Kaarle Hämeri

Emission Rates Due to Indoor Activities: Indoor Aerosol Model Development, Evaluation, and Applications

This study presents an indoor aerosol model based on size-resolved and multi-compartment approach. The current indoor aerosol model is also developed with a semi-empirical technique to estimate the emission rates due to indoor sources of aerosol particles. We present in this study a methodology to predict and estimate the best-fit input parameters for the current indoor aerosol model. The performance of the current indoor aerosol model in its single-compartment form was evaluated against previously measured indoor-outdoor aerosol data sets from an office room with mechanical ventilation and a family house with natural ventilation. The indoor aerosol model simulations show that the current methodology used to predict the best-fit input parameters to the indoor aerosol model is efficient. As expected, the penetration factor, aerosol particle deposition, and ventilation rate are the most important parameters in the indoor-outdoor relationship of aerosol particles transport. The emission rate analysis showed that fine aerosol particles production was as high as 26 particle/cm 3 s during wood burning in a fireplace. The emission rate was about eight times this value during grilling in a fireplace and sauna heating. Indoor activities take place in another room may significantly increase the aerosol particle concentrations in other rooms in the building. Therefore, it is recommended to use extra air cleaners in houses to reduce the number concentrations of emitted aerosol particles. The quantitative and qualitative results obtained by the current indoor aerosol model in this study are building and condition specific. Applying the current model to a broad range of conditions and previously measured indoor-outdoor aerosol data sets provides better understanding of aerosol particle characteristics indoors, especially regarding the aerosol particles produced during different indoor activities.

Dependence of home outdoor particulate mass and number concentrations on residential and traffic features in urban areas

Abstract The associations between residential outdoor and ambient particle mass, fine particle absorbance, particle number (PN) concentrations, and residential and traffic determinants were investigated in four European urban areas (Helsinki, Athens, Amsterdam, and Birmingham). A total of 152 nonsmoking participants with respiratory diseases, not exposed to occupational pollution, were included in the study, which comprised a 7-day intensive exposure monitoring period of both indoor and home outdoor particle mass and number concentrations. The same pollutants were also continuously measured at ambient fixed sites centrally located to the studied areas (fixed ambient sites). Relationships between concentrations measured directly outside the homes (residential outdoor) and at the fixed ambient sites were pollutant-specific, with substantial variations among the urban areas. Differences were more pronounced for coarse particles due to resuspension of road dust and PN, which is strongly related to traffic emissions. Less significant outdoor-to-fixed variation for particle mass was observed for Amsterdam and Birmingham, predominantly due to regional secondary aerosol. On the contrary, a strong spatial variation was observed for Athens and to a lesser extent for Helsinki. This was attributed to the overwhelming and time-varied inputs from traffic and other local sources. The location of the residence and traffic volume and distance to street and traffic light were important determinants of residential outdoor particle concentrations. On average, particle mass levels in suburban areas were less than 30% of those measured for residences located in the city center. Residences located less than 10 m from a street experienced 133% higher PN concentrations than residences located further away. Overall, the findings of this multi-city study, indicated that (1) spatial variation was larger for PN than for fine particulate matter (PM) mass and varied between the cities, (2) vehicular emissions in the residential street and location in the center of the city were significant predictors of spatial variation, and (3) the impact of traffic and location in the city was much larger for PN than for fine particle mass.

Modeling regional deposited dose of submicron aerosol particles

We developed a simple model to calculate the regional deposited dose of submicron aerosol particles in the respiratory system. This model incorporates measured outdoor and modeled indoor particle number size distributions, detailed activity patterns of three age groups (teens, adults, and the elderly), semi-empirical estimation of the regional deposition fraction, hygroscopic properties of urban aerosols, and reported breathing minute volumes. We calculated the total and regional deposited dose based on three concentration metrics: particle number (PN), mass (PM), and surface area (PSA). The 24-h total deposited dose of fine particles in adult males was around 40 μg (57×109 particles, 8×102 mm(2)) and 41 μg (40×109 particles, 8×102 mm(2)) on workdays and weekends, respectively. The total and regional 24-h deposited dose based on any of the metrics was at most 1.5 times higher in males than in females. The deposited dose values in the other age groups were slightly different than in adults. Regardless of the particle size fraction or the deposited dose metric, the pulmonary/alveolar region received the largest fraction of the deposited dose. These values represent the lowest estimate of the deposited dose and they are expected to be higher in real-life conditions after considering indoor sources of aerosol particles and spatial variability of outdoor aerosols. This model can be extended to youngsters (<12 years old) after gaining accurate information about the deposition fraction inside their respiratory system and their breathing pattern. This investigation is foreseen to bridge the gap between exposure and response in epidemiological studies.

Range-Finding Risk Assessment of Inhalation Exposure to Nanodiamonds in a Laboratory Environment

This study considers fundamental methods in occupational risk assessment of exposure to airborne engineered nanomaterials. We discuss characterization of particle emissions, exposure assessment, hazard assessment with in vitro studies, and risk range characterization using calculated inhaled doses and dose-response translated to humans from in vitro studies. Here, the methods were utilized to assess workers’ risk range of inhalation exposure to nanodiamonds (NDs) during handling and sieving of ND powder. NDs were agglomerated to over 500 nm particles, and mean exposure levels of different work tasks varied from 0.24 to 4.96 µg·m−3 (0.08 to 0.74 cm−3). In vitro-experiments suggested that ND exposure may cause a risk for activation of inflammatory cascade. However, risk range characterization based on in vitro dose-response was not performed because accurate assessment of delivered (settled) dose on the cells was not possible. Comparison of ND exposure with common pollutants revealed that ND exposure was below 5 μg·m−3, which is one of the proposed exposure limits for diesel particulate matter, and the workers’ calculated dose of NDs during the measurement day was 74 ng which corresponded to 0.02% of the modeled daily (24 h) dose of submicrometer urban air particles.

Wood Dust Particle and Mass Concentrations and Filtration Efficiency in Sanding of Wood Materials

The importance of fine particles has become apparent as the knowledge of their effects on health has increased. Fine particle concentrations have been published for outside air, plasma arc cutting, welding, and grinding, but little data exists for the woodworking industry. Sanding was evaluated as the producer of the woodworking industrys finest particles, and was selected as the target study. The number of dust particles in different particle size classes and the mass concentrations were measured in the following environments: workplace air during sanding in plywood production and in the inlet and return air; in the dust emission chamber; and in filter testing. The numbers of fine particles were low, less than 104 particles/cm3 (107 particles/L). They were much lower than typical number concentrations near 106 particles/cm3 measured in plasma arc cutting, grinding, and welding. Ultrafine particles in the size class less than 100 nm were found during sanding of MDF (medium density fiberboard) sheets. When the cleaned air is returned to the working areas, the dust content in extraction systems must be monitored continuously. One way to monitor the dust content in the return air is to use an after-filter and measure pressure drop across the filter to indicate leaks in the air-cleaning system. The best after-filtration materials provided a clear increase in pressure drop across the filter in the loading of the filter. The best after-filtration materials proved to be quite effective also for fine particles. The best mass removal efficiencies for fine particles around 0.3 μm were over 80% for some filter materials loaded with sanding wood dust.

Particle Concentration Profile in a Vertical Displacement Flow: A Study in an Industrial Hall

The effect of displacement flow on the distribution of aerosol concentration was investigated in an industrial hall. According to the displacement ventilation principle, vertical upflow is accomplished by introducing fresh air, cooler than room air, into the occupied zone near floor level. The fresh air is introduced from low-velocity devices and heated by warm processes. This technique allows warm air contaminants to rise to the ceiling, and the rising plume is then exhausted close to the ceiling. This study presents the results of a field study conducted in an industrial environment. The aerosol properties and behavior, especially the vertical gradients, are characterized in a displacement flow field. The results indicate that the fine particles, less than 1 microm in diameter, are transported away from the breathing zone by the ventilation process. However, the air quality is significantly influenced by the emission source, and therefore the number concentration of fine and ultrafine (smaller than 0.1 microm in diameter) aerosol particles in the breathing zone was clearly elevated compared to that of the incoming clean air. The vertical gradients displayed clear size dependence; the strongest gradients were found for particles between 0.003 and 0.015 microm in diameter.