Julia Fleck

Influence of Pressure and Steam Dilution on NOx and CO Emissions in a Premixed Natural Gas Flame

In the current study, the influence of pressure and steam on the emission formation in a premixed natural gas flame is investigated at pressures between 1.5 bar and 9 bar. A premixed, swirl-stabilized combustor is developed that provides a stable flame up to very high steam contents. Combustion tests are conducted at different pressure levels for equivalence ratios from lean blowout to near-stoichiometric conditions and steam-to-air mass ratios from 0% to 25%. A reactor network is developed to model the combustion process. The simulation results match the measured NOx and CO concentrations very well for all operating conditions. The reactor network is used for a detailed investigation of the influence of steam and pressure on the NOx formation pathways. In the experiments, adding 20% steam reduces NOx and CO emissions to below 10 ppm at all tested pressures up to near-stoichiometric conditions. Pressure scaling laws are derived: CO changes with a pressure exponent of approximately −0.5 that is not noticeably affected by the steam. For the NOx emissions, the exponent increases with equivalence ratio from 0.1 to 0.65 at dry conditions. At a steam-to-air mass ratio of 20%, the NOx pressure exponent is reduced to −0.1 to +0.25. The numerical analysis reveals that steam has a strong effect on the combustion chemistry. The reduction in NOx emissions is mainly caused by lower concentrations of atomic oxygen at steam-diluted conditions, constraining the thermal pathway.

Experimental investigation of a generic, fuel flexible reheat combustor at gas turbine relevant operating conditions

Fuel flexibility in stationary gas turbines (GT) is becoming increasingly important due to the use of a broader spectrum of primary energy sources, particularly H2 -rich fuels derived from the gasification of coal or biomass. GTs also must be able to operate at extremely low emission levels, which is currently achieved with lean-premixed burner designs. To investigate the performance of highly reactive fuels in the reheat combustion concept, mainly with respect to autoignition and flashback limits, a generic reheat combustor with excellent optical access has been developed. The first objective of this work was to carefully characterize the mixing section in order to derive well-defined boundary conditions for the subsequent autoignition studies. Initial autoignition results at T > 1000 K and p = 15 bar are presented for natural gas (NG) and H2 -rich fuels. No autoignition was detected for NG at the investigated operating conditions. For H2 /NG/N2 blends with a constant volumetric N2 concentration of 20% and H2 concentrations higher than 76%, autoignition in the mixing section was detected.Copyright

Autoignition of Hydrogen / Natural Gas / Nitrogen Fuel Mixtures at Reheat Combustor Operating Conditions

Previous autoignition studies at conditions relevant to reheat combustor operation have indicated that the presence of relatively small amounts of natural gas (NG) in H2/N2 fuel significantly changes the autoignition behavior. The present study further elucidates the influence of NG on autoignition, kernel propagation, and subsequent flame stabilization at conditions that are relevant for the practical operation of gas turbine reheat combustors (p = 15 bar, Tinlet > 1000 K, hot flue gas, appropriate residence times). The experimental investigation was carried out in a generic, optically accessible reheat combustor. Autoignition events in the mixing zone were recorded by a high-speed camera at frame rates of up to 30,000 fps. This paper describes the autoignition behavior as the H2 volume fraction is increased (decreasing NG) in a H2/NG/N2 fuel mixture for two different jet penetration depths. Additionally, the subsequent flame stabilization phenomena and the structure of the stabilized flame are discussed. The results reveal that autoignition kernels occurred even for the lowest H2 fuel fraction, but they did not initiate a stable flame in the mixing zone. Increasing the H2 volume fraction decreased the distance between the initial position of the autoignition kernels and the fuel injector, finally leading to flame stabilization. The occurrence of autoignition kernels at lower H2 volume fractions (H2/(H2+NG) < 85%) was not found to be significantly influenced by the fluid dynamic and mixing field differences related to the different jet penetration depths. In contrast, autoignition leading to flame stabilization was found to depend on jet penetration; flame stabilization occurred at lower H2 fractions for the higher jet penetration depth (H2/(H2+NG) ≈ 89 compared to H2/(H2+NG) ≈ 95 vol. %).© 2012 ASME