Jorge Sanjurjo Sánchez

TL and OSL Dating of Sediment and Pottery from Two Syrian Archaeological Sites

TL and OSL Dating of Sediment and Pottery from Two Syrian Archaeological Sites Luminescence dating is widely applied nowadays, mainly for archaeological material and artefacts and sediments of all types and origins. However, optically stimulated luminescence (OSL) from archaeological sediment, originated from mud brick buildings has been hardly studied. The archaeological sites of Tall Abu Fahd and Tall Qsubi are located in the Middle Euphrates Valley, Deir ez-Zor district, Syria. These two Bronze Age sites were recently discovered by a Spanish-Syrian team from the Directorate General of Antiquities and Museums (Damascus) and the University of Coruña. Both sites were dated (about 3.5 ka BC) by typological pottery classification. Sediment and pottery samples from these archaeological sites were collected for luminescence dating. Several analytical procedures for obtaining equivalent doses were tested on the sediment samples. Blue OSL from quartz subsamples and IRSL, post IRSL Blue OSL from feldspar contaminated quartz and polymineral subsamples were performed to obtain OSL ages. For the pottery samples, additive dose TL on a coarse grain feldspar contaminated quartz subsample was performed as well. Results have shown agreement among all the luminescence procedures tested on the Tall Abu Fahd site samples after fading correction, showing ages around 2.7 ka BP. Obtained ages from the other site samples show disagreement among quartz blue OSL and the other subsamples. Fading ratios allow correcting age underestimations from the polymineral post-IR OSL signal. However, the polymineral IRSL signal still shows underestimation. Final sediment and pottery ages have shown good agreement. Older 14C independent age (3.32 ka BP) corresponds to occupational periods of the site while sediment ages are attributed to a post occupation phase.

A SIMPLE METHOD TO SEPARATE QUARTZ AND FELDSPAR AND ITS APPLICATION TO TL/OSL METHODS

A Simple Method to Separate Quartz and Feldspar and its Application to TL/OSL Methods In the dating of sediments by luminescence methods, to obtain a sample the purest possible as to its mineralogy determines the rest of the analytical procedures. The isolation of the sample minerals is a critical stage due to the impossibility of quantifying the relative contributions to the dose from the different minerals. In this paper we propose a non chemical method to isolate quartz from feldspar extracted from different aeolian and fluvial sediments. Grinding together quartz and feldspar grains in an agate mortar results in crushing the feldspar fraction due to its smaller hardness. Later sieving of the grinded mixture enables simple separation of both fractions. Then it is possible to save the feldspar fraction for later analyses instead of losing it as it occurs when using acid etching. Also, we study the evolution of the feldspar abundance along different purification steps with acid etching or grinding with two numerical indexes. We conclude that the grinding procedure can be introduced in the purification methods as an effective way to separate quartz from feldspar. Nonetheless, it is not an standalone procedure to obtain pure quartz and must be combined with chemical methods when the sample is rich in feldspar minerals.

Post-depositional processes of elemental enrichment inside dark nodular masses of an ancient aeolian dune from A Coruña, Northwest Spain

This paper focuses on a residual ancient aeolian climbing dune from Punta Penaboa (A Coruna, Northwest Spain) showing evidence of post-depositional weathering, particularly the presence of dark brown nodular masses. The partitioning of trace elements between nodular masses and host sand during post-depositional weathering of the dune is investigated in this work, with the main objective of studying the elemental enrichment patterns in the dark masses. Data of the concentrations of chemical elements were obtained by instrumental neutron activation analysis (INAA) and complemented by mineralogical and microchemical studies, using X-ray powder diffraction (XRD) and scanning electron microscopy (SEM) / energy dispersive X-ray spectrometry (EDS). The dune was dated by optically stimulated luminescence (OSL) , yielding an age of 300ka B.P.. The dark nodular masses preserved the dune sand structure, without defined concentric layers, suggesting an early stage of formation. They consist mainly of quartz grains cemented by clay materials enriched in the majority of the elements studied, especially in Mn, Co, Ba, Sb, Ce, Tb, Th, As, Zr and Hf. The post-depositional transformations of the dune were most likely influenced by migration of chemical compounds from the surrounding slope deposits and granitic rocks, as well as microbial activity that promoted metals concentration in the solutions percolating through the pore network of the dune. Seasonal changes in the redox potential were required to produce the accumulation of Mn and other trace elements in the dune pore network and to promote the fractionation between Ce4+ and trivalent rare earth elements that was observed in the geochemical patterns.