Joseph Francis Schroeder

Origin of the refractive-index increase in laser-written waveguides in glasses

We present firm evidence that the mechanism for the refractive-index increase in fused silica caused by irradiation with ultrafast intense laser pulses is the densification of glass. This conclusion is based on the correlation observed between the refractive-index values in waveguides in silica produced by focused femtosecond laser pulses and the shift of the central frequency of ω4 (TO) band (Si–O stretching mode) in micro-Raman spectra. These data were compared with the relation of the Raman shift to density and to refractive index changes in glasses modified by high pressure or irradiation. We conclude that the measured refractive-index increase in silica waveguides can be explained by densification of glass and exclude other hypothesis such as fictive-temperature effect, color center formation, etc.

Laser-written high-contrast waveguides in glass

Laser writing of waveguides in bulk glasses opens the opportunity for creating three-dimensional photonic devices. In order to become practical, the numerical aperture (NA) of these waveguides should be significantly higher than currently achievable of 0.1 - 0.15. One reason is that with higher NAs one can decrease the bending radii of the embedded photonic devices without significant loss penalty and make them compact. Thus, femtosecond-laser-written waveguides in glasses do not allow bending radii smaller than 15 - 20 mm. In order to overcome this limitation, we propose to fabricate waveguides in phase-separable and leachable glass where the index contrast is determined by the difference between the refractive indices of the unprocessed glass and of the leached porous glass. We show that we can achieve the NA = 0.25 prior to optimization. Surface and sub-surface treatment with a nanosecond ultraviolet (UV) laser produces a similar effect with even higher NA = 0.35. Applications may include a range of tightly packed embedded and three-dimensional photonic devices in bulk glass like directional couplers, splitters, interferometers, etc.

Refractive-index increase in laser-written waveguides in glasses

We present estimates of the refractive-index change in waveguides in silica produced by focused femtosecond laser pulses. The estimates are based on the shift of the central frequency of ω4 (TO) band (Si-O stretching mode) in micro-Raman spectra. These data were compared with the relation of this parameter to density and to refractive index changes in seen in glasses modified by high pressure or irradiation. We conclude that the measured refractive-index increase in the waveguides can be explained by densification of glass.