Joseph Herzog

Thermoplasmonics: Quantifying Plasmonic Heating in Single Nanowires

Plasmonic absorption of light can lead to significant local heating in metallic nanostructures, an effect that defines the subfield of thermoplasmonics and has been leveraged in diverse applications from biomedical technology to optoelectronics. Quantitatively characterizing the resulting local temperature increase can be very challenging in isolated nanostructures. By measuring the optically induced change in resistance of metal nanowires with a transverse plasmon mode, we quantitatively determine the temperature increase in single nanostructures with the dependence on incident polarization clearly revealing the plasmonic heating mechanism. Computational modeling explains the resonant and nonresonant contributions to the optical heating and the dominant pathways for thermal transport. These results, obtained by combining electronic and optical measurements, place a bound on the role of optical heating in prior experiments and suggest design guidelines for engineered structures meant to leverage such effects.

Calculated thickness dependent plasmonic properties of gold nanobars in the visible to near-infrared light regime

Metallic, especially gold, nanostructures exhibit plasmonic behavior in the visible to near-infrared light range. In this study, we investigate optical enhancement and absorption of gold nanobars with different thicknesses for transverse and longitudinal polarizations using finite element method simulations. This study also reports on the discrepancy in the resonance wavelengths and optical enhancement of the sharp-corner and round-corner nanobars of constant length 100 nm and width 60 nm. The result shows that resonance amplitude and wavelength have strong dependences on the thickness of the nanostructure as well as the sharpness of the corners, which is significant since actual fabricated structure often have rounded corners. Primary resonance mode blue-shifts and broadens as the thickess increases due to decoupling of charge dipoles at the surface for both polarizations. The broadening effect is characterized by measuring the full width at half maximum of the spectra. We also present the surface charge distribution showing dipole mode oscillations at resonance frequency and multimode resonance indicating different oscillation directions of the surface charge based on the polarization direction of the field. Results of this work give insight for precisely tuning nanobar structures for sensing and other enhanced optical applications.

Substrate Oxide Layer Thickness Optimization for a Dual-Width Plasmonic Grating for Surface-Enhanced Raman Spectroscopy (SERS) Biosensor Applications

This work investigates a new design for a plasmonic SERS biosensor via computational electromagnetic models. It utilizes a dual-width plasmonic grating design, which has two different metallic widths per grating period. These types of plasmonic gratings have shown larger optical enhancement than standard single-width gratings. The new structures have additional increased enhancement when the spacing between the metal decreases to sub-10 nm dimensions. This work integrates an oxide layer to improve the enhancement even further by carefully studying the effects of the substrate oxide thickness on the enhancement and reports ideal substrate parameters. The combined effects of varying the substrate and the grating geometry are studied to fully optimize the device’s enhancement for SERS biosensing and other plasmonic applications. The work reports the ideal widths and substrate thickness for both a standard and a dual-width plasmonic grating SERS biosensor. The ideal geometry, comprising a dual-width grating structure atop an optimal SiO2 layer thickness, improves the enhancement by 800%, as compared to non-optimized structures with a single-width grating and a non-optimal oxide thickness.

Plasmonic Au Array SERS Substrate with Optimized Thin Film Oxide Substrate Layer

This work studies the effect of a plasmonic array structure coupled with thin film oxide substrate layers on optical surface enhancement using a finite element method. Previous results have shown that as the nanowire spacing increases in the sub-100 nm range, enhancement decreases; however, this work improves upon previous results by extending the range above 100 nm. It also averages optical enhancement across the entire device surface rather than localized regions, which gives a more practical estimate of the sensor response. A significant finding is that in higher ranges, optical enhancement does not always decrease but instead has additional plasmonic modes at greater nanowire and spacing dimensions resonant with the period of the structure and the incident light wavelength, making it possible to optimize enhancement in more accessibly fabricated nanowire array structures. This work also studies surface enhancement to optimize the geometries of plasmonic wires and oxide substrate thickness. Periodic oscillations of surface enhancement are observed at specific oxide thicknesses. These results will help improve future research by providing optimized geometries for SERS molecular sensors.

Localized surface plasmons on periodic monolayer black phosphorene nanoribbons tuned in the infrared region with a dielectric substrate

Localized surface plasmons have been reported for periodic 2D monolayer black phosphorene (BP) nanoribbons in the infrared region. The anisotropic nature of BP causes different plasmonic effects depending on their orientation over select dielectric substrates, leading to tunability and promising future applications in imaging and other detectors. Computational models are used to demonstrate that by tuning the localized plasmonic resonance, as well as the orientation of the BP nanoribbon, it is possible to obtain desired coupled resonance modes and enhanced absorption capabilities. The modes obtained from the absorption spectra span the infrared range and extend our understanding of BP plasmons.

The Role of Rayleigh-Wood Anomalies and Surface Plasmons in Optical Enhancement for Nano-Gratings

We propose and report on the design of a 1-D metallo-dielectric nano-grating on a GaAs substrate. We numerically study the impact of grating period, slit and wire widths, and irradiating angle of incidence on the optical response. The optimal wire width, w = 160 nm, was chosen based on previous results from investigations into the influence of wire width and nano-slit dimensions on optical and electrical enhancements in metal-semiconductor-metal photodetectors. In this present project, resonant absorption and reflection modes were observed while varying the wire and nano-slit widths to study the unique optical modes generated by Rayleigh-Wood anomalies and surface plasmon polaritons. We observed sharp and diffuse changes in optical response to these anomalies, which may potentially be useful in applications such as photo-sensing and photodetectors. Additionally, we found that varying the slit width produced sharper, more intense anomalies in the optical spectrum than varying the wire width.

Silicon nanowires to enhance the performance of self-powered near-infrared photodetectors with asymmetrical Schottky contacts

Silicon nanowires were etched vertically in the channel between asymmetrical interdigital electrodes. The self-powered near-infrared photodetector consists of a planar structure of Au-vertically aligned Si nanowire-Ti. The devices were characterized by measuring the current-voltage characteristics, the external quantum efficiency (EQE), and the spectral response. An enhancement of 32% in the short-circuit current was achieved after applying the Si nanowires. The EQE of the device with Si nanowires consists of a strong peak covering the near-infrared spectral range with a maximum EQE of 10.3% at 965 nm and 0 V. Furthermore, the spectral response measurements showed enhancement and broadening in the spectrum of devices with Si nanowires.