Julien Froidevaux

Natural and artificial ageing of spruce wood as observed by FTIR-ATR and UVRR spectroscopy

Abstract Spruce samples, naturally aged for 200, 400 and 500 years, artificially aged by a hydrothermal treatment (at 180, 160 or 130°C, relative air humidities of 14%, 40%, or 60% and for treatment times between 1 to 50 h), as well as reference samples, were analysed by Fourier transform infrared spectroscopy (FTIR) attenuated total reflection (FTIR-ATR) and ultraviolet resonance Raman (UVRR) spectroscopy. Natural ageing mostly affected the hemicelluloses and lignin, as observed from the FTIR-ATR and UVRR spectra, respectively. The UVRR spectra of the same samples after acetone extraction indicated that lignin was partially degraded and quinone structures were possibly formed. Artificial ageing at 160°C showed a significant change in the lignin structure, a well-known effect in the thermal treatment of wood, whereas treatment at 130°C did not alter the wood structure to any significant extent. Principal component analysis of the UVRR spectra confirmed that the spectra of artificially aged wood up to 160°C are dissimilar to naturally aged wood and which are also dissimilar to unaged wood.

Evaluation of the thermal stability and set recovery of thermo-hydro-mechanically treated lime ( Tilia cordata ) wood

The effect of the thermo-hydro-mechanical (THM) densification in a closed system on the set recovery and thermal stability of lime (Tilia cordata) wood was evaluated. The THM densification process consists of four steps: plastification, densification, post-treatment and cooling. The THM-densified wood samples were subjected to three different post-treatment temperatures, and for each one, three different periods were used. Comparison between THM-densified wood sample without and with post-treatment at different temperatures and times was made. The set recovery tests showed that the post-treatment at higher temperatures and times improves the dimensional stability of the samples suggesting a permanent fixation of the transversal compression, but also reduces their thermal stability, by having lower temperatures corresponding to the maximum decomposition rate, lower values for the mass loss at the end of decomposition stage and lower values for the kinetic parameters. The samples with post-treatments at lower temperatures showed high set recovery values and exhibited higher values for the temperatures corresponding to the maximum decomposition rate, lower values for the mass loss at the end of the stage and higher activation energies and reaction orders.

Viscoelastic behaviour of aged and non-aged spruce wood in the radial direction

Abstract The mechanical behaviour of non-aged (modern) and aged spruce [Picea abies (L.) Karst.] wood was investigated in the radial direction using a microtensile testing device. The size of the samples was 50 × 3 × 3 mm (radial × tangential × longitudinal). Elastic, creep, relaxation, rupture and mechanosorption tests were carried out under controlled temperature and relative humidity. Optical and electronic micrographs were produced in order to correlate the mechanical behaviour with the wood structure. Results indicate that the overall mechanical properties such as Youngs modulus and the time-dependent behaviour of wood in the radial direction do not change significantly with age. However, the strength of aged wood shows a decrease of about 25% in the radial direction. This loss of strength in aged wood might be explained by localized damage at the microstructural level in the wood.

Experimental study of the mechanosorptive behaviour of softwood in relaxation

In softwood material, the coupling between mechanical loading and hydric state is known as the mechanosorptive effect. However, the coupling with viscoelastic effect remains unclear so far, especially when the loading is controlled by strain. In this context, the present paper is focused on the process of creation and recovery of ‘hygrolock’ behaviour, i.e. a stress locking effect which occurs in a phase of drying under load. For this purpose, several relaxation tests were first performed on small-scale silver fir specimens in order to express the relaxation function in terms of the ambient humidity. Then, two mechanosorptive tests were carried out in order to induce hygrolock stresses in the same sample loaded in sustained strain condition, and subjected to cyclically varying humidity. Based on the assumption of stress partition, the analysis of the test results clearly shows the existence of a hygrolock stress. From these experimental evidences, a law is finally proposed to describe the evolution of the hygrolock stress in terms of the hydric state of the softwood material.

Aging law of spruce wood

Abstract Accelerated aging of spruce wood samples have been carried out by thermo-hydro (TH) treatments. These treatments were applied to accelerate the chemical reactions that take place during the natural aging of wood. In order to avoid dissimilar chemical reactions between the TH treatments and the natural aging, mild temperatures (between 100 and 150°C) have been selected at low relative humidity (RH). The mechanical properties of non-aged, natural aged and accelerated aged spruce wood have been compared. It is apparent that longitudinal Youngs modulus of accelerated aged wood increase slightly at the beginning of the treatment and is followed by a reduction. Along the radial direction, Youngs modulus remains almost unchanged. On the other hand the radial strength is severely reduced. From these results, the relative radial strength has been fitted on the chemical kinetic law. The rate constant of this law has been calculated and the treatment temperature and wood moisture content have been integrated. Finally this law has been extrapolated to standard climatic conditions in order to predict the loss of strength of old wood by knowing its age and its mean climate history of temperature and RH (ambiance condition).