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Dive into the research topics where Kaarlo Kalliorinne is active.

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Featured researches published by Kaarlo Kalliorinne.


Journal of Photochemistry and Photobiology A-chemistry | 1988

Kinetics of reactions between methyl and dimethyl-aminyl radicals formed in the flash photolysis of tetramethylhydrazine, tetramethylurea and tetramethyltetrazene in the gas phase

Kaarlo Kalliorinne; Jouko Koskikallio

Abstract Methyl and dimethylaminyl radicals are formed in the flash photolysis of tetramethylhydrazine, tetramethylurea and tetramethyltetrazene in the gas phase. The rate constants of radical combination and hydrogen exchange reactions between methyl and dimethylaminyl radicals were calculated with a computer integration program, using a least-squares iteration method, from the amounts of final products determined by gas chromatography. The ratio of the rate constants of the combination and hydrogen abstraction reactions between two dimethylmaminyl radicals (1.55 ± 0.2) is close to the value (1.59 ± 0.2) for the ratio of the rate constants of the respective reactions between methyl and dimethylaminyl radicals.


International Journal of Chemical Kinetics | 1990

Kinetics of reactions between methyl and acetyl radicals in gas phase produced by flash photolysis of acetic anhydride

Eero Hassinen; Kaarlo Kalliorinne; Jouko Koskikallio


Acta Chemica Scandinavica | 1986

Kinetics of Radical Reactions between Methyl, Acetyl and Dimethylamino Radicals Formed in the Flash Photolysis of N,N-Dimethylacetamide in the Gas Phase.

K. Blomqvist; Kaarlo Kalliorinne; Jouko Koskikallio; Fabio Urso; Ikuo Suzuki; Tadashi Tokii; Ralph A. Zingaro


International Journal of Chemical Kinetics | 1982

Flash photolysis of biacetyl in gas phase. Rate constants of reactions between methyl and acetyl radicals

Raimo S. Timonen; Kaarlo Kalliorinne; K. Blomqvist; Jouko Koskikallio


Acta Chemica Scandinavica | 1986

Kinetics of reactions of methyl and ethyl radicals with chlorine in the gas phase studied by photochlorination of methane

Raimo S. Timonen; Kaarlo Kalliorinne; Jouko Koskikallio


International Journal of Chemical Kinetics | 1985

Kinetics of reactions between methoxycarbonyl, methyl, and methoxy radicals formed in flash photolysis of dimethyl oxalate in gas phase

Eero Hassinen; P. Riepponen; K. Blomqvist; Kaarlo Kalliorinne; A. M. Evseev; Jouko Koskikallio


Acta Chemica Scandinavica | 1969

The Influence of the Solvent on Reaction Velocity. XL. The Reaction between Benzyl Chlorides and Thiosulphate Ion in Acetone-Water, Dioxane-Water, and Dimethyl Sulphoxide-Water Mixtures.

Kaarlo Kalliorinne; Eero Tommila; Osmo Mäkitie; D. Heinegard; Alexandru T. Balaban; J. Cymerman Craig


Acta Chemica Scandinavica | 1986

Photoinduced Water Exchange of the Isomeric Ammineaquachromium(III) Complexes, and Mechanism of Solvent-Assisted Excited State Deactivation.

L. Mønsted; O. Mønsted; Kaarlo Kalliorinne; Jouko Koskikallio; Fabio Urso; Ikuo Suzuki; Tadashi Tokii; Ralph A. Zingaro


Bulletin des Sociétés Chimiques Belges | 2010

Rates of Reactions Between Methoxycarbonyl, Methyl and Methoxy Radicals Formed in Flash Photolysis of Dimethyl Oxalate in Gas Phase

Eero Hassinen; P. Riepponen; K. Blomqvist; Kaarlo Kalliorinne; Jouko Koskikallio


ChemInform | 1986

Kinetics of Reactions Between Methoxycarbonyl, Methyl, and Methoxy Radicals Formed in Flash Photolysis of Dimethyl Oxalate in Gas Phase

E. Hassinen; P. Riepponen; K. Blomqvist; Kaarlo Kalliorinne; A. M. Evseev; Jouko Koskikallio

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Fabio Urso

Chalmers University of Technology

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Ikuo Suzuki

Nagoya Institute of Technology

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