José Manuel Grajales-Nishimura

The Chicxulub Asteroid Impact and Mass Extinction at the Cretaceous-Paleogene Boundary

The Fall of the Dinosaurs According to the fossil record, the rule of dinosaurs came to an abrupt end ∼65 million years ago, when all nonavian dinosaurs and flying reptiles disappeared. Several possible mechanisms have been suggested for this mass extinction, including a large asteroid impact and major flood volcanism. Schulte et al. (p. 1214) review how the occurrence and global distribution of a global iridium-rich deposit and impact ejecta support the hypothesis that a single asteroid impact at Chicxulub, Mexico, triggered the extinction event. Such an impact would have instantly caused devastating shock waves, a large heat pulse, and tsunamis around the globe. Moreover, the release of high quantities of dust, debris, and gases would have resulted in a prolonged cooling of Earths surface, low light levels, and ocean acidification that would have decimated primary producers including phytoplankton and algae, as well as those species reliant upon them. The Cretaceous-Paleogene boundary ~65.5 million years ago marks one of the three largest mass extinctions in the past 500 million years. The extinction event coincided with a large asteroid impact at Chicxulub, Mexico, and occurred within the time of Deccan flood basalt volcanism in India. Here, we synthesize records of the global stratigraphy across this boundary to assess the proposed causes of the mass extinction. Notably, a single ejecta-rich deposit compositionally linked to the Chicxulub impact is globally distributed at the Cretaceous-Paleogene boundary. The temporal match between the ejecta layer and the onset of the extinctions and the agreement of ecological patterns in the fossil record with modeled environmental perturbations (for example, darkness and cooling) lead us to conclude that the Chicxulub impact triggered the mass extinction.

Coeval 40Ar/39Ar Ages of 65.0 Million Years Ago from Chicxulub Crater Melt Rock and Cretaceous-Tertiary Boundary Tektites

40Ar/39Ar dating of drill core samples of a glassy melt rock recovered from beneath a massive impact breccia contained within the 180-kilometer subsurface Chicxulub crater in Yucat�n, Mexico, has yielded well-behaved incremental heating spectra with a mean plateau age of 64.98 � 0.05 million years ago (Ma). The glassy melt rock of andesitic composition was obtained from core 9 (1390 to 1393 meters) in the Chicxulub 1 well. The age of the melt rock is virtually indistinguishable from 40Ar/39Ar ages obtained on tektite glass from Beloc, Haiti, and Arroyo el Mimbral, northeastern Mexico, of 65.01 � 0.08 Ma (mean plateau age for Beloc) and 65.07 � 0.10 Ma (mean total fusion age for both sites). The 40Ar/39Ar ages, in conjunction with geochemical and petrological similarities, strengthen the recent suggestion that the Chicxulub structure is the source for the Haitian and Mexican tektites and is a viable candidate for the Cretaceous-Tertiary boundary impact site.

Chicxulub impact: The origin of reservoir and seal facies in the southeastern Mexico oil fields

Stratigraphic and mineralogic studies of Cretaceous-Tertiary (K-T) boundary sections demonstrate that the offshore oil-producing breccias and seals from oil fields in the Campeche marine platform are of K-T boundary age and that their mode of formation is probably related to the K-T impact event at Chicxulub. The oil-producing carbonate breccia and the overlying dolomitized ejecta layer (seal) found in several wells on the Campeche marine platform contain typical Chicxulub impact products, such as shocked quartz and plagioclase, and altered glass. These offshore units are correlated with thick (∼50–300 m) onshore breccia and impact ejecta layers found at the K-T boundary in the Guayal (Tabasco) and Bochil (Chiapas) sections. Regionally the characteristic sequence is composed of, from base to top, coarse-grained carbonate breccia covered by an ejecta bed and typical K-T boundary clay. The onshore and offshore breccia sequences are likely to have resulted from major slumping of the carbonate platform margin triggered by the Chicxulub impact. Successive arrival times in this area, ∼350–600 km from the crater, of seismic shaking, ballistic ejecta, and tsunami waves fit the observed stratigraphic sequence. The K-T breccia reservoir and seal ejecta layer of the Cantarell oil field, with a current daily production of 1.3 million barrels of oil, are probably the most important known oil-producing units related to an impact event.

Geochemistry of paleozoic basalts from the Juchatengo complex of southern Mexico: tectonic implications

Abstract Analyses of Lower Permian or older basalts and associated dykes of the Juchatengo sequence indicate that they are rift tholeiites that formed in a continental rift or back-arc tectonic setting. Age constraints include a Middle Permian fossil recovered from the tectonically overlying sediments and a cross-cutting, post-tectonic pluton dated by K/Ar on hornblende at 282±6 Ma. A location adjacent to the Oaxacan Complex or other old continental crust is suggested by (1) an e Nd i isotopic value of −8.95 and a T DM age of 1487 Ma in the overlying sediments, which are similar to the Oaxacan Complex; (2) enrichment of incompatible elements in the lavas, suggesting old crustal contamination; and (3) the presence of Permian–Triassic calc-alkaline plutons that stitch the Juchatengo–Oaxaca boundary. The possible tectonic models depend on the age of the Juchatengo basalts, which requires future geochronological work. If the Juchatengo basalts are Permo-Carboniferous, they could have formed near the eastern edge of a back-arc basin: the contemporaneous arc would have rifted away to the west. Eastward migration of the arc magmatism indicated by the Permian–Triassic calc-alkaline plutonism may reflect shallowing of the dip of the subduction zone, which probably also produced the deformation of the Juchatengo sequence.

Cretaceous-Paleogene boundary deposits at Loma Capiro, central Cuba: Evidence for the Chicxulub impact

A newly discovered Upper Cretaceous to lower Paleogene section at Loma Capiro (central Cuba) has provided new evidence for a Cretaceous-Paleogene boundary age for the Chicxulub impact. The studied sediments at Loma Capiro consist of a foraminifera-rich marl and sandstone hemipelagic sequence, and a 9.6-m-thick intercalated clastic complex. Planktic foraminifera indicate an upper Maastrichtian age for the sediments below the clastic complex and a lowermost Danian age for those just above this complex. Small benthic foraminifera from below and above the clastic complex indicate deposition at middle to lower bathyal depths. The fining-upward clastic complex consists of a basal breccia that is overlain by microconglomerates and coarse- to fine-grained sandstones. The clastic complex contains reworked foraminifera from different ages and different paleoenvironments and, toward the top, impact material such as altered microtektites, shocked quartz, terrestrial chondrules, and accretionary lapilli. These microfacies suggest deposition from gravity flows that eroded sediments from upper-slope and shelf settings and redeposited them in deeper bathyal environments. We suggest that the origin of the clastic complex may be linked to the collapse of the Cuban platform, triggered by the Cretaceous-Paleogene impact at Chicxulub.

Cretaceous-Tertiary boundary planktic foraminiferal mass extinction and biochronology at La Ceiba and Bochil, Mexico, and El Kef, Tunisia

Micropaleontology studies across the Cretaceous-Tertiary (K-T) boundary from sections at La Ceiba, Bochil, Mexico, and El Kef, Tunisia, suggest a close cause and effect relationship between the Chicxulub impact and the K-T planktic foraminiferal mass extinction. The K-T planktic foraminiferal biostratigraphy and assemblage turnover in Mexico was examined and the approximate deposition timing of K-T-related material (clastic unit) was estimated. On the basis of established biomagnetochronologic calibrations, the first appearance datum (FAD) of Parvularugoglobigerina longiapertura occurred 3.5–5 k.y. after the K-T boundary, and the FADs of Parvularugoglobigerina eugubina, Eoglobigerina simplicissima, and Parasubbotina pseudobulloides occurred 15–17.5 k.y., 28–31 k.y., and 45–55 k.y., respectively, after the K-T boundary. According to estimated average sedimentation rates and estimated age, the K-T red layer at El Kef was probably formed in 20 yr and the deposition of the K-T clastic unit in the Gulf of Mexico was geologically instantaneous. The last appearance of most Maastrichtian species is just below the K-T impact-generated bed, clearly implying a catastrophic planktic foraminiferal mass extinction.

Brine and hydrocarbon evolution during the filling of the Cantarell Oil Field (Gulf of Mexico)

The main oil reservoir in the Cantarell Field, offshore Campeche, consists of a dolomitized carbonate breccia with an ejecta seal on top, considered to have been formed during the Chicxulub impact event. Two different dolomitization events have been identified associated with the reservoir. The first generation (D1) is a bright-red luminescent saddle dolomite while the second generation is a minute, non-luminescent dolomite (D2). Brine fluid inclusions show an evolution from D1 to D2 to higher temperatures (from 80–120 to 100–120 jC) and salinities (from 2–8 to 6–8 wt.% eq. NaCl). Hydrocarbon-bearing fluid inclusions evolved from heavy oils to light oils in D1 (from core to rim), while in D2, all inclusions appear to be formed by heavy oil with an jAPI similar to the oil contained in the present reservoir. These facts suggest that the end of the dolomitization process was closely related with the beginning of the main accumulation of oil into the reservoir, displacing the aqueous fluids and precluding the precipitation of carbonates. D 2003 Elsevier Science B.V. All rights reserved.

The Cretaceous–Paleogene Boundary Chicxulub Impact: Its Effect on Carbonate Sedimentation on the Western Margin of the Yucatan Platform and Nearby Areas

Outcrops and offshore Campeche borehole data clearly document the presence of a carbonate facies succession, including calcareous breccia, on the western Yucatan Platform (Campeche Sound) and the Chiapas-Tabasco Platform. This carbonate sequence is associated with ejecta that contains altered glass, shocked minerals, and accretionary lapilli derived from the Chicxulub impact on the Yucatan Platform. The Cretaceous–Paleogene (K-Pg) boundary sedimentary succession is found at the El Guayal, Bochil, and Chilil outcrops of Tabasco and Chiapas, and offshore Campeche, 300–500 km (186–311 mi) west of the Chicxulub structure center. From base to top, this succession consists of four subunits: (1) carbonate breccia, 40–300 m (131–984 ft) thick, without ejecta; (2) fine- to medium-grained carbonate breccia, 10–20 m (33–66 ft) thick, mixed with sparse ejecta; and (3) siltstone, shale, and carbonate sand facies, 9–30 m (29–98 ft) thick, containing abundant ejecta (altered glass and shocked quartz). This unit culminates in a nearly pure clay layer (2 cm [0.7 in.] thick) with the well-known iridium anomaly at the top. Unit 4 is a conglomeratic breccia ranging from 10 to 20 m (33 to 66 ft) thick containing ejecta that is interbedded with or overlays subunit 3 (the ejecta layer) in some wells. Subunits 1, 2, and 3 are highly dolomitized in offshore Campeche, and the glass in subunit 3 is altered to clay minerals (smectite). Subunits 1 and 2 constitute hydrocarbon reservoir facies, whereas subunit 3 corresponds to the sealing layer of these reservoirs. Regionally, this sequence displays a gradational structure that represents a large debris flow followed by ballistic and clastic sedimentation with materials reworked by currents. Moreover, well logs, areal distribution, and stratigraphic relationships suggest that the thick K-Pg boundary sedimentary succession is a base-of-slope apron deposit. Based on the stratigraphy, sedimentology, and distribution of impact materials in the carbonate sedimentary succession, the following sequence of events can be inferred: megaseismic shaking that induced the collapse of the platform margin and produced the lower breccia facies (subunits 1 and 2); ballistic emplacement of ejected material (carbonate fragments, shocked minerals and glass) that supplied components to subunit 2 and formed the ejecta layer (subunit 3), the latter acting as the seal for Cantarell and neighboring oil fields; and reworking of the ejecta layer and coarser-grained carbonate fragments by the effect of one or more impact-generated tsunami waves to form a conglomeratic breccia (subunit 4) within subunit 3.

Determination of true bed thickness using folded bed model and borehole data

The true bed thickness (t) is the actual thickness of a given formation perpendicular to the bedding plane. The value of t depends on the angle and the direction of the dip of the measured formation, as well as the drift angle and azimuth of the borehole. The traditional methods to calculate the parameter t consider only the case of monoclinal beds but not the case of a folded bed, which will cause deviations when the bed dip on the top is different from that on the bottom. To avoid these deviations, this paper shows an approach to calculate the values of t using a folded bed model. The deviations for the monoclinal bed model are positively related to the bed dip, the dip difference and the deviated angle of the wells. A case study from the Cantarell oil field complex in the southern Gulf of Mexico (offshore Campeche) is used to test the folded bed method. The results indicate that this model can yield more uniform spatial change of the values of t, whereas the monoclinal bed model will overestimate the average value of t. Compared to the folded bed model, the maximum relative deviation of t from the monoclinal bed model reaches 22.3% and the maximum absolute deviation of t reaches 34.5 m.