Joshua Tower

Results for aliovalent doping of CeBr3 with Ca2

Despite the outstanding scintillation performance characteristics of cerium tribromide (CeBr3) and cerium-activated lanthanum tribromide, their commercial availability and application are limited due to the difficulties of growing large, crack-free single crystals from these fragile materials. This investigation employed aliovalent doping to increase crystal strength while maintaining the optical properties of the crystal. One divalent dopant (Ca2+) was used as a dopant to strengthen CeBr3 without negatively impacting scintillation performance. Ingots containing nominal concentrations of 1.9% of the Ca2+ dopant were grown. Preliminary scintillation measurements are presented for this aliovalently doped scintillator. Ca2+-doped CeBr3 exhibited little or no change in the peak fluorescence emission for 371 nm optical excitation for CeBr3. The structural, electronic, and optical properties of CeBr3 crystals were studied using the density functional theory within the generalized gradient approximation. The calculated lattice parameters are in good agreement with the experimental data. The energy band structures and density of states were obtained. The optical properties of CeBr3, including the dielectric function, were calculated.Despite the outstanding scintillation performance characteristics of cerium tribromide (CeBr3) and cerium-activated lanthanum tribromide, their commercial availability and application are limited due to the difficulties of growing large, crack-free single crystals from these fragile materials. This investigation employed aliovalent doping to increase crystal strength while maintaining the optical properties of the crystal. One divalent dopant (Ca2+) was used as a dopant to strengthen CeBr3 without negatively impacting scintillation performance. Ingots containing nominal concentrations of 1.9% of the Ca2+ dopant were grown, i.e., 1.9% of the CeBr3 molecules were replaced by CaBr2 molecules, to match our target replacement of 1 out of 54 cerium atoms be replaced by a calcium atom. Precisely the mixture was composed of 2.26 g of CaBr2 added to 222.14 g of CeBr3. Preliminary scintillation measurements are presented for this aliovalently doped scintillator. Ca2+-doped CeBr3 exhibited little or no change in the...

Neutron detection with LiInSe2

The detection of thermal neutrons has traditionally been accomplished with 3He-tubes, but with the recent shortage of 3He, much research has gone into finding suitable replacements. Both relatively inefficient 10B- and 6LiF-coated silicon diodes and HgI2 have been known for many years, and engineered structures in Si that have been filled with 10B and 6LiF have shown promise. These devices are intended to realize an optimal juxtaposition of neutron-sensitive material and semiconductor and thereby simulate a semiconductor containing B or Li. Such material has been realized for the first time in the form of 6LiInSe2 in which collectable charge from the 6Li(n,t) reaction indicates a neutron event. In this paper we report neutron and gamma responses of 6LiInSe2, we show pulse height spectra from pure gamma sources and from a thermal neutron source, and we derive the μτ product from the position of spectral features as a function of bias voltage. In addition, we demonstrate the observation of the beta decay of 116mIn in samples exposed to thermal neutrons. This feature of the response serves as an additional confirmation of exposure to neutrons.

Lithium and boron based semiconductors for thermal neutron counting

Thermal neutron detectors in planar configuration were fabricated from LiInSe2 and B2Se3 crystals grown at RMD Inc. All fabricated semiconductor devices were characterized for the current-voltage (I-V) characteristic and neutron counting measurement. Pulse height spectra were collected from 241AmBe (neutron source on all samples), as well as 137Cs and 60Co gamma ray sources. In this study, the resistivity of all crystals is reported and the collected pulse height spectra are presented for fabricated devices. Note that, the 241AmBe neutron source was custom designed with polyethylene around the source as the neutron moderator, mainly to thermalize the fast neutrons before reaching the detectors. Both LiInSe2 and B2Se3 devices showed response to thermal neutrons of the 241AmBe source.

Semiconductor neutron detectors

Lithium Indium Selenide (LiInSe2) has been under development in RMD Inc. and Fisk University for room temperature thermal neutron detection due to a number of promising properties. The recent advances of the crystal growth, material processing, and detector fabrication technologies allowed us to fabricate large detectors with 100 mm2 active area. The thermal neutron detection sensitivity and gamma rejection ratio (GRR) were comparable to 3He tube with 10 atm gas pressure at comparable dimensions. The synthesis, crystal growth, detector fabrication, and characterization are reported in this paper.

Results for aliovalent doping of CeBr{sub 3} with Ca{sup 2+}

Despite the outstanding scintillation performance characteristics of cerium tribromide (CeBr3) and cerium-activated lanthanum tribromide, their commercial availability and application are limited due to the difficulties of growing large, crack-free single crystals from these fragile materials. This investigation employed aliovalent doping to increase crystal strength while maintaining the optical properties of the crystal. One divalent dopant (Ca2+) was used as a dopant to strengthen CeBr3 without negatively impacting scintillation performance. Ingots containing nominal concentrations of 1.9% of the Ca2+ dopant were grown. Preliminary scintillation measurements are presented for this aliovalently doped scintillator. Ca2+-doped CeBr3 exhibited little or no change in the peak fluorescence emission for 371 nm optical excitation for CeBr3. The structural, electronic, and optical properties of CeBr3 crystals were studied using the density functional theory within the generalized gradient approximation. The calculated lattice parameters are in good agreement with the experimental data. The energy band structures and density of states were obtained. The optical properties of CeBr3, including the dielectric function, were calculated.Despite the outstanding scintillation performance characteristics of cerium tribromide (CeBr3) and cerium-activated lanthanum tribromide, their commercial availability and application are limited due to the difficulties of growing large, crack-free single crystals from these fragile materials. This investigation employed aliovalent doping to increase crystal strength while maintaining the optical properties of the crystal. One divalent dopant (Ca2+) was used as a dopant to strengthen CeBr3 without negatively impacting scintillation performance. Ingots containing nominal concentrations of 1.9% of the Ca2+ dopant were grown, i.e., 1.9% of the CeBr3 molecules were replaced by CaBr2 molecules, to match our target replacement of 1 out of 54 cerium atoms be replaced by a calcium atom. Precisely the mixture was composed of 2.26 g of CaBr2 added to 222.14 g of CeBr3. Preliminary scintillation measurements are presented for this aliovalently doped scintillator. Ca2+-doped CeBr3 exhibited little or no change in the...

Boron selenide semiconductor detectors for thermal neutron counting

Thermal neutron detectors in planar configuration were fabricated from B2Se3 (Boron Selenide) crystals grown at RMD Inc. All fabricated semiconductor devices were characterized for the current-voltage (I-V) characteristic and neutron counting measurement. In this study, the resistivity of crystals is reported and the collected pulse height spectra are presented for devices irradiated with the 241AmBe neutron source. Long-term stability of the B2Se3 devices for neutron detection under continuous bias and without being under continuous bias was investigated and the results are reported. The B2Se3 devices showed response to thermal neutrons of the 241AmBe source.

Pulse shape discrimination for CLYC based handheld instruments

Neutron detectors are used in homeland security to improve the identification of special nuclear materials (SNM). The detection of any neutrons above the natural background is a strong indication of SNM presence. Currently, there is a significant dependence on He-3 tubes for neutron detection. These devices are simple and effective detectors; however they have a number of drawbacks. He-3 tubes are pressure vessels and cannot be brought on board an airplane. They also exhibit micro-phonic effects, which are a serious issue for the handheld instrumentation. The last but not least is a diminishing stockpile of the He-3 gas, which stimulated the recent push to create new neutron detection technologies. In the last few years, RMD has developed a Cs2LiYCI6 (CLYC) scintillator that offers (1) efficient thermal neutron detection, which is higher on a per-volume basis than that of He-3; (2) excellent gamma rejection ratio (GRR), better than 1x10-7; and (3) gamma-ray energy resolution as good as 4% at 662 keV.

PbGa 2 Se 4 semiconductor for gamma-ray detection

In this paper the fabrication and characterization of lead gallium selenide (PbGa₂Se₄) semiconductor devices are reported. PbGa₂Se₄ semiconductor crystals were grown by vertical Bridgman method and planar devices were fabricated from cleaved crystals. The resistivity of the samples with chromium gold contacts was measured to be in the 10¹³ Ω cm range. Pulse height spectra were collected using ²⁴¹Am, ¹⁰⁹Cd, ⁵⁷CO, and ¹³⁷Cs gamma-ray sources. A full energy peak was also observed from the Ag x-rays of ¹⁰⁹Cd gamma ray source with 250 μm thick PbGa₂Se₄ planar device.