José Francisco Algorri

Electrical response of liquid crystal cells doped with multi-walled carbon nanotubes

Summary The inclusion of nanoparticles modifies a number of fundamental properties of many materials. Doping of nanoparticles in self-organized materials such as liquid crystals may be of interest for the reciprocal interaction between the matrix and the nanoparticles. Elongated nanoparticles and nanotubes can be aligned and reoriented by the liquid crystal, inducing noticeable changes in their optical and electrical properties. In this work, cells of liquid crystal doped with high aspect ratio multi-walled carbon nanotubes have been prepared, and their characteristic impedance has been studied at different frequencies and excitation voltages. The results demonstrate alterations in the anisotropic conductivity of the samples with the applied electric field, which can be followed by monitoring the impedance evolution with the excitation voltage. Results are consistent with a possible electric contact between the coated substrates of the LC cell caused by the reorientation of the nanotubes. The reversibility of the doped system upon removal of the electric field is quite low.

Modal liquid crystal array of optical elements

In this study, a novel liquid crystal array based on modal control principle is proposed and demonstrated. The advanced device comprises a six striped electrode structure that forms a configurable 2D matrix of optical elements. A simulation program based on the Frank-Oseen equations and modal control theory has been developed to predict the device electrooptic response, that is, voltage distribution, interference pattern and unwrapped phase. A low-power electronics circuit, that generates complex waveforms, has been built for driving the device. A combined variation of the waveform amplitude and phase has provided a high tuning versatility to the device. Thus, the simulations have demonstrated the generation of a liquid crystal prism array with tunable slope. The proposed device has also been configured as an axicon array. Test measurements have allowed us to demonstrate that electrooptic responses, simulated and empirical, are fairly in agreement.

An autostereoscopic device for mobile applications based on a liquid crystal microlens array and an OLED display

In recent years, many experimental and theoretical research groups worldwide have actively worked on demonstrating the use of liquid crystals (LCs) as adaptive lenses for image generation, waveform shaping, and non-mechanical focusing applications. In particular, important achievements have concerned the development of alternative solutions for 3D vision. This work focuses on the design and evaluation of the electro-optic response of a LC-based 2D/3D autostereoscopic display prototype. A strategy for achieving 2D/3D vision has been implemented with a cylindrical LC lens array placed in front of a display; this array acts as a lenticular sheet with a tunable focal length by electrically controlling the birefringence. The performance of the 2D/3D device was evaluated in terms of the angular luminance, image deflection, crosstalk, and 3D contrast within a simulated environment. These measurements were performed with characterization equipment for autostereoscopic 3D displays (angular resolution of 0.03°).

Note: Electrical modeling and characterization of voltage gradient in liquid crystal microlenses

In this work, a novel equivalent electric circuit for modeling liquid crystal microlenses is proposed. This model is focused on explaining a lens behavior at the micrometric scale, using its manufacturing parameters. It suggests an approach to predict the solution of the voltage gradient distribution across a microlens. An interesting feature of the model is that it provides an analytical solution for microlenses with modal and hole-patterned electrode schemes, by a simple software tool. The model flexibility allows lens designers to apply complex waveform signals with different harmonics. The voltage distribution has been tested. The simulated and measured voltage profiles are fairly in agreement.

Electrooptic Characterization of Tunable Cylindrical Liquid Crystal Lenses

In this work, one-dimensional arrays of cylindrical adaptive liquid crystal lenses were manufactured and characterized; and test devices were filled with nematic liquid crystal. Comb interdigitated electrodes were designed as a mask pattern for the control electrode on the top glass substrates. A radial graded refractive index along each microsized lens was achieved by fabricating a layer of high resistance sheet deposited as a control electrode. These tunable lenses were switched by applying amplitude and frequency optimized waveforms on the control electrode. Phase profiles generated by the radial electric field distribution on each lens were measured by a convectional interferometric technique.

Reflective sidewall electrodes for low voltage and high transmittance blue-phase liquid crystal displays

The typical sidewalls produced in the fabrication of protrusion electrodes are proposed to create a low voltage (4.5 Vrms) and high transmittance (93%) blue-phase liquid crystal display (BP-LCD). The tilted electrodes produce a strong horizontal electrical field that reduces the operating voltage considerably. The common problem of the ‘dead zones’ is solved by reflecting the light onto the electrodes. In order to estimate the phase retardation of the reflected light, a ray tracing simulation program for anisotropic mediums has been developed. The proposed device is more competitive than vertical field switching based BP-LCD and also, has the advantages of protruded in-plane-switching structures. These facts make this technology a potential candidate for the next generation of BP-LCDs.

A Novel High-Sensitivity, Low-Power, Liquid Crystal Temperature Sensor

A novel temperature sensor based on nematic liquid crystal permittivity as a sensing magnitude, is presented. This sensor consists of a specific micrometric structure that gives considerable advantages from other previous related liquid crystal (LC) sensors. The analytical study reveals that permittivity change with temperature is introduced in a hyperbolic cosine function, increasing the sensitivity term considerably. The experimental data has been obtained for ranges from −6 °C to 100 °C. Despite this, following the LC datasheet, theoretical ranges from −40 °C to 109 °C could be achieved. These results have revealed maximum sensitivities of 33 mVrms/°C for certain temperature ranges; three times more than of most silicon temperature sensors. As it was predicted by the analytical study, the micrometric size of the proposed structure produces a high output voltage. Moreover the voltages sensitivity to temperature response can be controlled by the applied voltage. This response allows temperature measurements to be carried out without any amplification or conditioning circuitry, with very low power consumption.

Generation of Optical Vortices by an Ideal Liquid Crystal Spiral Phase Plate

An ideal spiral phase plate based on liquid crystals and two high resistivity layers is proposed and theoretically analyzed. The proposed structure generates a spiral-like voltage with simple voltage control. The liquid crystal layer produces an optical phase shift that depends on the voltage distribution. These two effects cause light passing through the device to be twisted like a corkscrew around its travel axis. Because of the continuous phase shift, the proposed device is expected to exhibit a conversion efficiency of ~100%. In addition, this device is more efficient and simpler than previously reported optical vortex generators. Moreover, the device is completely reconfigurable, i.e., the operating wavelengths and topological charges are tunable. The device can be used to reduce the fabrication costs of current devices and generate different orbital angular momentum modes with improved light efficiency, simplicity, and possibility of reconfiguration.

The peculiar electrical response of liquid crystal-carbon nanotube systems as seen by impedance spectroscopy

Conductive nanoparticles, especially elongated ones such as carbon nanotubes, dramatically modify the electrical behavior of liquid crystal cells. These nanoparticles are known to reorient with liquid crystals in electric fields, causing significant variations of conductivity at minute concentrations of tens or hundreds ppm. The above notwithstanding, impedance spectroscopy of doped cells in the frequency range customarily employed by liquid crystal devices, 100 Hz–10 kHz, shows a relatively simple resistor/capacitor response where the components of the cell can be univocally assigned to single components of the electrical equivalent circuit. However, widening the frequency range up to 1 MHz or beyond reveals a complex behavior that cannot be explained with the same simple EEC. Moreover, the system impedance varies with the application of electric fields, their effect remaining after removing the field. Carbon nanotubes are reoriented together with liquid crystal reorientation when applying voltage, but barely reoriented back upon liquid crystal relaxation once the voltage is removed. Results demonstrate a remarkable variation in the impedance of the dielectric blend formed by liquid crystal and carbon nanotubes, the irreversible orientation of the carbon nanotubes and possible permanent contacts between electrodes.

Fiber Optic Temperature Sensor Based on Amplitude Modulation of Metallic and Semiconductor Nanoparticles in a Liquid Crystal Mixture

The response of an amplitude modulation temperature sensor based on a liquid crystal doped with either metallic or semiconductor nanoparticles has been theoretically analyzed. The effects of the concentration, the type of nanoparticle material, and liquid crystal compound have been studied in detail. The high sensitivity of light resonances to refraction index changes, in collaboration with the high thermooptic coefficients of liquid crystal materials, has resulted in the design of an optical fiber sensor with high temperature sensitivity. This sensitivity has been demonstrated to be dependent on nanoparticle concentration. A maximum theoretical sensitivity of 64 × 10-2 dB/°C has been observed. Moreover, the sensitivity is highly linear with a regression coefficient of 99.99%.