Juana N. Rossi

Petrology and geochemistry of the orbicular granitoid of Sierra de Velasco (NW Argentina) and implications for the origin of orbicular rocks

The Velasco orbicular granitoid is a small (65 × 15 m), irregularly-shaped body that crops out within the Huaco granite, central Sierra de Velasco, NW Argentina. It consists of ellipsoid-shaped orbicules of 3 to 15 cm length immersed in an aplitic to pegmatitic matrix. The orbicules are formed by a core made up of a K-feldspar megacryst, partially to totally replaced by plagioclase, an inner shell of radial and equant plagioclase crystals, a layer of tangentially oriented biotite laths, and an outer shell of plumose plagioclase crystals, containing diffuse rings of tangentially oriented biotite. The orbicular granitoid formed in situ in a pocket of evolved and volatile-rich melt segregated from the surrounding partially crystallized Huaco granite, possibly via a filter pressing mechanism. The segregated melt entrained relatively few K-feldspar megacrysts into the pocket, leaving behind a concentration of megacrysts around the pocket. High water concentration caused effective superheating of the melt and destruction of nuclei, with only the large megacrysts surviving as solids. Sudden water-pressure loss and exsolution of the volatile phase, perhaps related to a volcanic eruption or fracturing of the surrounding granite, caused rapid undercooling of the melt. The orbicules grew in the undercooled melt by heterogeneous nucleation on the megacrysts, which acted as nucleation seeds, and crystallization of reversely zoned radial plagioclase and sporadic crystallization of tangential biotite rings according to fluctuations in its saturation. Orbicular growth gave way to crystallization of the equiaxial inter-orbicular matrix in two stages, when sufficient polymerization of the melt was attained. The time scale of formation of the orbicular granitoid was fast, possibly a matter of a few weeks or months.

Basin evolution of the margin of Gondwana at the Neoproterozoic/ Cambrian transition: the Puncoviscana Formation of Northwest Argentina

The Puncoviscana Formation is an important stratigraphic sequence of sandstones and shales, with intercalated conglomerates, limestones and volcanic rocks. It was deposited at the Neo- proterozoic-Cambrian boundary in a shallow basin on the western margin of Gondwana. Trace fos- sils of the Puncoviscana Formation s.l. are represented by the Oldhamia and Nereites ichnoassocia- tions and the geographical distribution of assemblages are aligned as parallel belts, with a shallower eastern Nereites association and a deeper western Oldhamia association. They represent different temporal levels on the evolution of the basin. Detrital zircon spectra display a wide range of ages, which indicate their provenance from Neoproterozoic to Cambrian source areas as well as Meso- to Paleoproterozoic basement units, exhibiting typical Gondwanan ages. Thick limestone banks are interbedded in the Puncoviscana Formation s.l. that included the siliciclastic sequences, with very low- to medium-metamorphic grade. δ13C values for the limestones vary from -1.57 to +3.40/00 VPDB, while in the Sierras Pampeanas, δ13C values vary from +2.6 to +80/00 VPDB. Also, reported 87Sr/86Sr values allow a clear differentiation of two rock sets. The limestones interbedded with the Puncoviscana Formation yielded values typical for the Neoproterozoic-Cambrian transition, between 0.70868 and 0.70896; while the limestones of the Sierras Pampeanas display values between 0.70748 and 0.70756, common in the middle to late Ediacaran. Deformation and uplift of the Puncoviscana Formation is clearly represented in northern Argentina by the Tilcarian unconformity, which is over- lain by the Meson Group.