity for the interfaces. The experimental results in this case correlate in the form of an empirical scaling relation between the capillary number Ca and a dimensionless group, related to the ratio of centrifugal to capillary forces, which spans about three orders of magnitude in both quantities. Finally, the relative thickness of the coating film lef...

Interface roughening in Hele-Shaw flows with quenched disorder: Experimental and theoretical results

We study the forced fluid invasion of an air-filled model porous medium at constant flow rate, in 1+1 dimensions, both experimentally and theoretically. We focus on the nonlocal character of the interface dynamics, due to liquid conservation, and its effect on the scaling properties of the interface upon roughening. Specifically, we study the limit of large flow rates and weak capillary forces. Our theory predicts a roughening behaviour characterized at short times by a growth exponent β1 = 5/6, a roughness exponent α1 = 5/2, and a dynamic exponent z1 = 3, and by β2 = 1/2, α2 = 1/2, and z2 = 1 at long times, before saturation. This theoretical prediction is in good agreement with the experiments at long times. The ensemble of experiments, theory, and simulations provides evidence for a new universality class of interface roughening in 1+1 dimensions.

Interfacial instabilities of a fluid annulus in a rotating Hele–Shaw cell

We have studied the interfacial instabilities experienced by a liquid annulus as it moves radially in a circular Hele–Shaw cell rotating with angular velocity Ω. The instability of the leading interface (oil displacing air) is driven by the density difference in the presence of centrifugal forcing, while the instability of the trailing interface (air displacing oil) is driven by the large viscosity contrast. A linear stability analysis shows that the stability of the two interfaces is coupled through the pressure field already at a linear level. We have performed experiments in a dry cell and in a cell coated with a thin fluid layer on each plate, and found that the stability depends substantially on the wetting conditions at the leading interface. Our experimental results of the number of fingers resulting from the instability compare well with the predictions obtained through a numerical integration of the coupled equations derived from a linear stability analysis. Deep in the nonlinear regime we observ...

Anomalous roughening of viscous fluid fronts in spontaneous imbibition.

We report experiments on spontaneous imbibition of a viscous fluid by a model porous medium in the absence of gravity. The average position of the interface satisfies Washburns law. Scaling of the interface fluctuations provides a dynamic exponent z \simeq 3, indicative of global dynamics driven by capillary forces. The complete set of exponents clearly shows that interfaces are not self-affine, exhibiting distinct local and global scaling, both for time (b=0.64\pm 0.02, b* =0.33 \pm 0.03) and space (a=1.94 \pm 0.20, a_loc=0.94 \pm 0.10). These values are compatible with an intrinsic anomalous scaling scenario.

State equation for shape‐memory alloys: Application to Cu‐Zn‐Al

We deal with the hysteretic behavior of partial cycles in the two‐phase region associated with the martensitic transformation of shape‐memory alloys. We consider the problem from a thermodynamic point of view and adopt a local equilibrium formalism, based on the idea of thermoelastic balance, from which a formal writing follows a state equation for the material in terms of its temperature T, external applied stress σ, and transformed volume fraction x. To describe the striking memory properties exhibited by partial transformation cycles, state variables (x,σ,T) corresponding to the current state of the system have to be supplemented with variables (x,σ,T) corresponding to points where the transformation control parameter (−σ and/or T) had reached a maximum or a minimum in the previous thermodynamic history of the system. We restrict our study to simple partial cycles resulting from a single maximum or minimum of the control parameter. Several common features displayed by such partial cycles and repeatedly...

Measurements of the bulk and interfacial velocity profiles in oscillating Newtonian and Maxwellian fluids.

We present the dynamic velocity profiles of a Newtonian fluid (glycerol) and a viscoelastic Maxwell fluid (CPyCl-NaSal in water) driven by an oscillating pressure gradient in a vertical cylindrical pipe. The frequency range explored has been chosen to include the first three resonance peaks of the dynamic permeability of the viscoelastic-fluid--pipe system. Three different optical measurement techniques have been employed. Laser Doppler anemometry has been used to measure the magnitude of the velocity at the center of the liquid column. Particle image velocimetry and optical deflectometry are used to determine the velocity profiles at the bulk of the liquid column and at the liquid-air interface respectively. The velocity measurements in the bulk are in good agreement with the theoretical predictions of a linear theory. The results, however, show dramatic differences in the dynamic behavior of Newtonian and viscoelastic fluids, and demonstrate the importance of resonance phenomena in viscoelastic fluid flows, biofluids in particular, in confined geometries.

Anomalous roughening of Hele-Shaw flows with quenched disorder

The kinetic roughening of a stable oil-air interface moving in a Hele-Shaw cell that contains a quenched columnar disorder (tracks) has been studied. A capillary effect is responsible for the dynamic evolution of the resulting rough interface, which exhibits anomalous scaling. The three independent exponents needed to characterize the anomalous scaling are determined experimentally. The anomalous scaling is explained in terms of the initial acceleration and subsequent deceleration of the interface tips in the tracks coupled by mass conservation. A phenomenological model that reproduces the measured global and local exponents is introduced.