Junghwi Lee

Directly Drawn Organic Transistors by Capillary Pen: A New Facile Patterning Method using Capillary Action for Soluble Organic Materials

A capillary pen drawing technique, developed as a new patterning methodology for the large-area patterning and fabrication of organic electronics, provides several advantages over conventional approaches: the method is simple and versatile, there are no restrictions on the patterning shapes that could be produced, and the method can be tailored to a variety of substrates.

Microstructural Control over Soluble Pentacene Deposited by Capillary Pen Printing for Organic Electronics

Research into printing techniques has received special attention for the commercialization of cost-efficient organic electronics. Here, we have developed a capillary pen printing technique to realize a large-area pattern array of organic transistors and systematically investigated self-organization behavior of printed soluble organic semiconductor ink. The capillary pen-printed deposits of organic semiconductor, 6,13-bis(triisopropylsilylethynyl) pentacene (TIPS_PEN), was well-optimized in terms of morphological and microstructural properties by using ink with mixed solvents of chlorobenzene (CB) and 1,2-dichlorobenzene (DCB). Especially, a 1:1 solvent ratio results in the best transistor performances. This result is attributed to the unique evaporation characteristics of the TIPS_PEN deposits where fast evaporation of CB induces a morphological evolution at the initial printed position, and the remaining DCB with slow evaporation rate offers a favorable crystal evolution at the pinned position. Finally, a large-area transistor array was facilely fabricated by drawing organic electrodes and active layers with a versatile capillary pen. Our approach provides an efficient printing technique for fabricating large-area arrays of organic electronics and further suggests a methodology to enhance their performances by microstructural control of the printed organic semiconducting deposits.

Gate-Bias Stability Behavior Tailored by Dielectric Polymer Stereostructure in Organic Transistors

Understanding charge trapping in a polymer dielectric is critical to the design of high-performance organic field-effect transistors (OFETs). We investigated the OFET stability as a function of the dielectric polymer stereostructure under a gate bias stress and during long-term operation. To this end, iso-, syn-, and atactic poly(methyl methacrylate) (PMMA) polymers with identical molecular weights and polydispersity indices were selected. The PMMA stereostructure was found to significantly influence the charge trapping behavior and trap formation in the polymer dielectrics. This influence was especially strong in the bulk region rather than in the surface region. The regular configurational arrangements (isotactic > syntactic > atactic) of the pendant groups on the PMMA backbone chain facilitated closer packing between the polymer interchains and led to a higher crystallinity of the polymer dielectric, which caused a reduction in the free volumes that act as sites for charge trapping and air molecule absorption. The PMMA dielectrics with regular stereostructures (iso- and syn-stereoisomers) exhibited more stable OFET operation under bias stress compared to devices prepared using irregular a-PMMA in both vacuum and air.

Measurement of Cosmic-Ray Nuclei with the Third Flight of the CREAM Balloon-Borne Experiment

The balloon-borne Cosmic Ray Energetics And Mass experiment had its third flight (CREAM-III) over Antarctica for 29 days from December 17, 2007 to January 19, 2008. CREAM-III was designed to directly measure the elemental spectra of cosmic-ray nuclei from Hydrogen to Iron in the energy range from 10^12 to 10^15 eV. Energy of incident cosmic rays was measured with a calorimeter that consisted of a densified carbon target directly above a stack of 20 alternating layers of tungsten and scintillating fiber ribbons. Multiple charge measurements were independently made with the silicon charge detector (SCD), Cherenkov Camera (CherCam), and a Timing Charge Detector (TCD) in order to identify particles and minimize backscattering effects from the calorimeter. Compared to previous CREAM flights, the electronic noise of CREAM-III was reduced, significantly lowering the energy threshold. Results from on-going analysis of the energy spectra will be presented.

Measurements of the Proton and Helium Spectra from CREAM-V

The Cosmic Rays Energy And Mass (CREAM) balloon payload directly measures the composition and elemental spectra of cosmic rays in the upper stratosphere. It is designed to probe the acceleration mechanism and propagation history of cosmic rays at energies from 10

Performance of the ISS-CREAM Calorimeter

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Enhancement of Solvent-Resistance by Forming Interpenetrating Network for High-Performance Polymer Field-Effect Transistors

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Behavior of pentacene molecules deposited onto roughness-controlled polymer dielectrics films and its effect on FET performance

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Fully Drawn All‐Organic Flexible Transistors Prepared by Capillary Pen Printing on Flexible Planar and Curvilinear Substrates

eV. Being the fifth flight in a series of seven, CREAM-V took data above Antarctica for 39 days from December 1

Preparation of highly conductive reduced graphite oxide/poly(styrene-co-butyl acrylate) composites via miniemulsion polymerization

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