K. Sopian

Carbonaceous materials and their advances as a counter electrode in dye-sensitized solar cells: Challenges and prospects

Dye-sensitized solar cells (DSSCs) serve as low-costing alternatives to silicon solar cells because of their low material and fabrication costs. Usually, they utilize Pt as the counter electrode (CE) to catalyze the iodine redox couple and to complete the electric circuit. Given that Pt is a rare and expensive metal, various carbon materials have been intensively investigated because of their low costs, high surface areas, excellent electrochemical stabilities, reasonable electrochemical activities, and high corrosion resistances. In this feature article, we provide an overview of recent studies on the electrochemical properties and photovoltaic performances of carbon-based CEs (e.g., activated carbon, nanosized carbon, carbon black, graphene, graphite, carbon nanotubes, and composite carbon). We focus on scientific challenges associated with each material and highlight recent advances achieved in overcoming these obstacles. Finally, we discuss possible future directions for this field of research aimed at obtaining highly efficient DSSCs.

Techno-economical assessment of grid connected PV/T using nanoparticles and water as base-fluid systems in Malaysia

ABSTRACT In this study, the techno-economic assessment of GCPVT with nanofluid has been investigated based on theoretical and experimental work in Malaysia. The productivity and utilisation of the PV have been investigated using yield and capacity factors (CFs), respectively. Also, the cost of energy and payback period has been calculated. The system installed, tested, and data have been collected. Evaluation of the system in terms of current, voltage, power and efficiency are presented. The average daily ambient temperature and total global solar energy in Kuala Lumpur are 38.89°C and 4062 Wh/m2, respectively. MATLAB software is used to analyse the measured data. The assessment results show that the GCPVT system has annual yield factor, CF, the cost of energy; payback period, and efficiency are (128.34–183.75) kWh/kWp, (17.82–25.52)%, 0.196 USD/kWh, 7–8 years and 9.1%, respectively. This study indicates that the GCPVT system with nanofluid improved the PV technical and economic performance. GRAPHICAL ABSTRACT