K. J. Moody

Indication for a volatile element 114

Abstract Recently, the chemical investigation of element 112 revealed a highly volatile, noble metallic behaviour, as expected for the last group 12 member of the periodic table. The observed volatility and chemical inertness were ascribed to the growing influence of relativistic effects on the chemical properties of the heaviest elements with increasing nuclear charge. Here, we report for the first time on gas phase chemical experiments aiming at a determination of element 114 properties. This element was investigated using its isotopes 287114 and 288114 produced in the nuclear fusion reactions of 48Ca with 242Pu and 244Pu, respectively. Identification of three atoms of element 114 in thermochromatography experiments and their deposition pattern on a gold surface indicates that this element is at least as volatile as simultaneously investigated elements Hg, At, and element 112. This behaviour is rather unexpected for a typical metal of group 14.

Synthesis of 292116 in the 248Cm + 48Ca reaction

We report on the observation of the first decay event of the new nuclide 292116 produced in an experiment devoted to the synthesis of Z=116 nuclei in the 248Cm + 48Ca reaction. The implantation of a heavy recoil in the focal-plane detector was followed in 46.9 ms by an α particle with Eα=10.56MeV. The energies and decay times of the descendant nuclei are in agreement with those observed in the decay chains of the even-even isotope 288114, previously produced in the 244Pu + 48Ca reaction. Thus, the first α decay should be attributed to the parent nuclide 292116 produced via the evaporation of four neutrons in the complete fusion of 248Cm and 48Ca. The experiment is in progress at Flerov Laboratory for Nuclear Reactions (FLNR, JINR, Dubna).

Nuclear forensics in law enforcement applications

Over the past several years, the Livermore Forensic Science Center has conducted analyses of nuclear-related samples in conjunction with domestic and international criminal investigations. Law enforcement officials have sought conventional and nuclear-forensic analyses of questioned specimens that have typically consisted of miscellaneous metal species or actinide salts. The investigated activities have included nuclear smuggling and the proliferation of alleged fissionable materials, nonradioactive hoaxes such as “Red Mercury,” and the interdiction of illegal laboratories engaged in methamphetamine synthesis.

Cold (neutronless)αternary fission of252Cf

The phenomenon of cold (neutronless) alpha ternary fission in spontaneous fission of {sup 252}Cf was experimentally observed by triple gamma coincidence technique with Gammasphere with 72 gamma-ray detectors. Correlated pairs of {sub 36}Kr-{sub 60}Nd, {sub 38}Sr-{sub 58}Ce, {sub 40}Zr-{sub 56}Ba, {sub 42}Mo-{sub 54}Xe, {sub 44}Ru-{sub 52}Te, and {sub 46}Pd-{sub 50}Sn were observed to be associated with {alpha} ternary fission of {sup 252}Cf. Yields of cold {alpha} ternary fission were extracted. {copyright} {ital 1998} {ital The American Physical Society}

Random probability analysis of heavy-element data

Abstract In this paper, we present the Monte Carlo Random Probability (MCRP) calculational method details that were developed for the determination of random correlations in a set of unrelated data. After finding random correlations, we further process the correlations by applying nuclear property systematics. We compare the results of MCRP with methods presented in other references. The MCRP method can provide a conservative estimate of the random probability associated with observed events that takes into account the entire background observed in the experiment and any other running conditions (noise, decay of long-lived species, etc.) which may have been sporadic or intermittent. We discuss a particular example of a set of correlated alpha decays and its interpretation as a candidate decay chain.

Solid debris collection for radiochemical diagnostics at the National Ignition Facility.

Radiochemical analysis of post-ignition debris inside the National Ignition Facility (NIF) target chamber can help determine various diagnostic parameters associated with the implosion efficiency of the fusion capsule. This technique is limited by the ability to distinguish ablator material from other debris and by the collection efficiency of the capsule debris after implosion. Prior to designing an on-line collection system, the chemical nature and distribution of the debris inside the chamber must be determined. The focus of our current work has been on evaluating capture of activated Au hohlraum debris on passive foils (5 cm diameter, 50 cm from target center) post-shot. Preliminary data suggest that debris distribution is locally heterogeneous along the equatorial and polar line-of-sights.

Observation of a vh{sub 11/2} pair alignment in neutron-rich {sup 118}Pd

The yrast band was significantly extended to 14{sup +} and the {gamma} band to 5{sup +} in neutron-rich {sup 118}Pd by measuring the {gamma}-{gamma}-{gamma} coincidences emitted from the spontaneous fission of {sup 252}Cf with Gammasphere. The first band crossing was observed in the yrast band in {sup 118}Pd at a frequency of {Dirac_h}{omega}{approx}0.36 MeV at the starting point of the backbending, which is similar to that found in {sup 112-116}Pd. The first bandbending in the yrast cascade in {sup 118}Pd is interpreted to be built on a two h{sub 11/2} neutron configuration based on its similarity to the yrast bands in even-even {sup 112-116}Pd. Our result indicates {sup 118}Pd still maintains a prolate shape. The quasineutron Routhian calculations indicate a lower crossing frequency for the h{sub 11/2} level.

Synthesis of superheavy nuclei in 48Ca+244Pu interactions

This article reports the results of experiments aimed at producing hypothetical long-lived superheavy elements located near the spherical-shell closures with Z≥114 and N≥72. For the synthesis of superheavy nuclei, we used a combination of neutron-rich reaction partners, with a 244Pu target and a 48Ca projectile. The sensitivity of the present experiment exceeded by more than two orders of magnitude previous attempts at synthesizing superheavy nuclides in reactions of 48Ca projectiles with actinide targets. We observed new decay sequences of genetically linked alpha decays terminated by spontaneous fission. The high measured alpha-particle energies, together with the long decay times and spontaneous fission terminating the chains, offer evidence for the decay of nuclei with high atomic numbers. The decay properties of the synthesized nuclei are consistent with the consecutive alpha decays originating from the parent nuclides 288,289114, produced in the 3n-and 4n-evaporation channels with cross sections of about a picobarn. The present observations can be considered experimental evidence for the existence of the “island of stability” of superheavy elements and are discussed in terms of modern theoretical approaches.

The Radiochemical Analysis of Gaseous Samples (RAGS) apparatus for nuclear diagnostics at the National Ignition Facility (invited).

Radiochemical diagnostic methods are currently under development for the National Ignition Facility (NIF). Samples in the gas-phase offer a direct method of collection by pumping out the large target chamber following a NIF shot and transporting the gas down-stream for further analysis. Ignition capsules will have a small amount (roughly 1015 atoms) of dopant added to the inner-most layers of the ablator shell. These elements will undergo nuclear activation from neutrons, deuterons, or alpha particles produced via the fusion process. For example, doping 124Xe and 127I in the shell will create activated xenon isotopes that can be correlated to the amount of fuel ρR and long-range mix in the capsule. We are building the Radiochemical Analysis of Gaseous Samples (RAGS) apparatus for collecting and analyzing activated gases produced via the ignition process. Following a shot, gases will be pumped out of the chamber and transported to a two-part system. The first part consists of a pre-filter that will remove particulates and other reactive gases. The second part is a cryogenic xenon collection station where xenon will be isolated, and will then either be removed for mass spectrometric analysis, or counted via gamma spectroscopy. Preliminary results from RAGS commissioning will be presented and future improvements to the apparatus will also be discussed.

Nuclear forensic analysis of thorium

A comprehensive radiochemical isolation procedure and data analysis/interpretation method for the nuclear forensic investigation of Th has been developed. The protocol includes sample dissolution, chemical separation, nuclear counting techniques, consideration of isotopic parent-daughter equilibria, and data interpretation tactics. Practical application of the technology was demonstrated by analyses of a questioned specimen confiscated at an illegal drug synthesis laboratory by law enforcement authorities.