Jose L. Pantoja

Understanding the DayCent model

The ability of biogeochemical ecosystem models to represent agro-ecosystems depends on their correct integration with field observations. We report simultaneous calibration of 67 DayCent model parameters using multiple observation types through inverse modeling using the PEST parameter estimation software. Parameter estimation reduced the total sum of weighted squared residuals by 56% and improved model fit to crop productivity, soil carbon, volumetric soil water content, soil temperature, N2O, and soil NO 3 - compared to the default simulation. Inverse modeling substantially reduced predictive model error relative to the default model for all model predictions, except for soil NO 3 - and NH 4 + . Post-processing analyses provided insights into parameter-observation relationships based on parameter correlations, sensitivity and identifiability. Inverse modeling tools are shown to be a powerful way to systematize and accelerate the process of biogeochemical model interrogation, improving our understanding of model function and the underlying ecosystem biogeochemical processes that they represent. Several DayCent submodels were calibrated simultaneously using inverse modeling.Parameter estimation reduced DayCent total sum of weighted squared residuals by 56%.Soil temperature and water content are highly informative in DayCent calibration.Parameter estimation is an efficient way to calibrate soil biogeochemical models.Post-estimation analyses provide unique insights into model structure and function.

Does nitrogen fertilizer application rate to corn affect nitrous oxide emissions from the rotated soybean crop

Little information exists on the potential for N fertilizer application to corn ( L.) to affect NO emissions during subsequent unfertilized crops in a rotation. To determine if N fertilizer application to corn affects NO emissions during subsequent crops in rotation, we measured NO emissions for 3 yr (2011-2013) in an Iowa, corn-soybean [ (L.) Merr.] rotation with three N fertilizer rates applied to corn (0 kg N ha, the recommended rate of 135 kg N ha, and a high rate of 225 kg N ha); soybean received no N fertilizer. We further investigated the potential for a winter cereal rye ( L.) cover crop to interact with N fertilizer rate to affect NO emissions from both crops. The cover crop did not consistently affect NO emissions. Across all years and irrespective of cover crop, N fertilizer application above the recommended rate resulted in a 16% increase in mean NO flux rate during the corn phase of the rotation. In 2 of the 3 yr, N fertilizer application to corn (0-225 kg N ha) did not affect mean NO flux rates from the subsequent unfertilized soybean crop. However, in 1 yr after a drought, mean NO flux rates from the soybean crops that received 135 and 225 kg N ha N application in the corn year were 35 and 70% higher than those from the soybean crop that received no N application in the corn year. Our results are consistent with previous studies demonstrating that cover crop effects on NO emissions are not easily generalizable. When N fertilizer affects NO emissions during a subsequent unfertilized crop, it will be important to determine if total fertilizer-induced NO emissions are altered or only spread across a greater period of time.

Soil Inorganic Nitrogen with Incubation of Rye Cover Crop Biomass

ABSTRACT A soil incubation study was conducted to evaluate the effect of winter cereal rye (Secale cereale L.) cover crop (CC) biomass and fertilizer nitrogen (N) addition on soil inorganic-N. Rye aboveground biomass was collected following corn (Zea mays L.) and soybean [Glycine max (L.) Merr.], and incubated at equivalent field temperatures for 105 d at rates of 1120, 2240, and 3360 kg dry matter (DM) ha−1. Despite N addition from the rye biomass at any rate, there was no real effect on ammonium (NH4)-N, and only from 63 d to 105 d a limited net increase in nitrate (NO3)-N and inorganic-N was observed compared to no-rye. Nitrate-N and inorganic-N concentrations change per heat unit (HU) accumulation was negative with rye addition through 7 d, but was positive consistently across the remaining incubation period with or without rye. Overall, the rye CC biomass had only a neutral to small positive effect on soil inorganic-N.