Juraj Kurimsky

Dielectric response of transformer oil based ferrofluid in low frequency range

In this article, our experimental study of the dynamic dielectric behaviour of transformer oil-based ferrofluid with magnetite nanoparticles is presented. Frequency-dependent dielectric permittivity and dissipation factor were measured within the frequency range from 20 Hz to 2 MHz by a capacitance method. The ferrofluid samples were placed in a liquid crystal cell, and experiments were carried out in an electromagnetically anechoic chamber. Two polarization processes and corresponding relaxations were revealed within the applied frequency range. Schwarz theory of electric double layer polarization is used to explain the low frequency relaxation maximum. Moreover, the shift of the maximum position towards higher frequencies is observed as the magnetic volume fraction in the ferrofluid increases. The related decrease in relaxation time due to higher counterion mobility is analysed. Reduced electric field intensity due to depolarization field, which is dependent on the particle concentration, is proposed as...

Direct observation of electric field induced pattern formation and particle aggregation in ferrofluids

Ferrofluids typically respond to magnetic fields and can be manipulated by external magnetic fields. Here, we report on formation of visually observable patterns in a diluted low-polarity ferrofluid exposed to external electric fields. This presents a specific type of ferrofluid structure driven by a combined effect of electrohydrodynamics and electrical body forces. The free charge and permittivity variation are considered to play a key role in the observed phenomenon. The corresponding changes in the ferrofluid structure have been found at nanoscale as well. By small-angle neutron scattering (SANS), we show that the magnetic nanoparticles aggregate in direct current (dc) electric field with a strong dependence on the field intensity. The anisotropic aggregates preferably orient in the direction of the applied electric field. Conducting SANS experiments with alternating current (ac) electric fields of various frequencies, we found a critical frequency triggering the aggregation process. Our experimental study could open future applications of ferrofluids based on insulating liquids.

Electrode polarization and unusual magnetodielectric effect in a transformer oil-based magnetic nanofluid thin layer

In the present paper, we provide low-frequency dielectric spectra for a thin layer of a nanofluid based on transformer oil and iron oxide nanoparticles stabilized by oleic acid. The complex dielectric permittivity measured in the frequency range from 1 mHz to 200 kHz shows an obvious electrode polarization effect and a Debye-like dielectric relaxation process. Both effects stem from the presence of space charge in the oil due to impurity ions, and in the nanofluid represented predominantly by a residual surfactant and uncompensated particle surface charge. It is shown that the spectra, which were measured in the temperature range from 298 K to 358 K, can be well represented by a fitting function consisted of one Havriliak-Negami term and the Jonschers power law. In the investigated magnetic nanofluid layer, we found that the onset of the electrode polarization is suppressed to lower frequencies by the application of an external magnetic field (300 mT). This phenomenon is explained by a slowed-down migration of the space charge due to the Lorentz force and by a hindering effect of the formed magnetic nanoparticle aggregates. Surprisingly, a moderate decrease in the whole permittivity spectrum was observed for both parallel and perpendicular orientations of the electric and magnetic fields. This is in contradiction with the usual magnetodielectric anisotropy effect. Based on our qualitative analysis, we discuss potential reasons accountable for the observed effect.

Breakdown voltage of polypropylene film during C and thermal ageing

This paper investigates the electrical breakdown of biaxially oriented polypropylene (BOPP) film during accelerated DC and thermal ageing. The DC breakdown voltage of 6.5 μm thick capacitor grade polypropylene (PP) films was measured. Two types of films with different crystallinity were tested. 88 breakdowns per sample were collected. The scale and shape parameter of the Weibull distribution were fitted to the data. The scale parameter values obtained vary between 713 and 804 V. Results indicate that during ageing procedure the film crystallinity is an influencing factor of their breakdown voltages.

Experimental observation of interaction between radiofrequency electromagnetic field and blood tissue

The exposition of biological and technical systems to electromagnetic radiation has increased with the rapid development of wireless data transfer. Recent studies are incrementally aiming at electromagnetic compatibility between electromagnetic radiation sources and biological and technical systems. No source of electromagnetic radiation should affect operation of other technical systems and endanger biological systems. Studies show that biological organism reacts to electromagnetic fields. This paper is focused on experimental observation of interaction between electromagnetic radiation and biological samples in the form of blood preparations. Results of interaction of radiofrequency electromagnetic radiation produced by mobile phone and biological tissue are presented. Samples of animal blood were used. The first part is focused at actual research in the world. In the second part there is presented workplace setup for exposing biological tissues to non-ionizing electromagnetic field. Results of this exposure are presented in the end.

Influence of electromagnetic interference on time-domain spectroscopy of magnetic nanofluids

The article deals about magnetic fluids based on a transformer ITO100 oil and about behaviour of these fluids under influence of permanent magnetic field represented by time-current characteristics. The measurements were performed in an anechoic EMC chamber and outside the chamber for comparing the results on the same samples. The main objective was to determine how much is the measurement influenced by external electromagnetic fields that generate around electrical equipment and the impact of higher harmonics in the power supply voltage. The measurement is dependent from orientation of actuating magnetic field, this behaviour mainly shows the effect of nanoparticles structuring during exposition of specimen by magnetic field. These particles also changes polarization processes in fluid influence of nanoparticles concentration contained in the fluid.

Dielectric Spectroscopy of Ferronematics Based on 6CHBT Liquid Crystal

In our study, the dielectric behaviour of the rod-like liquid crystal (6CHBT) doped with magnetic nanoparticles of spherical shape was investigated by means of dielectric spectroscopy in the frequency range from 20 Hz to 2 MHz. A low frequency dielectric dispersion in the nematic and isotropic phases of the pure liquid crystal (LC) has been assigned to the space charge polarization. After doping the host LC with the magnetic nano particles, a nearly Debye-like relaxation process was observed with the temperature dependence obeying the Arrhenius law. Considering a possible electric double layer formation on the particle surfaces, the detected relaxation process in the doped LC can be associated with the electric double layer polarization. The experimental results point out that in the measured frequency range the space charge and interfacial effects constitute the main dielectric response. Any anchoring effects were not observed and are therefore expected to appear in higher frequencies.