K. Okazaki

Octet-Line Node Structure of Superconducting Order Parameter in KFe2As2

An Eight-Noded Monster In superconductors, electrons are bound into pairs, and the exact form of that pairing and the resulting energy gap can vary, depending on the details of the electron-electron interaction and the band structure of the material. The energy gaps of the recently discovered iron-based superconductors exhibit a variety of pairing functions. KFe2As2 has been suggested to have a d-wave gap, similar to cuprate superconductors. Okazaki et al. (p. 1314) use laser-based angle-resolved photoemission spectroscopy (ARPES) to map out the superconducting gap on three Fermi surfaces (FS) of the compound. They find a different gap structure on each, with the middle FS gap vanishing at eight distinct positions (nodes). It appears that the gap respects the tetragonal symmetry of the crystal, indicating (although the details may vary) the all iron-based superconductors have an extended s-wave–symmetric pairing—a finding that will help understanding of unconventional superconductivity. Laser-based photoemission spectroscopy is used to map out the pairing gap of an iron-based superconductor. In iron-pnictide superconductivity, the interband interaction between the hole and electron Fermi surfaces (FSs) is believed to play an important role. However, KFe2As2 has three zone-centered hole FSs and no electron FS but still exhibits superconductivity. Our ultrahigh-resolution laser angle-resolved photoemission spectroscopy unveils that KFe2As2 is a nodal s-wave superconductor with highly unusual FS-selective multi-gap structure: a nodeless gap on the inner FS, an unconventional gap with “octet-line nodes” on the middle FS, and an almost-zero gap on the outer FS. This gap structure may arise from the frustration between competing pairing interactions on the hole FSs causing the eightfold sign reversal. Our results suggest that the A1g superconducting symmetry is universal in iron-pnictides, in spite of the variety of gap functions.

Superconductivity in an electron band just above the Fermi level: possible route to BCS-BEC superconductivity

Conventional superconductivity follows Bardeen-Cooper-Schrieffer(BCS) theory of electrons-pairing in momentum-space, while superfluidity is the Bose-Einstein condensation(BEC) of atoms paired in real-space. These properties of solid metals and ultra-cold gases, respectively, are connected by the BCS-BEC crossover. Here we investigate the band dispersions in FeTe0.6Se0.4(Tc = 14.5 K ~ 1.2 meV) in an accessible range below and above the Fermi level(EF) using ultra-high resolution laser angle-resolved photoemission spectroscopy. We uncover an electron band lying just 0.7 meV (~8 K) above EF at the Γ-point, which shows a sharp superconducting coherence peak with gap formation below Tc. The estimated superconducting gap Δ and Fermi energy indicate composite superconductivity in an iron-based superconductor, consisting of strong-coupling BEC in the electron band and weak-coupling BCS-like superconductivity in the hole band. The study identifies the possible route to BCS-BEC superconductivity.

In situ Photoemission Study of the Room Temperature Ferromagnet ZnGeP2:Mn

The chemical states of the ZnGeP(2):Mn interface which shows ferromagnetism above room temperature have been studied by photoemission spectroscopy. Mn deposition on the ZnGeP2 substrate heated to 400 degrees C induced Mn substitution for Zn and then the formation of metallic Mn-Ge-P compounds. Depth profile studies have shown that Mn 3d electrons changed their character from itinerant to localized along the depth, and in the deep region, dilute divalent Mn species (<5% Mn) was observed with a coexisting metallic Fermi edge of non-Mn 3d character. The possibility of hole doping through Mn substitution for Ge and/or Zn vacancy is discussed.

Suppression of the antiferromagnetic pseudogap in the electron-doped high-temperature superconductor by protect annealing

In the hole-doped cuprates, a small number of carriers suppresses antiferromagnetism and induces superconductivity. In the electron-doped cuprates, on the other hand, superconductivity appears only in a narrow window of high-doped Ce concentration after reduction annealing, and strong antiferromagnetic correlation persists in the superconducting phase. Recently, Pr1.3−xLa0.7CexCuO4 (PLCCO) bulk single crystals annealed by a protect annealing method showed a high critical temperature of around 27 K for small Ce content down to 0.05. Here, by angle-resolved photoemission spectroscopy measurements of PLCCO crystals, we observed a sharp quasi-particle peak on the entire Fermi surface without signature of an antiferromagnetic pseudogap unlike all the previous work, indicating a dramatic reduction of antiferromagnetic correlation length and/or of magnetic moments. The superconducting state was found to extend over a wide electron concentration range. The present results fundamentally challenge the long-standing picture on the electronic structure in the electron-doped regime.

Abrupt change in the energy gap of superconducting Ba1−xKxFe2As2single crystals with hole doping

We performed a Laser angle-resolved photoemission spectroscopy (ARPES) study on a wide doping range of Ba1-xKxFe2As2 (BaK) and precisely determined the doping evolution of the superconducting (SC) gaps in this compound. The gap size of the outer hole Fermi surface (FS) sheet around the Brillioun zone (BZ) center shows an abrupt drop with overdoping (for x > 0.6) while the inner and middle FS gaps roughly scale with Tc. This is accompanied by the simultaneous disappearance of the electron FS sheet with similar orbital character at the BZ corner. These results browse the different contributions of X2-Y2 and XZ/YZ orbitals to superconductivity in BaK and can be hardly completely reproduced by the available theories on iron-based superconductors.

Observation of topological superconductivity on the surface of an iron-based superconductor

A topological superconductor A promising path toward topological quantum computing involves exotic quasiparticles called the Majorana bound states (MBSs). MBSs have been observed in heterostructures that require careful nanofabrication, but the complexity of such systems makes further progress tricky. Zhang et al. identified a topological superconductor in which MBSs may be observed in a simpler way by looking into the cores of vortices induced by an external magnetic field. Using angle-resolved photoemission, the researchers found that the surface of the iron superconductor FeTe0.55Se0.45 satisfies the required conditions for topological superconductivity. Science, this issue p. 182 Angle-resolved photoemission spectroscopy indicates that FeTe0.55Se0.45 harbors Dirac-cone–type spin-helical surface states. Topological superconductors are predicted to host exotic Majorana states that obey non-Abelian statistics and can be used to implement a topological quantum computer. Most of the proposed topological superconductors are realized in difficult-to-fabricate heterostructures at very low temperatures. By using high-resolution spin-resolved and angle-resolved photoelectron spectroscopy, we find that the iron-based superconductor FeTe1–xSex (x = 0.45; superconducting transition temperature Tc = 14.5 kelvin) hosts Dirac-cone–type spin-helical surface states at the Fermi level; the surface states exhibit an s-wave superconducting gap below Tc. Our study shows that the surface states of FeTe0.55Se0.45 are topologically superconducting, providing a simple and possibly high-temperature platform for realizing Majorana states.

Evidence for a cos(4φ) modulation of the superconducting energy gap of optimally doped FeTe(0.6)Se(0.4) single crystals using laser angle-resolved photoemission spectroscopy.

We study the superconducting-gap anisotropy of the Γ-centered hole Fermi surface in optimally doped FeTe(0.6)Se(0.4) (T(c)=14.5 K), using laser-excited angle-resolved photoemission spectroscopy. We observe sharp superconducting (SC) coherence peaks at T=2.5 K. In contrast to earlier angle-resolved photoemission spectroscopy studies but consistent with thermodynamic results, the momentum dependence shows a cos(4φ) modulation of the SC-gap anisotropy. The observed SC-gap anisotropy strongly indicates that the pairing interaction is not a conventional phonon-mediated isotropic one. Instead, the results suggest the importance of second-nearest-neighbor electronic interactions between the iron sites in the framework of s(±)-wave superconductivity.

Electronic structure of Mott–Hubbard-type transition-metal oxides

Abstract Oxides of Ti and V belong to the Mott–Hubbard regime of the Zaanen–Sawatzky–Allen classification scheme of transition-metal compounds and have simple electronic structures which allow us to study the effect of electron correlation in a transparent way. In this article, we make an overview of our recent photoemission studies on Ti and V oxides, with special emphasis on metal-insulator transitions induced by the control of the width and the filling of the Ti and V 3d bands. Spectroscopic data yield spectral weight transfer between the coherent and incoherent parts of the d band, the spectral intensities at the Fermi level and the chemical potential shifts as functions of band filling. We show that such spectroscopic information well corresponds to the thermodynamic and transport properties and is necessary to understand electron correlation phenomena from a fundamental viewpoint.

Unconventional Superconductivity in the BiS2 -Based Layered Superconductor NdO0.71F0.29BiS2

We investigate the superconducting-gap anisotropy in one of the recently discovered BiS_{2}-based superconductors, NdO_{0.71}F_{0.29}BiS_{2} (T_{c}∼5  K), using laser-based angle-resolved photoemission spectroscopy. Whereas the previously discovered high-T_{c} superconductors such as copper oxides and iron-based superconductors, which are believed to have unconventional superconducting mechanisms, have 3d electrons in their conduction bands, the conduction band of BiS_{2}-based superconductors mainly consists of Bi 6p electrons, and, hence, the conventional superconducting mechanism might be expected. Contrary to this expectation, we observe a strongly anisotropic superconducting gap. This result strongly suggests that the pairing mechanism for NdO_{0.71}F_{0.29}BiS_{2} is an unconventional one and we attribute the observed anisotropy to competitive or cooperative multiple paring interactions.

Temperature-dependent electronic structure of VO2 in the insulating phase

We have studied the temperature-dependent electronic structure of VO 2 in the insulating phase. The V 3 d and O 2 p bands become broader and their band edges are shifted toward the Fermi level ( E F ) with increasing temperature. The V 2 p and O 1 s core-level spectra also show a similar temperature dependence. These observations combined with optical spectra indicate that the position of E F relative to the conduction-band minimum is fixed and that the band gap changes mainly below E F . We also point out the possibility that electron-phonon interaction plays an important role in the temperature dependence of spectra in the insulating phase and may drive the metal-insulator transition.