Juliette W. Ioup

Iterative and function-continuation Fourier deconvolution methods for enhancing mass spectrometer resolution

Mass spectrometer data in the form of ion current versus mass-to-charge ratio often include overlapping mass peaks, especially in low- and medium-resolution instruments. Numerical deconvolution of such data effectively enhances the resolution by decreasing the overlap of mass peaks. In this paper two approaches to deconvolution are presented: a function-domain iterative technique and a Fourier transform method which uses transform-domain function-continuation. Both techniques include data smoothing to reduce the sensitivity of the deconvolution to noise. The efficacy of these methods is demonstrated through application to representative mass spectrometer data and the deconvolved results are discussed and compared to data obtained from a spectrometer with sufficient resolution to achieve separation of the mass peaks studied. A case for which the deconvolution is seriously affected by Gibbs oscillations is analyzed.

Acoustic Propagation Studies For Sperm Whale Phonation Analysis During LADC Experiments

The Littoral Acoustic Demonstration Center (LADC) conducted a series of passive acoustic experiments in the Northern Gulf of Mexico and the Ligurian Sea in 2001 and 2002. Environmental and acoustic moorings were deployed in areas of large concentrations of marine mammals (mainly, sperm whales). Recordings and analysis of whale phonations are among the objectives of the project. Each mooring had a single autonomously recording hydrophone (Environmental Acoustic Recording System (EARS)) obtained from the U.S. Naval Oceanographic Office after modification to record signals up to 5,859 Hz in the Gulf of Mexico and up to 12,500 Hz in the Ligurian Sea. Self‐recording environmental sensors, attached to the moorings, and concurrent environmental ship surveys provided the environmental data for the experiments. The results of acoustic simulations of long‐range propagation of the broad‐band (500–6,000 Hz) phonation pulses from a hypothetical whale location to the recording hydrophone in the experimental environment...