Kahraman Keskinbora

Rapid prototyping of Fresnel zone plates via direct Ga+ ion beam lithography for high-resolution x-ray imaging

A significant challenge to the wide utilization of X-ray microscopy lies in the difficulty in fabricating adequate high-resolution optics. To date, electron beam lithography has been the dominant technique for the fabrication of diffractive focusing optics called Fresnel zone plates (FZP), even though this preparation method is usually very complicated and is composed of many fabrication steps. In this work, we demonstrate an alternative method that allows the direct, simple, and fast fabrication of FZPs using focused Ga(+) beam lithography practically, in a single step. This method enabled us to prepare a high-resolution FZP in less than 13 min. The performance of the FZP was evaluated in a scanning transmission soft X-ray microscope where nanostructures as small as sub-29 nm in width were clearly resolved, with an ultimate cutoff resolution of 24.25 nm, demonstrating the highest first-order resolution for any FZP fabricated by the ion beam lithography technique. This rapid and simple fabrication scheme illustrates the capabilities and the potential of direct ion beam lithography (IBL) and is expected to increase the accessibility of high-resolution optics to a wider community of researchers working on soft X-ray and extreme ultraviolet microscopy using synchrotron radiation and advanced laboratory sources.

Ion beam lithography for Fresnel zone plates in X-ray microscopy

Fresnel Zone Plates (FZP) are to date very successful focusing optics for X-rays. Established methods of fabrication are rather complex and based on electron beam lithography (EBL). Here, we show that ion beam lithography (IBL) may advantageously simplify their preparation. A FZP operable from the extreme UV to the limit of the hard X-ray was prepared and tested from 450 eV to 1500 eV. The trapezoidal profile of the FZP favorably activates its 2nd order focus. The FZP with an outermost zone width of 100 nm allows the visualization of features down to 61, 31 and 21 nm in the 1st, 2nd and 3rd order focus respectively. Measured efficiencies in the 1st and 2nd order of diffraction reach the theoretical predictions.

Efficient focusing of 8 keV X-rays with multilayer Fresnel zone plates fabricated by atomic layer deposition and focused ion beam milling

The fabrication and performance of multilayer Al2O3/Ta2O5 Fresnel zone plates in the hard X-ray range and a discussion of possible future developments considering available materials are reported.

Multilayer Fresnel zone plates for high energy radiation resolve 21 nm features at 1.2 keV

X-ray microscopy is a successful technique with applications in several key fields. Fresnel zone plates (FZPs) have been the optical elements driving its success, especially in the soft X-ray range. However, focusing of hard X-rays via FZPs remains a challenge. It is demonstrated here, that two multilayer type FZPs, delivered from the same multilayer deposit, focus both hard and soft X-rays with high fidelity. The results prove that these lenses can achieve at least 21 nm half-pitch resolution at 1.2 keV demonstrated by direct imaging, and sub-30 nm FWHM (full-pitch) resolution at 7.9 keV, deduced from autocorrelation analysis. Reported FZPs had more than 10% diffraction efficiency near 1.5 keV.

High-resolution high-efficiency multilayer Fresnel zone plates for soft and hard x-rays

X-ray microscopy enables high spatial resolutions, high penetration depths and characterization of a broad range of materials. Calculations show that nanometer range resolution is achievable in the hard X-ray regime by using Fresnel zone plates (FZPs) if certain conditions are satisfied. However, this requires, among other things, aspect ratios of several thousands. The multilayer (ML) type FZPs, having virtually unlimited aspect ratios, are strong candidates to achieve single nanometer resolutions. Our research is focused on the fabrication of ML-FZPs which encompasses deposition of multilayers over a glass fiber via the atomic layer deposition (ALD), which is subsequently sliced in the optimum thickness for the X-ray energy by a focused ion beam (FIB). We recently achieved aberration free imaging by resolving 21 nm features with an efficiency of up to 12.5 %, the highest imaging resolution achieved by an ML-FZP. We also showed efficient focusing of 7.9 keV X-rays down to 30 nm focal spot size (FWHM). For resolutions below ~10 nm, efficiencies would decrease significantly due to wave coupling effects. To compensate this effect high efficiency, low stress materials have to be researched, as lower intrinsic stresses will allow fabrication of larger FZPs with higher number of zones, leading to high light intensity at the focus. As a first step we fabricated an ML-FZP with a diameter of 62 μm, an outermost zone width of 12 nm and 452 active zones. Further strategies for fabrication of high resolution high efficiency multilayer FZPs will also be discussed.

Optimizing the fabrication of diffractive optical elements using a focused ion beam system

In the past, UV lithography has been used extensively for the fabrication of diffractive optical elements (DOEs). The advantage of this technique is that the entire structure can be written at one time, however, the minimum feature size is limited to about 1 μm. Many 1-d and 2-d periodic grating structures may not need such fine details but it is essential for diffractive optics with circular structures. This is because the spacing between features typically decreases towards the edge of the element resulting in the smallest feature falling well below 1 μm. 1-d structures such as sub-wavelength gratings will also have smaller feature sizes throughout the structure. In such cases, advanced techniques such as Focused Ion Beam and Electron-beam Lithography are required for the fabrication of finer structures. In this paper, we present results of DOEs fabricated with a focused ion beam system (Nova Nanolab 600 from FEI) directly on a single mode fibre tip. The ability to write DOEs directly on fibre tip is of great importance in fields such as endoscopy and optical trapping. The DOE itself, transforms the laser beam to a phase and intensity profile that matches the requirement. Because it is located directly on the fibre, no extra alignment is required. In addition, the system becomes more compact, which is especially important for applications in the field of endoscopy. The main goal of the present work was to develop the most accurate method for creating the desired pattern (that is, the DOE structure) into an actually working element. Different exposure strategies for writing test structures directly with the ion beam on the fibre tip have been tested and carefully evaluated. The paper will present in detail the initial fabrication and optical test results for blazed and binary structures of 1-d and circularly symmetric Fresnel axicons on optical fibres.

Recent advances in use of atomic layer deposition and focused ion beams for fabrication of Fresnel zone plates for hard x-rays

Developments and advances in the e-beam lithography (EBL) made it possible to reach resolutions in a single digit nanometer range in the soft x-ray microscopy using Fresnel Zone Plates (FZP). However, it is very difficult to fabricate efficient FZPs for hard x-rays via this conventional fabrication technique due to limitations in the achievable aspect ratios. Here, we demonstrate the use of alternative fabrication techniques that depend on utilization of atomic layer deposition and focused ion beam processing to deliver FZPs that are efficient for the hard X-ray range.

Overview of the multilayer-Fresnel zone plate and the kinoform lens development at MPI for Intelligent Systems

The ultimate goal of our research is to develop novel fabrication methods for high efficiency and high resolution X-ray optics. To this end, we have been pursuing the fabrication of several innovative diffractive/refractive optics designs. One such optic is the multilayer type Fresnel zone plate (ML-FZP). Our fabrication process relies on the atomic layer deposition (ALD) of two materials on a smooth glass fiber followed by a focused ion beam (FIB) based slicing and polishing. The ALD process allows much smaller outermost zone widths than the standard electron beam lithography based FZPs, meaning FZPs with potentially higher resolutions. Moreover, by depositing the multilayer on a cm long glass-fiber FZPs with very high optical thicknesses can be fabricated that can efficiently focus harder X-rays as well. A 21 nm half-pitch resolution was achieved using the ML-FZPs. Another optic we have been working on is the kinoform lens, which is a refractive/diffractive optic with a 100 % theoretical focusing efficiency. Their fabrication is usually realized by using approximate models which limit their success. Recently the fabrication of real kinoform lenses has been successfully realized in our lab via gray-scale direct-write ion beam lithography without any approximations. The lenses have been tested in the soft X-ray range achieving up to ~90 % of the calculated efficiency which indicates outstanding replication of the designed profile. Here we give an overview of our research and discuss the future challenges and opportunities for these optics.

Fabrication and X-ray testing of true kinoform lenses with high efficiencies

Kinoform lenses are focusing optics with a 100 % theoretical focusing efficiency. Up to date, the actual continuous 3D surface relief profiles of X-ray kinoform lenses could only be approximately fabricated. Now, we have come up with an effective ion beam lithography fabrication strategy producing first-ever imaging-quality circularly symmetric kinoform lenses which demonstrated reasonably high focusing efficiencies. Here, we will discuss the potential of the fabrication method and the utility of kinoform lenses enabled by it. Special emphases will be placed on materials development including selection and design, efficiency considerations for various energies and possible applications.

3D Nanofabrication of High-Resolution Multilayer Fresnel Zone Plates

Abstract Focusing X‐rays to single nanometer dimensions is impeded by the lack of high‐quality, high‐resolution optics. Challenges in fabricating high aspect ratio 3D nanostructures limit the quality and the resolution. Multilayer zone plates target this challenge by offering virtually unlimited and freely selectable aspect ratios. Here, a full‐ceramic zone plate is fabricated via atomic layer deposition of multilayers over optical quality glass fibers and subsequent focused ion beam slicing. The quality of the multilayers is confirmed up to an aspect ratio of 500 with zones as thin as 25 nm. Focusing performance of the fabricated zone plate is tested toward the high‐energy limit of a soft X‐ray scanning transmission microscope, achieving a 15 nm half‐pitch cut‐off resolution. Sources of adverse influences are identified, and effective routes for improving the zone plate performance are elaborated, paving a clear path toward using multilayer zone plates in high‐energy X‐ray microscopy. Finally, a new fabrication concept is introduced for making zone plates with precisely tilted zones, targeting even higher resolutions.