K Mishchik

Femtosecond laser pulse train interaction with dielectric materials

The interaction of trains of femtosecond microjoule laser pulses with dielectric materials by means of a multi-scale model is investigated. Theoretical predictions are directly confronted with experimental observations in soda-lime glass. It is shown that due to the low heat conductivity, a significant fraction of the laser energy can be accumulated in the absorption region. Depending on the pulse repetition rate, the material can be heated to high temperatures even though the single pulse energy is too low to induce a significant material modification. Regions heated above the glass transition temperature in the simulations correspond very well to zones of permanent material modifications observed in the experiments. It turns out that pulse-to-pulse variations of the laser absorption are negligible and of minor influence to permanent material modifications.

Dual-color control and inhibition of direct laser writing in silver-containing phosphate glasses

We report on dual-color control of femtosecond direct laser writing (DLW) in a noncommercial silver-containing zinc phosphate glass, thanks to an additional illumination with a cw (continuous wave) UV laser, either after the femtosecond irradiation or simultaneously. By tuning the cw UV power, we demonstrate the tunable control and inhibition of the production efficiency of laser-induced fluorescent silver clusters, leading up to 100% inhibition for simultaneous co-illumination when the laser writing is performed close enough to the permanent structuring threshold. The role of the cw UV illumination is discussed in terms of inhibition of the silver cluster precursors or of dissolution of the laser-induced silver clusters. These results show the ability of laser writing inhibition in our photosensitive silver-containing phosphate glass, which is a necessary step to further develop super-resolution laser writing approaches, such as STED-like DLW, either of fluorescent silver clusters or of silver metallic nanoparticles with plasmonic properties.

Improved laser glass cutting by spatio-temporal control of energy deposition using bursts of femtosecond pulses

We demonstrate the advantage of combining non-diffractive beam shapes and femtosecond bursts for volume laser processing of transparent materials. By re-distribution of the single laser pulse energy into several sub-pulses with 25 ns time delay, the energy deposition in the material can be enhanced significantly. Our combined experimental and theoretical analysis shows that in burst-mode detrimental defocusing by the laser generated plasma is reduced, and the non-diffractive beam shape prevails. At the same time, heat accumulation during the interaction with the burst leads to temperatures high enough to induce material melting and even in-volume cracks. In an exemplary case study, we demonstrate that the formation of these cracks can be controlled to allow high-speed and high-quality glass cutting.

Dash line glass- and sapphire-cutting with high power USP laser

Glass cutting is a subject of high interest for flat panel display and consumer electronics industries. Among laser-based, water jet-based and diamond tool-based existing solutions, ultra-short pulses (USP) appear as a promising technology since this laser technology has the unique capacity to produce highly localized bulk modification owing to non-linear absorption. The cutting using USP lasers could be performed either by full ablation which is slow and generates a lot of dust, by controlled fracture propagation which is slow as well and may lead to path deviation, by stealth dicing which produces rough sidewalls, or by self-breaking induced by in-volume laser irradiation. The laser treatment is often continuous which is not necessary to perform glass cutting and may lead to over-exposure. In this paper we report on single pass glass and sapphire cutting using an USP laser (20W @200kHz or 8W@2MHz) using dash line laser treatment along the cutting trajectory. In-volume energy deposition was done along the glass thickness owing to a Bessel beam. The results will be discussed in terms of sidewall profile and roughness, path deviation, rim sharpness, energy dose and feed rate. Dash line treatment enables to tune the energy deposition and to produce the cutting effect but with a narrower heat affected zone, a better sidewall quality and a more accurate trajectory control of the cutting path.

Effects of burst mode on transparent materials processing

We investigated the effect of burstmode with nanosecond (ns) time delay between subpulses on sodalime glass volume machining. We observed in tight focusing configuration that the use of burstmode with ns time delay between subpulses does not increase the absorption efficiency and does not bring a significant effect on the heat affected zone diameter with respect to single pulse mode. On the contrary in loose focusing configuration the use of burst mode allows increasing the aspect ratio of the heat affected zone without extra energy absorption. This effect is highly interesting for filamentation glass cutting applications.

Femtosecond laser processing of silver-containing glass with optical vortex beams

We report on vortex-assisted femtosecond direct laser writing (DLW) in silver-containing phosphate glasses with complex light fields endowed with optical phase singularities. This allows us to engrave complex patterns showing sub-wavelength dimensions. The associated linear and nonlinear optical properties show remarkably correlated but distinct spatial distributions. The creation of a perennial buried electric field leads to an efficient electric- field induced second harmonic generation. The magnitude and distribution of such buried field is also considered to actively drive the pattern topology of the fluorescent silver clusters. Using DLW with phase and amplitude engineered beams, we demonstrate a promising approach to control both fluorescent and nonlinear responses below the diffraction limit.